Spectroscopic characterization of the first excited state and photochemistry of the HO3 radical

2020 ◽  
Vol 152 (6) ◽  
pp. 064304 ◽  
Author(s):  
Tarek Trabelsi ◽  
Joseph S. Francisco
2007 ◽  
Vol 11 (06) ◽  
pp. 442-447 ◽  
Author(s):  
Christian Ehli ◽  
Stéphane Campidelli ◽  
Fulvio G. Brunetti ◽  
Maurizio Prato ◽  
Dirk M. Guldi

We describe the synthesis, microscopic and spectroscopic characterization of a novel donor-acceptor prototype, namely, a single wall carbon nanotube (SWNT) nanoconjugate bearing a covalently linked free base porphyrin ( H 2 P ). In the characterized SWNT- H 2 P nanoconjugate the electronic features of SWNT are largely retained, when compared to pristine SWNT. In fact, carefully controlled reaction conditions lead to a low degree of SWNT functionalization, as evidenced by the preservation of the SWNT van Hove singularities. As a consequence, the overall SWNT loading with H 2 P is so low that in the ground state, the H 2 P features are barely seen, which is different from the excited state, where features of H 2 P are clearly discernable. For example, fluorescence and transient absorption characteristics corroborate, unequivocally, the formation of the H 2 P singlet excited state, which is, however, impacted by the presence of SWNT.


2004 ◽  
Vol 380 (1-2) ◽  
pp. 352-356 ◽  
Author(s):  
P. Gawryszewska ◽  
G. Oczko ◽  
J.P. Riehl ◽  
V. Tsaryuk ◽  
J. Legendziewicz

2003 ◽  
Vol 119 (19) ◽  
pp. 10169-10174 ◽  
Author(s):  
D. Bellert ◽  
D. K. Winn ◽  
W. H. Breckenridge

2001 ◽  
Vol 74 (6) ◽  
pp. 794 ◽  
Author(s):  
Antoine Royant ◽  
Karl Edman ◽  
Thomas Ursby ◽  
Eva Pebay-Peyroula ◽  
Ehud. M. Landau ◽  
...  

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