Observation of a dynamical crossover in the shear relaxation processes in supercooled selenium near the glass transition

2019 ◽  
Vol 150 (9) ◽  
pp. 094502 ◽  
Author(s):  
Weidi Zhu ◽  
Bruce G. Aitken ◽  
Sabyasachi Sen
Polymer ◽  
2012 ◽  
Vol 53 (1) ◽  
pp. 161-168 ◽  
Author(s):  
Marcin Pastorczak ◽  
Michael Wübbenhorst ◽  
Gustavo Dominguez-Espinosa ◽  
Lidia Okrasa ◽  
Marek Pyda ◽  
...  

2004 ◽  
Vol 93 (24) ◽  
Author(s):  
Silvina Cerveny ◽  
Gustavo A. Schwartz ◽  
Rikard Bergman ◽  
Jan Swenson

2011 ◽  
Vol 6 (2) ◽  
pp. 91-95
Author(s):  
Ion Dranca ◽  
Igor Povar ◽  
Tudor Lupascu

This research has been carried out in order to demonstrate the use of differential scanning calorimetry (DSC) in detecting and measuring α- and β-relaxation processes in amorphous pharmaceutical systems. DSC has been employed to study amorphous samples of poly (vinylpyrrolidone) (PVP), indomethacin (InM), and ursodeoxycholic acid (UDA) that are annealed at temperature (Ta) around 0.8 of their glass transition temperature (Tg). Dynamic mechanical analysis (DMA) is used to measure β- relaxation in PVP. Yet, the DSC has been used to study the glassy indomethacin aged at 0 and -10 oC for periods of time up to 109 and 210 days respectively. The results demonstrate the emergence of a small melting peak of the α-polymorph after aging for 69 days at 0°C and for 147 days at -10°C (i.e., ~55°C below the glass transition temperature) that provides evidence of nucleation occurring in the temperature region of the β-relaxation.


1966 ◽  
Vol 45 (11) ◽  
pp. 4375-4376
Author(s):  
G. C. Knollman ◽  
D. O. Miles ◽  
A. S. Hamamoto

1968 ◽  
Vol 7 (5) ◽  
pp. 451-461 ◽  
Author(s):  
Eiichi Morita ◽  
Ryusuke Kono ◽  
Haruyo Yoshizaki

1965 ◽  
Vol 43 (4) ◽  
pp. 1160-1170 ◽  
Author(s):  
G. C. Knollman ◽  
D. O. Miles ◽  
A. S. Hamamoto

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