scholarly journals Ionic structure and decay length in highly concentrated confined electrolytes

AIP Advances ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 125312
Author(s):  
Nasim Anousheh ◽  
Francisco J. Solis ◽  
Vikram Jadhao
Keyword(s):  
Decay Length ◽  
Ionic Structure

EHT demonstration of ionic structure of 1-methyl-3-carbamoylpyridinium fluoride and tetrafluoroborate

1978 ◽  
Vol 43 (11) ◽  
pp. 3056-3063
Author(s):  
Josef Kuthan ◽  
Vratislav Skála ◽  
Stanislav Böhm
Keyword(s):  
Ionic Structure

Porous imine-based networks with protonated imine linkages for carbon dioxide separation from mixtures with nitrogen and methane

2015 ◽  
Vol 3 (36) ◽  
pp. 18492-18504 ◽  
Author(s):  
Nadine Popp ◽  
Thomas Homburg ◽  
Norbert Stock ◽  
Jürgen Senker
Keyword(s):  
Carbon Dioxide ◽  
Ionic Structure ◽  
Carbon Dioxide Separation ◽  
Protonated Imine

Porous imine-linked networks with protonated imine linkages and an ionic structure were synthesized. They exhibit good carbon dioxide uptakes and CO2/N2 as well as CO2/CH4 separation coefficients.

The attachment length in orificed hollow cathodes

2021 ◽  
Author(s):  
Christopher Wordingham ◽  
Pierre-Yves Taunay ◽  
Edgar Choueiri
Keyword(s):  
Electron Temperature ◽  
Plasma Density ◽  
Hollow Cathode ◽  
Computational Models ◽  
Closed Form Solution ◽  
Form Solution ◽  
Decay Length ◽  
Plasma Density Profile ◽  
Wide Range ◽  
Approximate Boundary Condition

Abstract A first-principles approach to obtain the attachment length within a hollow cathode with a constrictive orifice, and its scaling with internal cathode pressure, is developed. This parameter, defined herein as the plasma density decay length scale upstream of (away from) the cathode orifice, is critical because it controls the utilization of the hollow cathode insert and influences cathode life. A two-dimensional framework is developed from the ambipolar diffusion equation for the insert-region plasma. A closed-form solution for the plasma density is obtained using standard partial differential equation techniques by applying an approximate boundary condition at the cathode orifice plane. This approach also yields the attachment length and electron temperature without reliance on measured plasma property data or complex computational models. The predicted plasma density profile is validated against measurements from the NSTAR discharge cathode, and calculated electron temperatures and attachment lengths agree with published values. Nondimensionalization of the governing equations reveals that the solution depends almost exclusively on the neutral pressure-diameter product in the insert plasma region. Evaluation of analytical results over a wide range of input parameters yields scaling relations for the variation of the attachment length and electron temperature with the pressure-diameter product. For the range of orifice-to-insert diameter ratio studied, the influence of orifice size is shown to be small except through its effect on insert pressure, and the attachment length is shown to be proportional to the insert inner radius, suggesting high-pressure cathodes should be constructed with larger-diameter inserts.

Synthese und Kristallstrukturen einiger Tetramethylstibonium-Hydrogendicarboxylate / Synthesis and Crystal Structures of Some Tetramethylstibonium Hydrogendicarboxylates

1982 ◽  
Vol 37 (11) ◽  
pp. 1393-1401 ◽  
Author(s):  
Beatrix Milewski-Mahrla ◽  
Hubert Schmidbaur
Keyword(s):  
Hydrogen Bonds ◽  
Crystal Structures ◽  
Spectroscopic Data ◽  
Molar Ratio ◽  
Ionic Structure ◽  
X Ray Diffraction ◽  
X Ray ◽  
Carboxylate Oxygen ◽  
Donor Acceptor ◽  
New Compounds

Reactions of pentamethylantimony (CH3)5Sb with carboxylic acids in the molar ratio 1:2 afford one equivalent of methane and essentially quantitative yields of crystalline tetramothylstibonium hydrogendicarboxylates. Six new compounds of this series have been synthesized using benzoic, o-phthalic, salicylic, 4-ethoxy-salicylic, oxalic, and malic acid, and characterized by analytical and spectroscopic data. An ionic structure with strong hydrogen bonds in the anionic components is proposed.The crystal structures of the hydrogen-dibenzoato (1), hydrogen-ortho-plithalato (2) and 4-ethoxy-hydrogen-salicylate (3) were determined by single crystal X-ray diffraction. The compounds can be described as having ionic lattices with some donor-acceptor inter­actions between the stibonium centers and the carboxylate oxygen atoms. The anions are characterized by strong hydrogen bonds O...H...O. Thus, the (CH3)4Sb-tetrahedron in 1 is distorted by two benzoate oxygon atoms (at 304(2) and 340(2) pin). The cation in 2 is largely undistorted and the anion has a hydrogenphthalate hydrogen bond of d(O...H...O) = 232 pm. The cation-anion contact in 3 is as short as d(Sb-O) = 289 pm rendering the Sb atom pentacoordinate.

Observation of an Exponential FeSi Spacer Thickness Dependence of the Antiferromagnetic Exchange Coupling in Fe/Si-Based Multilayers

1997 ◽  
Vol 475 ◽  
Author(s):  
J.T. Kohlhepp ◽  
J.J. De Vries ◽  
F.J.A. Den Broeder ◽  
R. Coehoorn ◽  
R.M. Jungblut ◽  
...  
Keyword(s):  
Exchange Coupling ◽  
Room Temperature ◽  
Decay Length ◽  
Antiferromagnetic Exchange ◽  
Interlayer Exchange Coupling ◽  
Magnetic Layers ◽  
Magnetic Analysis ◽  
Spacer Thickness ◽  
Interlayer Exchange ◽  
B2 Structure

ABSTRACTThe magnetic interlayer exchange coupling in Fe/Si-based thin film structures employing sputtered multilayers with variations of Si-alloyed Fe for the magnetic layers and Fe-alloyed Si spacers, as well as wedge-shaped MBE-grown Fe/Si/Fe sandwich samples has been systematically studied. From structural and magnetic analysis it is concluded that ultrathin Si and FexSi100-x (x < 50) spacer layers transform into a crystalline iron suicide with a composition close to Fe50Si50. The exchange coupling mediated by this metallic suicide is antiferromagnetic and depends on the spacer thickness in an exponential, i.e. non-oscillatory, manner with a universial characteristic decay length of 3–4 Å at room temperature. This observation can be qualitatively explained within the framework of a recent coupling theory on the premise that the FeSi interlayer has the metastable CsCl(B2)-structure.

scholarly journals catena-Poly[bis(1,3-benzothiazol-3-ium) [[dichloridoantimonate(III)]-di-μ-chlorido-μ-oxido-[chloridoantimonate(III)]-μ-chlorido]]

2016 ◽  
Vol 72 (2) ◽  
pp. 212-214
Author(s):  
Oussama Chebout ◽  
Mhamed Boudraa ◽  
Sofiane Bouacida ◽  
Hocine Merazig ◽  
Chaouki Boudaren
Keyword(s):  
Crystal Packing ◽  
Three Dimensional ◽  
Organic Cations ◽  
Ionic Structure ◽  
Compound C ◽  
Dimensional Network ◽  
Inorganic Cation ◽  
Distorted Octahedral ◽  
Common Face ◽  
Cl Atoms

The title compound, {(C7H6NS)2[Sb2Cl6O]}n, contains two benzothiazolidium cations and one tri-μ-chlorido-trichlorido-μ-oxido-diantimonate(III) anion. The structure of the inorganic cation may be described as as being built up from two polyhedra,i.e.a square-pyramidal SbCl4O and a distorted octahedral SbOCl5unit, sharing a common face (comprising the O atom and two Cl atoms). The two benzothiazole cations are quasi-planar and subtend a dihedral angle of 19.93 (5)°. The crystal packing can be described by alternating (100) layers and [001] chains of the organic cations and inorganic anions connected through an extensive three-dimensional network of N—H...Cl, C—H...O and C—H...Cl hydrogen bonds. This is consolidated by slipped π–π stacking, with centroid-to-centroid distances between the benzothiazole rings of 3.7111 (18)–3.8452 (16) Å. These interactions link the molecules within the layers and also link the layers together and reinforce the cohesion of the ionic structure.

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