scholarly journals Electric deflection of imidazole dimers and trimers in helium nanodroplets: Dipole moments, structure, and fragmentation

2020 ◽  
Vol 153 (8) ◽  
pp. 081101
Author(s):  
Benjamin S. Kamerin ◽  
John W. Niman ◽  
Vitaly V. Kresin
Keyword(s):  
Dipole Moments ◽  
Helium Nanodroplets ◽  
Electric Deflection

Dipole Moments of Molecules Solvated in Helium Nanodroplets

2003 ◽  
Vol 90 (13) ◽  
Author(s):  
Paul L. Stiles ◽  
Klaas Nauta ◽  
Roger E. Miller
Keyword(s):  
Dipole Moments ◽  
Helium Nanodroplets

scholarly journals Direct detection of polar structure formation in helium nanodroplets by beam deflection measurements

2019 ◽  
Vol 21 (37) ◽  
pp. 20764-20769 ◽  
Author(s):  
John W. Niman ◽  
Benjamin S. Kamerin ◽  
Lorenz Kranabetter ◽  
Daniel J. Merthe ◽  
Jiří Suchan ◽  
...  
Keyword(s):  
Structure Formation ◽  
Long Range ◽  
Self Assembly ◽  
Direct Detection ◽  
Molecular Complexes ◽  
Beam Deflection ◽  
Helium Nanodroplets ◽  
Polar Structure ◽  
Electric Deflection

Self-assembly, via long-range forces, of highly polar molecular complexes in helium nanodroplets is revealed by electric deflection of nanodroplet beams.

Dipole moments and tautomeric equilibria of some aroylacetanilides

1981 ◽  
Vol 78 ◽  
pp. 155-159 ◽  
Author(s):  
Magdi M. Naoum ◽  
Hakim G. Shinouda ◽  
Ahmed S. Shawali ◽  
Hanna A. Rizk
Keyword(s):  
Dipole Moments ◽  
Tautomeric Equilibria

A Transferable, Polarisable Force Field for Ionic Liquids

2019 ◽  
Author(s):  
Kateryna Goloviznina ◽  
José N. Canongia Lopes ◽  
Margarida Costa Gomes ◽  
Agilio Padua
Keyword(s):  
Ionic Liquids ◽  
Force Field ◽  
Force Fields ◽  
Dipole Moments ◽  
Van Der Waals Interactions ◽  
First Principles Calculations ◽  
Ion Diffusion ◽  
Fixed Integer ◽  
Molecular Compounds ◽  
Induced Dipoles

A general, transferable polarisable force field for molecular simulation of ionic liquids and their mixtures with molecular compounds is developed. This polarisable model is derived from the widely used CL\&P fixed-charge force field that describes most families of ionic liquids, in a form compatible with OPLS-AA, one of the major force fields for organic compounds. Models for ionic liquids with fixed, integer ionic charges lead to pathologically slow dynamics, a problem that is corrected when polarisation effects are included explicitly. In the model proposed here, Drude induced dipoles are used with parameters determined from atomic polarisabilities. The CL\&P force field is modified upon inclusion of the Drude dipoles, to avoid double-counting of polarisation effects. This modification is based on first-principles calculations of the dispersion and induction contributions to the van der Waals interactions, using symmetry-adapted perturbation theory (SAPT) for a set of dimers composed of positive, negative and neutral fragments representative of a wide variety of ionic liquids. The fragment approach provides transferability, allowing the representation of a multitude of cation and anion families, including different functional groups, without need to re-parametrise. Because SAPT calculations are expensive an alternative predictive scheme was devised, requiring only molecular properties with a clear physical meaning, namely dipole moments and atomic polarisabilities. The new polarisable force field, CL\&Pol, describes a broad set set of ionic liquids and their mixtures with molecular compounds, and is validated by comparisons with experimental data on density, ion diffusion coefficients and viscosity. The approaches proposed here can also be applied to the conversion of other fixed-charged force fields into polarisable versions.<br>

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