scholarly journals Determination of the dehydration pathway in a flexible metal–organic framework by dynamic in situ x-ray diffraction

2020 ◽  
Vol 7 (3) ◽  
pp. 034305
Author(s):  
Ian M. Walton ◽  
Jordan M. Cox ◽  
Shea D. Myers ◽  
Cassidy A. Benson ◽  
Travis B. Mitchell ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
X Ray Diffraction ◽  
X Ray ◽  
Metal Organic ◽  
Flexible Metal ◽  
Organic Framework

scholarly journals Exceptional adsorption-induced cluster and network deformation in the flexible metal–organic framework DUT-8(Ni) observed by in situ X-ray diffraction and EXAFS

2015 ◽  
Vol 17 (26) ◽  
pp. 17471-17479 ◽  
Author(s):  
Volodymyr Bon ◽  
Nicole Klein ◽  
Irena Senkovska ◽  
Andreas Heerwig ◽  
Jürgen Getzschmann ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
X Ray Diffraction ◽  
X Ray ◽  
Gate Opening ◽  
Metal Organic ◽  
Flexible Metal ◽  
Organic Framework

The “gate opening” mechanism in flexible MOF Ni2(2,6-ndc)2dabco was elucidated in detail.

Adsorption of N/S heterocycles in the flexible metal–organic framework MIL-53(FeIII) studied by in situ energy dispersive X-ray diffraction

2013 ◽  
Vol 15 (22) ◽  
pp. 8606 ◽  
Author(s):  
Ben Van de Voorde ◽  
Alexis S. Munn ◽  
Nathalie Guillou ◽  
Franck Millange ◽  
Dirk E. De Vos ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Energy Dispersive ◽  
X Ray Diffraction ◽  
X Ray ◽  
Metal Organic ◽  
Flexible Metal ◽  
Organic Framework

scholarly journals Twinning in Zr-Based Metal-Organic Framework Crystals

Chemistry ◽  
2020 ◽  
Vol 2 (3) ◽  
pp. 777-786
Author(s):  
Sigurd Øien-Ødegaard ◽  
Karl Lillerud
Keyword(s):  
Crystal Structures ◽  
Metal Organic Framework ◽  
Special Importance ◽  
X Ray Diffraction ◽  
X Ray ◽  
Metal Organic ◽  
Ab Initio Structure ◽  
Crystal Twinning ◽  
Organic Framework

Ab initio structure determination of new metal-organic framework (MOF) compounds is generally done by single crystal X-ray diffraction, but this technique can yield incorrect crystal structures if crystal twinning is overlooked. Herein, the crystal structures of three Zirconium-based MOFs, that are especially prone to twinning, have been determined from twinned crystals. These twin laws (and others) could potentially occur in many MOFs or related network structures, and the methods and tools described herein to detect and treat twinning could be useful to resolve the structures of affected crystals. Our results highlight the prevalence (and sometimes inevitability) of twinning in certain Zr-MOFs. Of special importance are the works of Howard Flack which, in addition to fundamental advances in crystallography, provide accessible tools for inexperienced crystallographers to take twinning into account in structure elucidation.

Guest Adsorption in the Nanoporous Metal–Organic Framework Cu3(1,3,5-Benzenetricarboxylate)2: Combined In Situ X-ray Diffraction and Vapor Sorption

2014 ◽  
Vol 26 (16) ◽  
pp. 4712-4723 ◽  
Author(s):  
Vanessa K. Peterson ◽  
Peter D. Southon ◽  
Gregory J. Halder ◽  
David J. Price ◽  
Joseph J. Bevitt ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Vapor Sorption ◽  
X Ray Diffraction ◽  
X Ray ◽  
Nanoporous Metal ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Time-Resolved In Situ X-ray Diffraction Reveals Metal-Dependent Metal-Organic Framework Formation

2016 ◽  
Vol 55 (45) ◽  
pp. 14081-14084 ◽  
Author(s):  
Yue Wu ◽  
Sebastian Henke ◽  
Gregor Kieslich ◽  
Inke Schwedler ◽  
Miaosen Yang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
X Ray Diffraction ◽  
Time Resolved ◽  
X Ray ◽  
Metal Organic ◽  
Organic Framework
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