Anomalous behaviors of elastic constants of lead-free piezoelectric (Na1/2Bi1/2)TiO3-5%BaTiO3 single crystals studied by Brillouin spectroscopy

2019 ◽  
Vol 126 (17) ◽  
pp. 174103
Author(s):  
Byoung Wan Lee ◽  
Jeong Woo Lee ◽  
Jae-Hyeon Ko ◽  
Xiaobing Li ◽  
Haosu Luo
Keyword(s):  
Single Crystals ◽  
Elastic Constants ◽  
Lead Free ◽  
Brillouin Spectroscopy

Elastic and photo-elastic constants of CH4 and CD4 obtained by Brillouin scattering

1982 ◽  
Vol 60 (3) ◽  
pp. 287-298 ◽  
Author(s):  
S. C. Rand ◽  
B. P. Stoicheff
Keyword(s):  
High Resolution ◽  
Single Crystals ◽  
Elastic Constants ◽  
Brillouin Scattering ◽  
Low Frequency ◽  
Mass Ratio ◽  
Translational Coupling ◽  
Brillouin Spectroscopy ◽  
Transverse Modes ◽  
Triple Points

The elastic constants and Pockels coefficients of CH4 and CD4 single crystals near their triple points have been determined using high-resolution Brillouin spectroscopy. For CH4 at 90.4 K, the elastic constants are C11 = 19.57 ± 0.30, C12 = 14.46 ± 0.20, C44 = 9.20 ± 0.15 kbar, and the ratios of the Pockels coefficients are p12/p11 = 1.031 ± 0.035 and p44/p11 = 0.069 ± 0.010. For CD4 at 89.2 K, C12 = 20.04 ± 0.30, C12 = 15.00 ± 0.25, C44 = 9.15 ± 0.15 kbar, and p12/p11 = 1.027 ± 0.020, P44/p11 = 0.138 ± 0.010. The velocities of the low-frequency transverse modes in CH4 and CD4 are anomalously slow in the [Formula: see text] direction, indicative of rotational–translational coupling of molecules. Isotopic differences are also evident: the Pockels coefficient p44 in CD4 is double that in CH4; and the velocities of both transverse modes in the principle directions [Formula: see text], [Formula: see text], and [Formula: see text] are in the ratio V(CH4)/V(CD4) = 1.130 instead of 1.118 as expected from the isotopic mass ratio.

scholarly journals Lead-free halide perovskite Cs3Bi2Br9 single crystals for high-performance X-ray detection

2021 ◽  
Author(s):  
Xiang Li ◽  
Xinyuan Du ◽  
Peng Zhang ◽  
Yunqiu Hua ◽  
Lin Liu ◽  
...  
Keyword(s):  
Single Crystals ◽  
High Performance ◽  
Lead Free ◽  
X Ray ◽  
Halide Perovskite

Temperature-induced phase transition of -oriented 0.92Na0.5Bi0.5TiO3-0.08Bi(Zn0.5Ti0.5)O3 lead-free single crystals

2021 ◽  
Author(s):  
Junjie Xiao ◽  
Sixing Liu ◽  
Jushan Wang ◽  
Jialin Xu ◽  
Zhang Zhang ◽  
...  
Keyword(s):  
Phase Transition ◽  
Single Crystals ◽  
Lead Free

All‐Inorganic Lead‐Free Perovskite(‐Like) Single Crystals: Synthesis, Properties, and Applications

Small Methods ◽  
2021 ◽  
pp. 2001308
Author(s):  
Shuangyi Zhao ◽  
Wensi Cai ◽  
Huaxin Wang ◽  
Zhigang Zang ◽  
Jiangzhao Chen
Keyword(s):  
Single Crystals ◽  
Lead Free ◽  
Inorganic Lead ◽  
Synthesis Properties

Investigation of the domain structure and hierarchy in potassium–sodium niobate lead-free piezoelectric single crystals

RSC Advances ◽  
2016 ◽  
Vol 6 (54) ◽  
pp. 49060-49067 ◽  
Author(s):  
Micka Bah ◽  
Natalya Alyabyeva ◽  
Richard Retoux ◽  
Fabien Giovannelli ◽  
Mustapha Zaghrioui ◽  
...  
Keyword(s):  
Single Crystals ◽  
Domain Structure ◽  
Lead Free ◽  
Nanometer Scale ◽  
Sodium Niobate ◽  
Potassium Sodium Niobate ◽  
Length Scales ◽  
Potassium Sodium ◽  
Domain Structures ◽  
Self Organized

We reported self-organized and hierarchized domain structures on various length scales ranging from micrometer to nanometer scale in K0.5Na0.5NbO3 crystals.

The Characteristic of the La3Ga5SiO14 Single Crystal Grown by Vertical Bridgman Method in Ar Atmosphere

2006 ◽  
Vol 510-511 ◽  
pp. 842-845 ◽  
Author(s):  
Noriko Bamba ◽  
Kentaro Kato ◽  
Toshinori Taishi ◽  
Takayuki Hayashi ◽  
Keigo Hoshikawa ◽  
...  
Keyword(s):  
Melting Point ◽  
Single Crystal ◽  
Single Crystals ◽  
Room Temperature ◽  
Color Change ◽  
Piezoelectric Materials ◽  
Lead Free ◽  
Piezoelectric Constant ◽  
Interstitial Oxygen ◽  
Vertical Bridgman

Langasite (La3Ga5SiO14: denoted by LGS) single crystal is one of the lead free piezoelectric materials with high piezoelectricity that is maintained up to its melting point (1470°C). Although LGS single crystals have usually been grown by Czochralski (CZ) method in oxygen contained atmosphere to prevent evaporation of Ga, they were grown by the vertical Bridgman (VB) method in Ar atmosphere without oxygen, and their properties were evaluated in this work. Transparent and colorless LGS single crystals were successfully obtained without Ga evaporation by the VB method in Ar atmosphere, and their resistivity at room temperature was much higher than that grown by conventional CZ method. Piezoelectric constant d11 of the crystal grown by the VB method was 6 x 10-12 C/N, which was close to that of the crystal grown by CZ method. The colorless transparent LGS single crystal turned to orange and its resistivity decreased by annealing in air. Since an orange-colored transparent LGS single crystal has been grown by conventional CZ method, this indicates that color change and the resistivity decrease of LGS crystal is caused by extra interstitial oxygen atoms in the crystal.

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