Carrier accumulation enhanced Auger recombination and inner self-heating-induced spectrum fluctuation in CsPbBr3 perovskite nanocrystal light-emitting devices

2019 ◽  
Vol 115 (24) ◽  
pp. 243503 ◽  
Author(s):  
Wenhui Wu ◽  
Yumeng Zhang ◽  
Tianyuan Liang ◽  
Jiyang Fan
Keyword(s):  
Auger Recombination ◽  
Light Emitting ◽  
Light Emitting Devices ◽  
Self Heating ◽  
Inner Self

scholarly journals Excitation Wavelength and Intensity-Dependent Multiexciton Dynamics in CsPbBr3 Nanocrystals

Nanomaterials ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 463
Author(s):  
Chaochao Qin ◽  
Zhinan Jiang ◽  
Zhongpo Zhou ◽  
Yufang Liu ◽  
Yuhai Jiang
Keyword(s):  
Auger Recombination ◽  
Transient Absorption ◽  
Photoluminescence Spectroscopy ◽  
Transient Absorption Spectroscopy ◽  
Excitation Wavelength ◽  
Time Resolved ◽  
Recombination Lifetime ◽  
Light Emitting ◽  
Light Emitting Devices ◽  
Femtosecond Transient Absorption

CsPbBr3 has attracted great attention due to unique optical properties. The understanding of the multiexciton process is crucial for improving the performance of the photoelectric devices based on CsPbBr3 nanocrystals. In this paper, the ultrafast dynamics of CsPbBr3 nanocrystals is investigated by using femtosecond transient absorption spectroscopy. It is found that Auger recombination lifetime increases with the decrease of the excitation intensity, while the trend is opposite for the hot-exciton cooling time. The time of the hot-carriers cooling to the band edge is increased when the excitation energy is increased from 2.82 eV (440 nm) to 3.82 eV (325 nm). The lifetime of the Auger recombination reaches the value of 126 ps with the excitation wavelength of 440 nm. The recombination lifetime of the single exciton is about 7 ns in CsPbBr3 nanocrystals determined by nanosecond time-resolved photoluminescence spectroscopy. The exciton binding energy is 44 meV for CsPbBr3 nanocrystals measured by the temperature-dependent steady-state photoluminescence spectroscopy. These findings provide a favorable insight into applications such as solar cells and light-emitting devices based on CsPbBr3 nanocrystals.

Heterostructures based on nitrides of group III elements: technical processes, properties, and light-emitting devices

2001 ◽  
Vol 171 (8) ◽  
pp. 857 ◽  
Author(s):  
Igor L. Krestnikov ◽  
V.V. Lundin ◽  
A.V. Sakharov ◽  
D.A. Bedarev ◽  
E.E. Zavarin ◽  
...  
Keyword(s):  
Light Emitting ◽  
Group Iii ◽  
Light Emitting Devices

Probing local photophysical properties in perovskite based light-emitting devices

2019 ◽  
Author(s):  
Miguel Anaya ◽  
Kyle Frohna ◽  
Linsong Cui ◽  
Javad Shamsi ◽  
Sam Stranks
Keyword(s):  
Photophysical Properties ◽  
Light Emitting ◽  
Light Emitting Devices

Color Variable Bipolar/AC Light-Emitting Devices Based on Conjugated Polymers

1997 ◽  
Author(s):  
Y. Z. Wang ◽  
D. D. Gebler ◽  
D. K. Fu ◽  
T. M. Swager ◽  
A. J. Epstein
Keyword(s):  
Conjugated Polymers ◽  
Light Emitting ◽  
Light Emitting Devices

scholarly journals Exciton Coupling and Conformational Changes Impacting the Excited State Properties of Metal Organic Frameworks

Molecules ◽  
2020 ◽  
Vol 25 (18) ◽  
pp. 4230
Author(s):  
Andreas Windischbacher ◽  
Luca Steiner ◽  
Ritesh Haldar ◽  
Christof Wöll ◽  
Egbert Zojer ◽  
...  
Keyword(s):  
Conformational Changes ◽  
Photophysical Properties ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Red Shift ◽  
Light Emitting ◽  
Light Emitting Devices ◽  
Exciton Coupling ◽  
Metal Organic ◽  
Crystalline Metal

In recent years, the photophysical properties of crystalline metal-organic frameworks (MOFs) have become increasingly relevant for their potential application in light-emitting devices, photovoltaics, nonlinear optics and sensing. The availability of high-quality experimental data for such systems makes them ideally suited for a validation of quantum mechanical simulations, aiming at an in-depth atomistic understanding of photophysical phenomena. Here we present a computational DFT study of the absorption and emission characteristics of a Zn-based surface-anchored metal-organic framework (Zn-SURMOF-2) containing anthracenedibenzoic acid (ADB) as linker. Combining band-structure and cluster-based simulations on ADB chromophores in various conformations and aggregation states, we are able to provide a detailed explanation of the experimentally observed photophysical properties of Zn-ADB SURMOF-2: The unexpected (weak) red-shift of the absorption maxima upon incorporating ADB chromophores into SURMOF-2 can be explained by a combination of excitonic coupling effects with conformational changes of the chromophores already in their ground state. As far as the unusually large red-shift of the emission of Zn-ADB SURMOF-2 is concerned, based on our simulations, we attribute it to a modification of the exciton coupling compared to conventional H-aggregates, which results from a relative slip of the centers of neighboring chromophores upon incorporation in Zn-ADB SURMOF-2.

Cs0.05(FA0.85MA0.15)0.95Pb(I0.85Br0.15)3 based flexible perovskite light-emitting devices with excellent mechanical bending durability

2019 ◽  
Vol 723 ◽  
pp. 33-38 ◽  
Author(s):  
Minhuan Wang ◽  
Yulin Feng ◽  
Qingshun Dong ◽  
Jiming Bian ◽  
Chen Wang ◽  
...  
Keyword(s):  
Light Emitting ◽  
Light Emitting Devices ◽  
Mechanical Bending

The study of intramolecular decay and intermolecular energy transfer for phosphorescent organic light-emitting devices

2021 ◽  
Vol 23 (12) ◽  
pp. 7495-7503
Author(s):  
Wanlin Cai ◽  
Kai Ren ◽  
Ancong Zhao ◽  
Xiulan Wu ◽  
Rongxing He ◽  
...  
Keyword(s):  
Energy Transfer ◽  
Rational Design ◽  
Energy Transfer Efficiency ◽  
Transfer Efficiency ◽  
Light Emitting ◽  
Light Emitting Devices ◽  
Organic Light ◽  
Intermolecular Energy ◽  
Intermolecular Energy Transfer ◽  
Organic Light Emitting Devices

Compared to the PtOO7-based system, the greater EQE of the PtON7-based system is mainly governed by the stronger energy transfer efficiency (ηEET); thus, it is necessary to evaluate ηEET from hosts to guests for the rational design of OLEDs.

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