scholarly journals Simulation of ultrafast excited-state dynamics and elastic x-ray scattering by quantum wavepacket dynamics

2019 ◽  
Vol 151 (10) ◽  
pp. 104307 ◽  
Author(s):  
Mátyás Pápai ◽  
Tamás Rozgonyi ◽  
Thomas J. Penfold ◽  
Martin M. Nielsen ◽  
Klaus B. Møller
Keyword(s):  
Excited State ◽  
X Ray ◽  
Excited State Dynamics ◽  
X Ray Scattering ◽  
Quantum Wavepacket ◽  
Wavepacket Dynamics ◽  
Ray Scattering

Time-Resolved X-ray Scattering of an Electronically Excited State in Solution. Structure of the3A2uState of Tetrakis-μ-pyrophosphitodiplatinate(II)

2009 ◽  
Vol 131 (2) ◽  
pp. 502-508 ◽  
Author(s):  
Morten Christensen ◽  
Kristoffer Haldrup ◽  
Klaus Bechgaard ◽  
Robert Feidenhans’l ◽  
Qingyu Kong ◽  
...  
Keyword(s):  
Excited State ◽  
Solution Structure ◽  
Time Resolved ◽  
X Ray ◽  
Electronically Excited State ◽  
X Ray Scattering ◽  
Electronically Excited ◽  
Ray Scattering

scholarly journals The nature of frontier orbitals under systematic ligand exchange in (pseudo-)octahedral Fe(ii) complexes

2018 ◽  
Vol 20 (44) ◽  
pp. 27745-27751 ◽  
Author(s):  
Raphael M. Jay ◽  
Sebastian Eckert ◽  
Mattis Fondell ◽  
Piter S. Miedema ◽  
Jesper Norell ◽  
...  
Keyword(s):  
Excited State ◽  
Ligand Exchange ◽  
Ligand Substitution ◽  
Frontier Orbitals ◽  
X Ray ◽  
X Ray Scattering ◽  
The Impact ◽  
Metal Ligand ◽  
Ray Scattering

The impact of ligand substitution on metal-ligand covalency and the valence excited state landscape is investigated using resonant inelastic soft X-ray scattering.

Theoretical study of the triplet excited state of PtPOP and the exciplexes M-PtPOP (M=Tl, Ag) in solution and comparison with ultrafast X-ray scattering results

2012 ◽  
Vol 393 (1) ◽  
pp. 117-122 ◽  
Author(s):  
Qingyu Kong ◽  
Kasper S. Kjaer ◽  
Kristoffer Haldrup ◽  
Stephan P.A. Sauer ◽  
Tim Brandt van Driel ◽  
...  
Keyword(s):  
Excited State ◽  
Theoretical Study ◽  
Triplet Excited State ◽  
X Ray ◽  
X Ray Scattering ◽  
Ray Scattering

Structure of a short-lived excited state trinuclear Ag–Pt–Pt complex in aqueous solution by time resolved X-ray scattering

2010 ◽  
Vol 12 (26) ◽  
pp. 6921 ◽  
Author(s):  
Morten Christensen ◽  
Kristoffer Haldrup ◽  
Kasper S. Kjær ◽  
Marco Cammarata ◽  
Michael Wulff ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Excited State ◽  
Time Resolved ◽  
X Ray ◽  
Pt Complex ◽  
X Ray Scattering ◽  
Ray Scattering

Nuclear dynamics in the core-excited state of aqueous ammonia probed by resonant inelastic soft x-ray scattering

2011 ◽  
Vol 84 (10) ◽  
Author(s):  
L. Weinhardt ◽  
M. Weigand ◽  
O. Fuchs ◽  
M. Bär ◽  
M. Blum ◽  
...  
Keyword(s):  
Excited State ◽  
Aqueous Ammonia ◽  
Nuclear Dynamics ◽  
X Ray ◽  
The Core ◽  
X Ray Scattering ◽  
Ray Scattering

scholarly journals Time-resolved X-ray scattering of an electronically excited state in metal complexes in solution

2008 ◽  
Vol 64 (a1) ◽  
pp. C140-C140
Author(s):  
M.M. Nielsen ◽  
M. Christensen ◽  
K. Haldrup ◽  
N. Harrit ◽  
R. Feidenhans'l ◽  
...  
Keyword(s):  
Excited State ◽  
Metal Complexes ◽  
Time Resolved ◽  
X Ray ◽  
Electronically Excited State ◽  
X Ray Scattering ◽  
Electronically Excited ◽  
Ray Scattering

Microtubule nucleation sequence studied by time-resolved x-ray scattering and electron microscopy

1983 ◽  
Vol 41 ◽  
pp. 766-767
Author(s):  
Eva-Maria Mandelkow ◽  
Eckhard Mandelkow ◽  
Joan Bordas
Keyword(s):  
Electron Microscopy ◽  
Dynamic Equilibrium ◽  
Time Resolved ◽  
X Ray ◽  
Additional Information ◽  
X Ray Scattering ◽  
Low Concentrations ◽  
Microtubule Growth ◽  
Ray Patterns ◽  
Ray Scattering

When a solution of microtubule protein is changed from non-polymerising to polymerising conditions (e.g. by temperature jump or mixing with GTP) there is a series of structural transitions preceding microtubule growth. These have been detected by time-resolved X-ray scattering using synchrotron radiation, and they may be classified into pre-nucleation and nucleation events. X-ray patterns are good indicators for the average behavior of the particles in solution, but they are difficult to interpret unless additional information on their structure is available. We therefore studied the assembly process by electron microscopy under conditions approaching those of the X-ray experiment. There are two difficulties in the EM approach: One is that the particles important for assembly are usually small and not very regular and therefore tend to be overlooked. Secondly EM specimens require low concentrations which favor disassembly of the particles one wants to observe since there is a dynamic equilibrium between polymers and subunits.

Time-Resolved Cryo-Electron Microscopy of Oscillating Microtubules

1990 ◽  
Vol 48 (1) ◽  
pp. 502-503
Author(s):  
Eva-Maria Mandelkow ◽  
Ron Milligan
Keyword(s):  
Electron Microscopy ◽  
Dynamic Instability ◽  
Entire Solution ◽  
Reaction Scheme ◽  
Time Resolved ◽  
X Ray ◽  
X Ray Scattering ◽  
A Chain ◽  
Ray Scattering

Microtubules form part of the cytoskeleton of eukaryotic cells. They are hollow libers of about 25 nm diameter made up of 13 protofilaments, each of which consists of a chain of heterodimers of α-and β-tubulin. Microtubules can be assembled in vitro at 37°C in the presence of GTP which is hydrolyzed during the reaction, and they are disassembled at 4°C. In contrast to most other polymers microtubules show the behavior of “dynamic instability”, i.e. they can switch between phases of growth and phases of shrinkage, even at an overall steady state [1]. In certain conditions an entire solution can be synchronized, leading to autonomous oscillations in the degree of assembly which can be observed by X-ray scattering (Fig. 1), light scattering, or electron microscopy [2-5]. In addition such solutions are capable of generating spontaneous spatial patterns [6].In an earlier study we have analyzed the structure of microtubules and their cold-induced disassembly by cryo-EM [7]. One result was that disassembly takes place by loss of protofilament fragments (tubulin oligomers) which fray apart at the microtubule ends. We also looked at microtubule oscillations by time-resolved X-ray scattering and proposed a reaction scheme [4] which involves a cyclic interconversion of tubulin, microtubules, and oligomers (Fig. 2). The present study was undertaken to answer two questions: (a) What is the nature of the oscillations as seen by time-resolved cryo-EM? (b) Do microtubules disassemble by fraying protofilament fragments during oscillations at 37°C?

X-ray scattering by 1D molecular Guinier-Preston zones in ordered smectic phases

1992 ◽  
Vol 2 (6) ◽  
pp. 899-913 ◽  
Author(s):  
Patrick Davidson ◽  
Elisabeth Dubois-Violette ◽  
Anne-Marie Levelut ◽  
Brigitte Pansu
Keyword(s):  
X Ray ◽  
X Ray Scattering ◽  
Smectic Phases ◽  
Ray Scattering
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