scholarly journals Kinetic parameters and calorific value of biochar from mahogany (Swietenia macrophylla King) wood pyrolysis with heating rate and final temperature variations

2018 ◽  
Author(s):  
Sintia Wardani ◽  
Pranoto ◽  
Dwi Aries Himawanto
Keyword(s):  
Kinetic Parameters ◽  
Heating Rate ◽  
Calorific Value ◽  
Swietenia Macrophylla ◽  
Final Temperature ◽  
Temperature Variations ◽  
Wood Pyrolysis

scholarly journals QUALITY OF Eucalyptus urograndis CHARCOAL PRODUCED IN THE SOUTHERN REGION OF TOCANTINS

FLORESTA ◽  
2019 ◽  
Vol 49 (4) ◽  
pp. 691
Author(s):  
Raquel Marchesan ◽  
Daniela Mendonça ◽  
Ana Carolina Caixeta Dias ◽  
Renata Carvalho da Silva ◽  
José Fernando Pereira ◽  
...  
Keyword(s):  
Heating Rate ◽  
Eucalyptus Grandis ◽  
Basic Density ◽  
Calorific Value ◽  
Fixed Carbon ◽  
Tree Plantation ◽  
Final Temperature ◽  
Good Energy ◽  
Eucalyptus Urograndis

The objective of this work was to determine the quality of the Eucalyptus urophilla x Eucalyptus grandis clone charcoal, defining the basic density and wood retractability, apparent density, breaking index, charcoal yield, condensable and non-condensable gas yield, AQI and calorific values, comparing the results of different trunk positions and in two different heating ramps, ramp 1 (R1) with a heating rate of 1.25 ºC/min, final temperature of 450ºC and total of 6 hours, and ramp 2 (R2) with a heating rate of 1.19 ºC/min, final temperature of 500ºC and total time of 7 hours. The six evaluated trees were from a six-year-old cloned tree plantation located in the municipality of Gurupi, in the south of Tocantins state. The specimens for the characterizations were made from wooden discs removed from three trunk positions (base, DBH, top). The Eucalyptus urograndis wood presented basic density considered average (0.47 g/cm³) and good dimensional stability. The charcoal presented an expected yield and high calorific value influenced by the final temperature of the heating ramps, high fixed carbon content, acceptable ash content, as well as a low breaking rate. The results were satisfactory and identified the species as a good energy source.

scholarly journals Evaluation of Non-Isothermal Kinetic Parameters for Pyrolysis of Teak Wood using Model-Fitting Techniques

2021 ◽  
Vol 18 (24) ◽  
pp. 1432
Author(s):  
Adekunle Adeleke ◽  
Peter Ikubanni ◽  
Jamiu Odusote ◽  
Thomas Orhadahwe ◽  
Olumuyiwa Lasode ◽  
...  
Keyword(s):  
Activation Energy ◽  
Weight Loss ◽  
Kinetic Parameters ◽  
Heating Rate ◽  
Model Fitting ◽  
Calorific Value ◽  
Wood Dust ◽  
Heating Rates ◽  
Teak Wood ◽  
Isothermal Kinetic

Teak wood is one of the prominently used raw material in the construction industry, thus contributing extremely to the biomass waste available in Nigeria. These wastes are usually used for energy generation that requires upgrade into better fuel before application. Hence, the present study evaluates the non-isothermal kinetic parameters for pyrolysis of teak wood using model-fitting techniques. Teak wood dust was subjected to proximate, ultimate and calorific value analyses based on different ASTM standards. The thermal degradation and decomposition behaviour of the teak wood dust was examined using a thermogravimetric analyzer. Pulverized teak (6.5 mg) was heated from 30 to 800 ºC at varying heating rates (5, 10 and 15 ºC) in an environment where 100 mL/min of nitrogen gas was charged in continuously to maintain an inert condition. Avrami-Erofeev, Ginstling-Broushtein (GB) and Mampel models were used to evaluate the kinetic parameters of the pyrolysis of teak wood dust. The teak wood dust contained 7.25 % moisture, 79.26 % volatile matter (VM), 1.74 % ash and 11.75 % fixed carbon. The calorific value of the wood dust was 18.72 MJ/kg. The results of the thermogravimetric analyses depicted that heating rate has no effect on weight loss during the reactive drying zone. However, as the thermal treatment progressed into the active pyrolysis and passive pyrolysis zones, the weight loss decreased with increase in heating rate.  The devolatilization parameters also increased with heating rates except for the maximum conversion. The results of the kinetic parameters evaluation revealed that the GB model was best fit to evaluate the kinetic parameters of teak in the active pyrolysis zone while GB and Mampel models were considered most appropriate for the evaluation of the kinetic parameters in the passive pyrolysis zone. Model-fitting method has the capacity to capture a wide range of fractional conversion at a glance. HIGHLIGHTS Arrhenius parameters in terms of activation energy and pre-exponential factor for the pyrolysis of teak wood while comparing 4 different model-fitting techniques were obtained The α-temperature plot for solid state reaction of teak wood dust was a bell-shape (sigmoidal model) The Avrami-Erofeev and SSS models were unable to capture the overlapping multiple reactions that took place simultaneously at the active pyrolysis zone Higher energy input is needed for devolatilization of teak wood dust to give 10 - 80 % conversion due to higher activation energy at the active pyrolysis zone Ginstling-Broushtein was found to be the best model for evaluating the kinetic parameters at the active pyrolysis zone as it had the highest R2 value GRAPHICAL ABSTRACT

scholarly journals Effect of the Incorporation of Biomass in the Carbonization of Waste Electrical and Electronic Equipment

Proceedings ◽  
2021 ◽  
Vol 52 (1) ◽  
pp. 4
Author(s):  
Roberta Mota-Panizio ◽  
Luis F. Carmo-Calado ◽  
Octávio Alves ◽  
Catarina Nobre ◽  
J. L. Silveira ◽  
...  
Keyword(s):  
Heating Rate ◽  
Lignocellulosic Biomass ◽  
Residence Time ◽  
Calorific Value ◽  
Electronic Equipment ◽  
Initial Value ◽  
Carbonization Process ◽  
Chlorine Removal

The behavior of chars from the carbonization process were studied when the lignocellulosic biomass was incorporated into the waste of electrical and electronic equipment for chlorine removal. Tests were performed at 300°C with a heating rate of 15°C/min and residence time of 60 min. Compositions studied had 100, 75, 50, 25 and 0% of waste electrical and electronic equipment (WEEE) in the mixtures. The composition of 50% WEEE with 50% lignocellulosic biomass presented the best char properties, having an increment of the calorific value in 5.5% relative to the initial value, and chlorine removal of 23.4% when compared to the forestry biomass.

scholarly journals Reply to Comments on ‘Effect of heating rate on kinetic parameters of β-irradiated Li2B4O7:Cu,Ag,P in TSL measurements’

2009 ◽  
Vol 20 (5) ◽  
pp. 058002
Author(s):  
A (Turkler) Ege ◽  
E (Ekdal) Tekin ◽  
T Karali ◽  
N Can ◽  
M Prokić
Keyword(s):  
Kinetic Parameters ◽  
Heating Rate

scholarly journals Effects of heating rate and heating up time to central biomass particles for bio-oil production

2016 ◽  
Vol 51 (1) ◽  
pp. 13-22
Author(s):  
MB Ahmed ◽  
ATMK Hasan ◽  
M Mohiuddin ◽  
M Asadullah ◽  
MS Rahman ◽  
...  
Keyword(s):  
Heating Rate ◽  
Particle Temperature ◽  
Product Distribution ◽  
Heating Rates ◽  
Final Temperature ◽  
Central Mass ◽  
Bio Oil ◽  
Reactor Temperature ◽  
Biomass Particles ◽  
Heating Up

Objective of this work was to pyrolysis woody biomass. Experiments were carried out at 300 to 500oC. Relatively bigger particles were used. Special emphasis was given to investigate the effects of heating rate and heating up time of the central mass of the particles on the product distribution. Surface temperature reached to the reactor set temperature immediately while the temperature at the central part was as low as 50oC. The center temperature gradually increased to the final temperature within 3 to 8 minutes, depending on the wood types and the reactor set temperature. For ipil-ipil wood the heating rate of the central mass was much faster than krishnachura and koroi woods, and thus the heating up time was lower. Ipil-ipil wood was experienced higher yield (65%) even at lower reactor temperature 300oC with particle temperature 450oC. In the case of krishnachura and koroi woods, the bio-oil yields were lower under the same condition due to the heating rates of the central parts were much slower. Further researchon different biomasses may be necessary to demonstrate overall process.Bangladesh J. Sci. Ind. Res. 51(1), 13-22, 2016

Research on Pyrolysis Kinetics of Shenhua Coal and Direct Liquefaction Residue

2012 ◽  
Vol 550-553 ◽  
pp. 2758-2762 ◽  
Author(s):  
Xi Jie Chu ◽  
Yong Gang Wang ◽  
Li Hong Zhao
Keyword(s):  
Experimental Data ◽  
Activation Energy ◽  
Kinetic Parameters ◽  
Heating Rate ◽  
Coal Pyrolysis ◽  
Pyrolysis Kinetics ◽  
Differential Heating ◽  
Pyrolysis Behavior ◽  
Direct Liquefaction ◽  
Kinetics Of

The pyrolysis tests of Shenhua coal and Shenhua direct liquefaction residue have been carried out using thermogravimetric at the differential heating rate. The kinetic parameters k and E were calculated using DAEM method. Results show DAME model can describe the pyrolysis behavior of Shenhua coal within the range of 20% to 95%, the activation energy of coal pyrolysis ranges from 53.98 to 279.38 kJ/mol, and DAME model can describe the behavior of Shenhua direct liquefaction residue within the range of 10% to 80%, the activation energy of residue pyrolysis is about 170 kJ/mol. The results of which are basically consistent with the experimental data.

Study on Combustion Characteristics of Impurity Coal Based on TG-DTG-DTA

2012 ◽  
Vol 568 ◽  
pp. 360-363
Author(s):  
Zhan Wen He ◽  
Chuan Cheng Zhang
Keyword(s):  
Kinetic Equation ◽  
Kinetic Parameters ◽  
Heating Rate ◽  
Ignition Temperature ◽  
Combustion Process ◽  
Combustion Characteristics ◽  
Diffusion Kinetic

Abstract.Based on TG-DTG-DTA, combustion characteristics and kinetic parameters of impure coal in the 10 °C / min heating rate were studied. The results showed that with the increase in the proportion of impurities, ignition temperature, burned temperature significantly improved; combustion characteristics of index clearly decreased; combustion process can be described by a diffusion kinetic equation

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