Influence of several chemical treatment on the interfacial shear strength of zalacca fibres and low-density polyethylene matrix

2019 ◽  
Author(s):  
Wahyu Purwo Raharjo ◽  
Rudy Soenoko ◽  
Anindito Purnowidodo ◽  
Moch Agus Choiron
Author(s):  
Joshua D. Weed ◽  
William Jordan

The increasing social pressure for biodegradable, sustainable, and environmentally-friendly products has launched the use of natural fibers in fiber reinforced polymer composites. Unfortunately, due to the integration of organic material in thermoplastic components, the fiber-matrix interfacial bonding is poor. While the organic material is hydrophilic, able to absorb water, the majority of polymer matrices are hydrophobic, unable to bond with water. The interfacial shear strength, a quantity to measure this bonding, has been shown to be improved through morphological and chemical treatment. In this context, the interfacial shear strength of banana fiber in low-density polyethylene has not been fully characterized. The aim of this study is to identify and optimize the interfacial shear strength of banana fiber in a polymer matrix through a polymer-compatibilization technique. For characterization of the fiber-matrix interfacial bonding, a commonly used micromechanical technique, the pull-out test, is used. While these initial results range from 0.4 MPa to 1.5 MPa, multiple samples exhibit greater than 30% improvement in interfacial bonding. The results reveal a need for a more exact measurement method; however, they also reveal the potential use of polymer-compatibilization as a replacement to fiber-modification treatments.


Materials ◽  
2018 ◽  
Vol 11 (12) ◽  
pp. 2552 ◽  
Author(s):  
Uwe Gohs ◽  
Michael Mueller ◽  
Carsten Zschech ◽  
Serge Zhandarov

Continuous glass fiber-reinforced polypropylene composites produced by using hybrid yarns show reduced fiber-to-matrix adhesion in comparison to their thermosetting counterparts. Their consolidation involves no curing, and the chemical reactions are limited to the glass fiber surface, the silane coupling agent, and the maleic anhydride-grafted polypropylene. This paper investigates the impact of electron beam crosslinkable toughened polypropylene, alkylene-functionalized single glass fibers, and electron-induced grafting and crosslinking on the local interfacial shear strength and critical energy release rate in single glass fiber polypropylene model microcomposites. A systematic comparison of non-, amino-, alkyl-, and alkylene-functionalized single fibers in virgin, crosslinkable toughened and electron beam crosslinked toughened polypropylene was done in order to study their influence on the local interfacial strength parameters. In comparison to amino-functionalized single glass fibers in polypropylene/maleic anhydride-grafted polypropylene, an enhanced local interfacial shear strength (+20%) and critical energy release rate (+80%) were observed for alkylene-functionalized single glass fibers in electron beam crosslinked toughened polypropylene.


Mathematics ◽  
2021 ◽  
Vol 9 (9) ◽  
pp. 990
Author(s):  
Yasser Zare ◽  
Kyongyop Rhee

This study focuses on the simultaneous stiffening and percolating characteristics of the interphase section in polymer carbon nanotubes (CNTs) systems (PCNTs) using two advanced models of tensile modulus and strength. The interphase, as a third part around the nanoparticles, influences the mechanical features of such systems. The forecasts agree well with the tentative results, thus validating the advanced models. A CNT radius of >40 nm and CNT length of <5 μm marginally improve the modulus by 70%, while the highest modulus development of 350% is achieved with the thinnest nanoparticles. Furthermore, the highest improvement in nanocomposite’s strength (350%) is achieved with the CNT length of 12 μm and interfacial shear strength of 8 MPa. Generally, the highest ranges of the CNT length, interphase thickness, interphase modulus and interfacial shear strength lead to the most desirable mechanical features.


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