Features of nonstationary combustion of double hydrate (methane - n-propanol) in air atmosphere

2019 ◽  
Author(s):  
Yu. Yu. Bozhko ◽  
I. S. Voytkov
Keyword(s):  
Nonstationary Combustion ◽  
Air Atmosphere

ON THE MECHANISMS OF POROUS SILICON COMBUSTION IN OXYGEN AND AIR ATMOSPHERE WHEN SODIUM PERCHLORATE IS INCORPORATED IN PORES

2020 ◽  
Author(s):  
V. N. MIRONOV ◽  
◽  
O. G. PENYAZKOV ◽  
P. N. KRIVOSHEYEV ◽  
I. A. IVANOV ◽  
...  
Keyword(s):  
Porous Silicon ◽  
Porous Layer ◽  
Sodium Perchlorate ◽  
Spark Ignition ◽  
Joule Heat ◽  
Air Atmosphere ◽  
Breakdown Region ◽  
Ignition And Combustion ◽  
Heating Up

The processes of pSi ignition and combustion in oxygen are described. When spark ignition in the porous layer releases the Joule heat, it leads to a significant heating-up of the breakdown region.

Regularities of Structural and Morphological Changes of Nanosystems Based on Zn Conden-sates at their Oxidation in Air Atmosphere

2018 ◽  
Vol 10 (1) ◽  
pp. 01021-1-01021-5 ◽  
Author(s):  
A. S. Kornyushchenko ◽  
◽  
Yu. A. Rybalko ◽  
V. I. Perekrestov ◽  
◽  
...  
Keyword(s):  
Morphological Changes ◽  
Air Atmosphere ◽  
Oxidation In Air

Catalyst-free synthesis of 3,1-benzoxathiin-4-ones/1,3-benzodioxin-4-ones

2021 ◽  
Vol 19 (7) ◽  
pp. 1508-1513
Author(s):  
Sengodagounder Muthusamy ◽  
Muthukumar Malarvizhi ◽  
Eringathodi Suresh
Keyword(s):  
Precise Method ◽  
Propargylic Alcohols ◽  
Catalyst Free ◽  
Air Atmosphere

An unambiguous and precise method for the synthesis of 3,1-benzoxathiin-4-ones/1,3-benzodioxin-4-ones by the reaction of propargylic alcohols and salicylic/thiosalicylic acids under a catalyst-free and open-air atmosphere is described.

scholarly journals Isothermal Kinetic Analysis of the Thermal Decomposition of Wood Chips from an Apple Tree

Processes ◽  
2021 ◽  
Vol 9 (2) ◽  
pp. 195
Author(s):  
Ivan Vitázek ◽  
Martin Šotnar ◽  
Stella Hrehová ◽  
Kristína Darnadyová ◽  
Jan Mareček
Keyword(s):  
Thermal Decomposition ◽  
Apple Tree ◽  
Combustion Process ◽  
Reaction Model ◽  
Wood Chips ◽  
Small Scale ◽  
Exponential Factor ◽  
Air Atmosphere ◽  
First Order Chemical Reaction ◽  
Isothermal Kinetic

The thermal decomposition of wood chips from an apple tree is studied in a static air atmosphere under isothermal conditions. Based on the thermogravimetric analysis, the values of the apparent activation energy and pre-exponential factor are 34 ± 3 kJ mol−1 and 391 ± 2 min−1, respectively. These results have also shown that this process can be described by the rate of the first-order chemical reaction. This reaction model is valid only for a temperature range of 250–290 °C, mainly due to the lignin decomposition. The obtained results are used for kinetic prediction, which is compared with the measurement. The results show that the reaction is slower at higher values of degree of conversion, which is caused by the influence of the experimental condition. Nevertheless, the obtained kinetic parameters could be used for the optimization of the combustion process of wood chips in small-scale biomass boilers.

Porphyrin-Catalyzed Oxidation of N-Substituted Tetrahydroisoquinolines to Dihydroisoquinolones

Synlett ◽  
2021 ◽  
Author(s):  
Ao Li ◽  
Bin Pan ◽  
Mu Chao ◽  
Na Wang ◽  
Yu-Long Li ◽  
...  
Keyword(s):  
Visible Light ◽  
Room Temperature ◽  
Air Atmosphere ◽  
Wide Range ◽  
Convenient Route ◽  
Catalyzed Oxidation

A visible-light-induced direct α-oxygenation of N-substituted tetrahydroisoquinoline derivatives has been successfully developed. Metalloporphyrin (ZnTPP) has been identified as an effective and inexpensive photocatalyst for this transformation with a wide range of substrates. This protocol provides a convenient route to afford the desired products in moderate to good yields at room temperature under air atmosphere.

scholarly journals Experimental validation of the reaction mechanism models of dechlorination and [Zn] reclaiming in the roasting steelmaking zinc-rich dust process

2020 ◽  
Vol 39 (1) ◽  
pp. 107-116
Author(s):  
Hongyang Wang ◽  
Kai Dong ◽  
Rong Zhu
Keyword(s):  
Reaction Mechanism ◽  
Dust Particle ◽  
Chemical Reaction ◽  
Reaction Mechanisms ◽  
Experimental Validation ◽  
Step Process ◽  
Mass Percent ◽  
Mechanism Model ◽  
Air Atmosphere ◽  
Almost All

AbstractThe reaction mechanism models of dechlorination and [Zn] reclaiming in the roasting steelmaking zincrich dust process are studied. The dust collected from a steelwork contains 63.8% zinc and 3.18% chlorine (mass percent), of which, almost all zinc elements exist in ZnO and ZnCl2 forms, and all the chlorine elements are stored in ZnCl2. When the dust is roasted at above 732∘C in an air atmosphere, the ZnCl2 in the steelmaking zinc-rich dust is volatilized into steam and then oxidized into ZnO. Finding the position where the chemical reaction occurs is the key to determining the reaction mechanisms of dechlorination and [Zn] reclaiming. In this study, two groups of thermal experiments are designed and executed for roasting in different atmosphere environments and at different roasting temperatures. Based on the experiment results, the mechanism model is discussed and built, and the reaction of dechlorination and [Zn] reclaiming is shown to be a multi-step process. Because O2 from the air cannot transmit into the dust particle interior or dust bed effectively, the chemical reaction of [Zn] reclaiming occurs in the external gas environment outside of the dust, where the [Zn] recalcining reaction should be limited by the dynamics of new nucleation of ZnO solids.

Base-Free Synthesis and Synthetic Application of Novel 3-(organochalcogenyl)prop-2-yn-1-yl Esters: Promising Anticancer Agents

Synthesis ◽  
2021 ◽  
Author(s):  
Fabiane Gritzenco ◽  
Jean Carlo Kazmierczak ◽  
Thiago Anjos ◽  
Adriane Sperança ◽  
Maura Luise Bruckchem Peixoto ◽  
...  
Keyword(s):  
Anticancer Agents ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Chalcogen Bond ◽  
Cross Coupling Reactions ◽  
Air Atmosphere ◽  
Carbon Carbon Bonds ◽  
Palladium Catalyzed ◽  
Synthetic Application

This manuscript portrays the CuI-catalyzed Csp-chalcogen bond formation through cross-coupling reactions of propynyl esters and diorganyl dichalcogenides by using DMSO as solvent, at room temperature, under base-free and open-to-air atmosphere. Generally, the reactions have proceeded very smoothly, being tolerant to range of substituents present in both substrates, affording the novel 3-(organochalcogenyl)prop-2-yn-1-yl esters in moderate to good yields. Noteworthy, the 3-(butylselanyl)prop-2-yn-1-yl benzoate proved to be useful as synthetic precursor in palladium-catalyzed Suzuki and Sonogashira type cross-coupling reactions by replacing the carbon-chalcogen bond by new carbon-carbon bonds. Moreover, the 3-(phenylselanyl)prop-2-yn-1-yl benzoate has shown promising in vitro activity against glioblastoma cancer cells.

Paper 23: The Collision of Drops with Dry and Wet Surfaces in an Air Atmosphere

1969 ◽  
Vol 184 (7) ◽  
pp. 57-63
Author(s):  
G. J. Parker ◽  
E. Bruen
Keyword(s):  
Steam Turbine ◽  
High Speed ◽  
Size Range ◽  
Drop Surface ◽  
Wet Steam ◽  
Air Atmosphere ◽  
Made In

This paper describes an investigation into the behaviour of drops which impinge upon dry and wet surfaces. This is of particular interest in the context of the wet steam turbine. Two approaches have been made in the studies; these are: (1) Drops were made to impinge normally on to various types of dry, stationary surfaces. The drops were in the size range 300–1500 μm diameter with velocities of 2–9 m/s. (2) Drops were made to impinge on to surfaces moving with considerable velocity at right angles to the motion of the drop. Surface velocities ranged up to 45 m/s. The latter study is of direct interest for the splashing of drops on turbine casings at small glancing angles, as occurs near drainage belts. Analysis of the mechanisms involved is made from the records of high-speed ciné photography.

SINGLE-STEP SYNTHESIS OF COBALT-OXIDE SHELLED NANOCARBONS

2005 ◽  
Vol 04 (04) ◽  
pp. 591-598
Author(s):  
LIHONG LIU
Keyword(s):  
Cobalt Oxide ◽  
Cobalt Complex ◽  
Single Step ◽  
Complexing Agent ◽  
Solid State Method ◽  
Shell Nanostructures ◽  
Air Atmosphere ◽  
State Method ◽  
Oxide Matrix ◽  
Carbon Core

In this paper, we report a simple solid-state method for fabricating cobalt-oxide–carbon core-shell nanostructures. With this technique, various forms of nanocarbons such as nanotubes, polyhedrons and onions can be generated via pyrolyzing cobalt–complex xerogels at 150 ~ 340°C. The thus-formed nanocarbons can be protected by cobalt-oxide matrix up to 1000°C in air atmosphere. Cobalt-oxide shelled or unshelled nanocarbons can be controlled by choosing a suitable complexing agent for the xerogel precursors. In particular, glycine has been proven to be a good complexing agent for low-temperature formation of unshelled nanocarbons and high-temperature generation of shelled nanocarbons.

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