Evaluated Kinetic Data for High‐Temperature Reactions. Volume 5. Part 1. Homogeneous Gas Phase Reactions of the Hydroxyl Radical with Alkanes

1986 ◽  
Vol 15 (2) ◽  
pp. 465-592 ◽  
Author(s):  
D. L. Baulch ◽  
M. Bowers ◽  
D. G. Malcolm ◽  
R. T. Tuckerman
Keyword(s):  
High Temperature ◽  
Hydroxyl Radical ◽  
Gas Phase ◽  
Kinetic Data ◽  
Gas Phase Reactions ◽  
High Temperature Reactions

The reactions of O(3P) with the butanols

1983 ◽  
Vol 61 (12) ◽  
pp. 2716-2720 ◽  
Author(s):  
John M. Roscoe
Keyword(s):  
Free Energy ◽  
Gas Phase ◽  
Rate Constants ◽  
Substrate Concentration ◽  
Kinetic Data ◽  
Absolute Rate ◽  
Gas Phase Reactions ◽  
Linear Free Energy ◽  
Different Types ◽  
Energy Relations

The reactions of O(3P) with the butanols were studied kinetically as a function of temperature and substrate concentration. The absolute rate constants for the gas phase reactions, in the units M−1 s−1, obey the following relations.[Formula: see text]The results suggest that although the α-CH bond in these alcohols is the most reactive one, reaction of O(3P) with other CH bonds in the alcohols is also appreciable. The kinetic data for these and other alcohols are separated into contributions from the different types of CH bonds and the results are discussed in terms of linear free energy relations.

scholarly journals Evaluated kinetic and photochemical data for atmospheric chemistry: Volume III – gas phase reactions of inorganic halogens

2007 ◽  
Vol 7 (4) ◽  
pp. 981-1191 ◽  
Author(s):  
R. Atkinson ◽  
D. L. Baulch ◽  
R. A. Cox ◽  
J. N. Crowley ◽  
R. F. Hampson ◽  
...  
Keyword(s):  
Kinetic Parameters ◽  
Gas Phase ◽  
Atmospheric Chemistry ◽  
Kinetic Data ◽  
Photochemical Reactions ◽  
Gas Phase Reactions ◽  
The Third ◽  
Summary Sheet ◽  
Present Evaluation ◽  
Halogen Species

Abstract. This article, the third in the series, presents kinetic and photochemical data evaluated by the IUPAC Subcommittee on Gas Kinetic Data Evaluation for Atmospheric Chemistry. It covers the gas phase and photochemical reactions of inorganic halogen species, which were last published in J. Phys. Chem. Ref. Data, in 2000 (Atkinson et al., 2000), were updated on the IUPAC website in 2003 and are updated again in the present evaluation. The article consists of a summary sheet, containing the recommended kinetic parameters for the evaluated reactions, and five appendices containing the data sheets, which provide information upon which the recommendations were made.

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