High‐Δnoptical waveguides in LiNbO3: Thallium‐lithium ion exchange

1980 ◽  
Vol 37 (8) ◽  
pp. 739-741 ◽  
Author(s):  
Janet Jackel
Keyword(s):  
Crystals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 293
Author(s):  
Liangzhu Zhu ◽  
Anil V. Virkar

Na-β″-alumina (Na2O.~6Al2O3) is known to be an excellent sodium ion conductor in battery and sensor applications. In this study we report fabrication of Na- β″-alumina + YSZ dual phase composite to mitigate moisture and CO2 corrosion that otherwise can lead to degradation in pure Na-β″-alumina conductor. Subsequently, we heat-treated the samples in molten AgNO3 and LiNO3 to respectively form Ag-β″-alumina + YSZ and Li-β″-alumina + YSZ to investigate their potential applications in silver- and lithium-ion solid state batteries. Ion exchange fronts were captured via SEM and EDS techniques. Their ionic conductivities were measured using electrochemical impedance spectroscopy. Both ion exchange rates and ionic conductivities of these composite ionic conductors were firstly reported here and measured as a function of ion exchange time and temperature.


2018 ◽  
Vol 8 (11) ◽  
pp. 2252 ◽  
Author(s):  
Wei-Sheng Chen ◽  
Cheng-Han Lee ◽  
Hsing-Jung Ho

Purification of lithium carbonate, in the battery industry, is an important step in the future. In this experiment, the waste lithium-ion batteries were crushed, sieved, leached with sulfuric acid, eluted with an extractant, and finally sulphate solutions were extracted, through selective precipitation. Next, sodium carbonate was first added to the sulphate solutions, to precipitate lithium carbonate (Li2CO3). After that, lithium carbonate was put into the water to create lithium carbonate slurry and CO2 was added to it. The aeration of CO2 and the hydrogenation temperature were controlled, in this experiment. Subsequently, Dowex G26 resin was used to remove impurities, such as the calcium and sodium in lithium carbonate. Moreover, the adsorption isotherms, described by means of the Langmuir and Freundlich isotherms, were used to investigate the ion-exchange behaviors of impurities. After removing the impurities, the different heating rate was controlled to obtain lithium carbonate. In a nutshell, this study showed the optimum condition of CO2 aeration, hydrogenation temperature, ion-exchange resin and the heating rate to get high yields and purity of lithium carbonate.


2016 ◽  
Vol 216 ◽  
pp. 94-101 ◽  
Author(s):  
Wenming Liao ◽  
Jianhua Tian ◽  
Zhongqiang Shan ◽  
Ren Na ◽  
Lan Cui ◽  
...  

2005 ◽  
Vol 21 (07) ◽  
pp. 782-785
Author(s):  
LOU Tai-ping ◽  
◽  
LI Da-gang ◽  
DAI Hou-chen ◽  
TANG Shu-huan ◽  
...  

2006 ◽  
Vol 972 ◽  
Author(s):  
Natasha A. Chernova ◽  
Miaomiao Ma ◽  
Jie Xiao ◽  
M. Stanley Whittingham ◽  
Jordi Cabana Jiménez ◽  
...  

AbstractThe magnetic properties of layered LiNi0.5Mn0.5O2 and NaNi0.5Mn0.5O2 cathode materials are studied using AC susceptibility and DC magnetization techniques in order to elucidate magnetic interactions within transition metal (TM) layers and between them in samples with various TM distributions. In NaNi0.5Mn0.5O2 antiferromagnetic (AF) ordering transition is found at 60 K and a spin-flop transition at high magnetic field. In LiNi0.5Mn0.5O2 obtained by ion exchange from NaNi0.5Mn0.5O2 ferrimagnetic ordering is found at around 100 K. The saturation magnetization and the hysteresis loop size of ion-exchanged compounds vary from sample to sample, which implies that the Ni2+ ions migrate upon ion exchange process. Magnetic properties of high-temperature and ion-exchanged LiNi0.5Mn0.5O2 are compared; magnetic ordering models for all compounds are proposed based on experimental results and Goodenough-Kanamori rules.


2019 ◽  
Vol 302 ◽  
pp. 363-372 ◽  
Author(s):  
Wenming Liao ◽  
Wanfei Li ◽  
Jianhua Tian ◽  
Qingbo Xiao ◽  
Mimi Dai ◽  
...  

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