scholarly journals Vibronic structure of the cyanobutadiyne cation. I. VUV photoionization study of HC5N

2019 ◽  
Vol 150 (24) ◽  
pp. 244304
Author(s):  
Bérenger Gans ◽  
Nicolas Lamarre ◽  
Jean-Claude Guillemin ◽  
Stéphane Douin ◽  
Christian Alcaraz ◽  
...  
1989 ◽  
Vol 42 (6) ◽  
pp. 365-373 ◽  
Author(s):  
K.P. O'Donnell ◽  
A. Marshall ◽  
M. Yamaga ◽  
B. Henderson ◽  
B. Cockayne

1999 ◽  
Vol 71 (9) ◽  
pp. 1674-1678 ◽  
Author(s):  
Eyal Nir ◽  
Heinrich E. Hunziker ◽  
Mattanjah S. de Vries

2002 ◽  
Vol 116 (21) ◽  
pp. 9315-9325 ◽  
Author(s):  
Andreas Bach ◽  
J. Matthew Hutchison ◽  
Robert J. Holiday ◽  
F. Fleming Crim
Keyword(s):  

2012 ◽  
Vol 393 (1) ◽  
pp. 107-116 ◽  
Author(s):  
Martin Schwell ◽  
Yves Bénilan ◽  
Nicolas Fray ◽  
Marie-Claire Gazeau ◽  
Et. Es-Sebbar ◽  
...  

1993 ◽  
Vol 13 (2) ◽  
pp. 113-119 ◽  
Author(s):  
S. Georgiou ◽  
E. Mastoraki ◽  
E. Raptakis ◽  
Z. Xenidi

The paper examines the potential of vacuum ultraviolet (VUV) photoionization mass spectroscopy in probing the fragmentation of organometallics in molecular-beam studies and laser-assisted deposition processes. To this end, the ionic fragmentation pattern of few common organometallics, namely metallocenes and carbonyls, is examined at selected VUV wavelengths, produced by microwave-discharge resonance atomic lamps. Discussion of the recorded spectra in terms of the electronic structure of the compounds indicates lack of dynamical bias in the VUV photoionization/fragmentation of metal complexes. Excitation with VUV light results in simpler ionic fragmentation patterns than what observed with electron-impact ionization, thereby enabling accurate monitoring of the excimer-laser photodissociation of organometallics. Finally, the intensity of the VUV ionic signal appears to be adequate for molecular-beam studies. An illustrative example is provided for the study of the 248nm-induced photodesorption of Mo(CO)6 from cryogenic films.


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