Study of frequency dependent dielectric response and ferroelectric behaviour of (Nd,Ni) co-doped BiFeO3

2020 ◽  
Author(s):  
Mehroosh Fatema ◽  
Shahid Husain ◽  
Samiya Manzoor ◽  
Anand Somvanshi ◽  
Naima Zarrin ◽  
...  
Molecules ◽  
2021 ◽  
Vol 26 (11) ◽  
pp. 3230
Author(s):  
Theeranuch Nachaithong ◽  
Narong Chanlek ◽  
Pairot Moontragoon ◽  
Prasit Thongbai

(Co, Nb) co-doped rutile TiO2 (CoNTO) nanoparticles with low dopant concentrations were prepared using a wet chemistry method. A pure rutile TiO2 phase with a dense microstructure and homogeneous dispersion of the dopants was obtained. By co-doping rutile TiO2 with 0.5 at.% (Co, Nb), a very high dielectric permittivity of ε′ » 36,105 and a low loss tangent of tanδ » 0.04 were achieved. The sample–electrode contact and resistive outer-surface layer (surface barrier layer capacitor) have a significant impact on the dielectric response in the CoNTO ceramics. The density functional theory calculation shows that the 2Co atoms are located near the oxygen vacancy, creating a triangle-shaped 2CoVoTi complex defect. On the other hand, the substitution of TiO2 with Nb atoms can form a diamond-shaped 2Nb2Ti complex defect. These two types of complex defects are far away from each other. Therefore, the electron-pinned defect dipoles cannot be considered the primary origins of the dielectric response in the CoNTO ceramics. Impedance spectroscopy shows that the CoNTO ceramics are electrically heterogeneous, comprised of insulating and semiconducting regions. Thus, the dielectric properties of the CoNTO ceramics are attributed to the interfacial polarization at the internal insulating layers with very high resistivity, giving rise to a low loss tangent.


2020 ◽  
Vol 124 (38) ◽  
pp. 20682-20692
Author(s):  
Jakkree Boonlakhorn ◽  
Narong Chanlek ◽  
Prasit Thongbai ◽  
Pornjuk Srepusharawoot

2012 ◽  
Vol 177 (9) ◽  
pp. 673-677 ◽  
Author(s):  
Yunhua Li ◽  
Liang Fang ◽  
Laijun Liu ◽  
Yanming Huang ◽  
Changzheng Hu

2020 ◽  
Vol 127 (20) ◽  
pp. 204103 ◽  
Author(s):  
Payal Sengupta ◽  
Priyabrata Sadhukhan ◽  
Apurba Ray ◽  
Ruma Ray ◽  
Satyaranjan Bhattacharyya ◽  
...  

Soft Matter ◽  
2020 ◽  
Vol 16 (36) ◽  
pp. 8492-8505 ◽  
Author(s):  
Abhishek Sasmal ◽  
Shrabanee Sen ◽  
P. Sujatha Devi

Corona poling improved the energy storage and mechanical energy harvesting performance of PVDF–Bi0.95Ba0.05Fe0.95Zr0.05O3 composite films.


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