scholarly journals Influencing parameters on the sintering process of steel slag-based ceramics for high-temperature thermal energy storage

2020 ◽  
Author(s):  
Kholoud M. Al Naimi ◽  
Jean-Francois Hoffmann ◽  
Khalid Al Ali ◽  
Nicolas Calvet
Keyword(s):  
High Temperature ◽  
Energy Storage ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Steel Slag ◽  
Sintering Process ◽  
Influencing Parameters

scholarly journals Demonstration of Phase Change Thermal Energy Storage in Zinc Oxide Microencapsulated Sodium Nitrate

2021 ◽  
Vol 11 (13) ◽  
pp. 6234
Author(s):  
Ciprian Neagoe ◽  
Ioan Albert Tudor ◽  
Cristina Florentina Ciobota ◽  
Cristian Bogdanescu ◽  
Paul Stanciu ◽  
...  
Keyword(s):  
Zinc Oxide ◽  
Thermal Properties ◽  
High Temperature ◽  
Energy Storage ◽  
Phase Change ◽  
Thermal Energy ◽  
Sodium Nitrate ◽  
Thermal Energy Storage ◽  
Metal Corrosion ◽  
Scanning Calorimetry

Microencapsulation of sodium nitrate (NaNO3) as phase change material for high temperature thermal energy storage aims to reduce costs related to metal corrosion in storage tanks. The goal of this work was to test in a prototype thermal energy storage tank (16.7 L internal volume) the thermal properties of NaNO3 microencapsulated in zinc oxide shells, and estimate the potential of NaNO3–ZnO microcapsules for thermal storage applications. A fast and scalable microencapsulation procedure was developed, a flow calorimetry method was adapted, and a template document created to perform tank thermal transfer simulation by the finite element method (FEM) was set in Microsoft Excel. Differential scanning calorimetry (DSC) and transient plane source (TPS) methods were used to measure, in small samples, the temperature dependency of melting/solidification heat, specific heat, and thermal conductivity of the NaNO3–ZnO microcapsules. Scanning electron microscopy (SEM) and chemical analysis demonstrated the stability of microcapsules over multiple tank charge–discharge cycles. The energy stored as latent heat is available for a temperature interval from 303 to 285 °C, corresponding to onset–offset for NaNO3 solidification. Charge–self-discharge experiments on the pilot tank showed that the amount of thermal energy stored in this interval largely corresponds to the NaNO3 content of the microcapsules; the high temperature energy density of microcapsules is estimated in the range from 145 to 179 MJ/m3. Comparison between real tank experiments and FEM simulations demonstrated that DSC and TPS laboratory measurements on microcapsule thermal properties may reliably be used to design applications for thermal energy storage.

scholarly journals Multidisciplinary Approaches for Assessing a High Temperature Borehole Thermal Energy Storage Facility at Linköping, Sweden

Energies ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 4379
Author(s):  
Max Hesselbrandt ◽  
Mikael Erlström ◽  
Daniel Sopher ◽  
Jose Acuna
Keyword(s):  
Thermal Properties ◽  
High Temperature ◽  
Energy Storage ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Thermal Response ◽  
Site Investigation ◽  
Thermal Response Test ◽  
Response Test ◽  
Crystalline Bedrock

Assessing the optimal placement and design of a large-scale high temperature energy storage system in crystalline bedrock is a challenging task. This study applies and evaluates various methods and strategies for pre-site investigation for a potential high temperature borehole thermal energy storage (HT-BTES) system at Linköping in Sweden. The storage is required to shift approximately 70 GWh of excess heat generated from a waste incineration plant during the summer to the winter season. Ideally, the site for the HT-BTES system should be able to accommodate up to 1400 wells to 300 m depth. The presence of major fracture zones, high groundwater flow, anisotropic thermal properties, and thick Quaternary overburden are all factors that play an important role in the performance of an HT-BTES system. Inadequate input data to the modeling and design increases the risk of unsatisfactory performance, unwanted thermal impact on the surroundings, and suboptimal placement of the HT-BTES system, especially in a complex crystalline bedrock setting. Hence, it is crucial that the subsurface geological conditions and associated thermal properties are suitably characterized as part of pre-investigation work. In this study, we utilize a range of methods for pre-site investigation in the greater Distorp area, in the vicinity of Linköping. Ground geophysical methods, including magnetic and Very Low-Frequency (VLF) measurements, are collected across the study area together with outcrop observations and lab analysis on rock samples. Borehole investigations are conducted, including Thermal Response Test (TRT) and Distributed Thermal Response Test (DTRT) measurements, as well as geophysical wireline logging. Drone-based photogrammetry is also applied to characterize the fracture distribution and orientation in outcrops. In the case of the Distorp site, these methods have proven to give useful information to optimize the placement of the HT-BTES system and to inform design and modeling work. Furthermore, many of the methods applied in the study have proven to require only a fraction of the resources required to drill a single well, and hence, can be considered relatively efficient.

Polymer-derived silicon nitride aerogels as shape stabilizers for low and high-temperature thermal energy storage

2021 ◽  
Author(s):  
Andrea Zambotti ◽  
Edoardo Caldesi ◽  
Massimo Pelizzari ◽  
Francesco Valentini ◽  
Alessandro Pegoretti ◽  
...  
Keyword(s):  
High Temperature ◽  
Energy Storage ◽  
Silicon Nitride ◽  
Thermal Energy ◽  
Thermal Energy Storage

New Thermal Energy Storage Materials From Industrial Wastes: Compatibility of Steel Slag With the Most Common Heat Transfer Fluids

2015 ◽  
Vol 137 (4) ◽  
Author(s):  
Iñigo Ortega-Fernández ◽  
Javier Rodríguez-Aseguinolaza ◽  
Antoni Gil ◽  
Abdessamad Faik ◽  
Bruno D’Aguanno
Keyword(s):  
Heat Transfer ◽  
Energy Storage ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Steel Slag ◽  
Industrial Wastes ◽  
Energy Storage Materials ◽  
Iron And Steel ◽  
Heat Transfer Fluids ◽  
Wide Range

Slag is one of the main waste materials of the iron and steel manufacturing. Every year about 20 × 106 tons of slag are generated in the U.S. and 43.5 × 106 tons in Europe. The valorization of this by-product as heat storage material in thermal energy storage (TES) systems has numerous advantages which include the possibility to extend the working temperature range up to 1000 °C, the reduction of the system cost, and at the same time, the decrease of the quantity of waste in the iron and steel industry. In this paper, two different electric arc furnace (EAF) slags from two companies located in the Basque Country (Spain) are studied. Their thermal stability and compatibility in direct contact with the most common heat transfer fluids (HTFs) used in the concentrated solar power (CSP) plants are analyzed. The experiments have been designed in order to cover a wide range of temperature up to the maximum operation temperature of 1000 °C corresponding to the future generation of CSP plants. In particular, three different fluids have been studied: synthetic oil (Syltherm 800®) at 400 °C, molten salt (Solar Salt) at 500 °C, and air at 1000 °C. In addition, a complete characterization of the studied slags and fluids used in the experiments is presented showing the behavior of these materials after 500 hr laboratory-tests.

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