Mutual solubility of substitutional alloy and pure crystal

2019 ◽  
Author(s):  
K. I. Borodin ◽  
V. A. Volkov
Keyword(s):  
Mutual Solubility ◽  
Pure Crystal ◽  
Substitutional Alloy

The effect of systematic errors of the equilibrium distribution concentrations on the number of stages of countercurrent extraction with various consumption of extractant

1989 ◽  
Vol 54 (4) ◽  
pp. 981-989
Author(s):  
Ján Dojčanský ◽  
Soňa Bafrncová ◽  
Július Surový
Keyword(s):  
Equilibrium Distribution ◽  
Systematic Errors ◽  
Mutual Solubility ◽  
Operating Conditions ◽  
Liquid Equilibrium ◽  
Countercurrent Extraction ◽  
Absolute Deviation ◽  
Line Slope ◽  
Tie Line ◽  
Calculated Number

On using five hypothetical systems differing in the extent of mutual solubility of components, tie-line slope, and type of binodal curve, the effect is evaluated of systematic errors in the form of absolute deviation in the liquid-liquid equilibrium distribution concentrations on the accuracy of calculated number of theoretical stages of isothermal countercurrent extraction under various operating conditions.

Diffusive layering during film growth in two-component systems with limited mutual solubility

2000 ◽  
Author(s):  
Grigory V. Merkulov ◽  
Valentin M. Ievlev ◽  
Evgeny V. Shvedov ◽  
Vadim P. Ampilogov
Keyword(s):  
Film Growth ◽  
Mutual Solubility ◽  
Component Systems ◽  
Two Component ◽  
Two Component Systems

scholarly journals Mutual Solubility of Pyridine Base-Water-Salt System

1958 ◽  
Vol 78 (8) ◽  
pp. 837-841 ◽  
Author(s):  
Sozaburo Arakawa ◽  
Taro Kawaguchi ◽  
Hiromasa Kato
Keyword(s):  
Mutual Solubility ◽  
Salt System ◽  
Pyridine Base ◽  
Water Salt

Theoretical Study of the Local Lattice Distortion at the Trigonal Cr3+ Center in BiI3

2006 ◽  
Vol 61 (1-2) ◽  
pp. 78-82 ◽  
Author(s):  
Shao-Yi Wu ◽  
Xiu-Ying Gao ◽  
Hui-Ning Dong
Keyword(s):  
Lattice Distortion ◽  
Theoretical Study ◽  
Impurity Center ◽  
Cluster Approach ◽  
Pure Crystal ◽  
Local Lattice Distortion ◽  
Trigonal Symmetry ◽  
Local Lattice ◽  
Epr Parameters ◽  
Local Angle

The local lattice distortion at the trigonal Cr3+ center in BiI3 is theoretically studied by the perturbation formulas of the EPR parameters for a 3d3 ion in trigonal symmetry, based on the cluster approach. In these formulas the contributions from the s-orbitals of the ligands, which were often ignored, are taken into account. It is found that the local angle β (between the direction of the impurityligand bonding R and the C3 axis) in the impurity center is smaller than the host angle βH in the pure crystal. The calculated EPR parameters are improved compared to those in absence of the ligand s-orbital contributions. The local lattice distortion obtained in this work is discussed.

scholarly journals Deformation twinning and the role of amino acids and magnesium in calcite hardness from molecular simulation

2015 ◽  
Vol 17 (31) ◽  
pp. 20178-20184 ◽  
Author(s):  
A. S. Côté ◽  
R. Darkins ◽  
D. M. Duffy
Keyword(s):  
Molecular Dynamics ◽  
Amino Acids ◽  
Molecular Simulation ◽  
Elastic Properties ◽  
Deformation Twinning ◽  
Pure Crystal ◽  
Classical Molecular Dynamics ◽  
Deformation Twins

We employ classical molecular dynamics to calculate elastic properties and to model the nucleation and propagation of deformation twins in calcite, both as a pure crystal and with magnesium and aspartate inclusions.

Mechanisms of Thermo-Solutal Transport and Segregation in High-Pressure Liquid-Encapsulated Czochralski Crystal Growth

1999 ◽  
Vol 121 (1) ◽  
pp. 148-159 ◽  
Author(s):  
Y. F. Zou ◽  
G.-X. Wang ◽  
H. Zhang ◽  
V. Prasad
Keyword(s):  
Boundary Layer ◽  
High Pressure ◽  
Natural Convection ◽  
Driving Forces ◽  
Axisymmetric Flow ◽  
Melt Flow ◽  
Pure Crystal ◽  
Radial Segregation ◽  
Crystal Rotation ◽  
Crucible Rotation

The mechanism of dopant transport and segregation in high-pressure liquid-encapsulated Czochralski (HPLEC) grown III-V compound crystals (e.g., GaAs, InP) has been numerically studied using an integrated model, MASTRAPP. The model approximates the melt flow in the crucible as a quasi-steady-state, laminar, and axisymmetric flow, but the gas flow is considered as turbulent. Based on the physics of the growth process, a two-time-level scheme has been implemented where the dopant transport and growth are simulated at a smaller time scale while flow and temperature solutions are obtained from quasi-static calculations. Detailed numerical analyses are performed for the conditions of pure crystal rotation, pure thermally driven natural convection, and pure crucible rotation as well as for mixed flow with all of these forces present simultaneously. The dopant transport and segregation in these cases are well correlated to the corresponding melt flow pattern. Very weak radial segregation is predicted for pure crystal rotation because the resulting melt flow leads to a fairly flat solute boundary layer. The natural convection, on the other hand, produces a nonuniform boundary layer along the melt/crystal interface. This leads to a strong radial segregation with a high concentration along the central axis of the crystal. The crucible rotation has a similar effect. The combined effect of all of these flow mechanisms produces a strong radial segregation, whose extent depends on the relative strength of the driving forces. In all of these cases, strong melt flows lead to thin boundary layers that result in decreased longitudinal segregation. The predictions agree well with the experimental observations reported in the literature.

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