scholarly journals Modeling vibrational anharmonicity in infrared spectra of high frequency vibrations of polyatomic molecules

2019 ◽  
Vol 150 (9) ◽  
pp. 090901 ◽  
Author(s):  
Edwin L. Sibert
Author(s):  
S. R. Rakhmanov

In some cases, the processes of piercing or expanding pipe blanks involve the use of high-frequency active vibrations. However, due to insufficient knowledge, these processes are not widely used in the practice of seamless pipes production. In particular, the problems of increasing the efficiency of the processes of piercing or expanding a pipe blank at a piercing press using high-frequency vibrations are being solved without proper research and, as a rule, by experiments. The elaboration of modern technological processes for the production of seamless pipes using high-frequency vibrations is directly related to the choice of rational modes of metal deformation and the prediction resistance indicators of technological tools and the reliability of equipment operation. The creation of a mathematical model of the process of vibrating piercing (expansion) of an axisymmetric pipe blank at a piercing press of a pipe press facility is an actual task. A calculation scheme for the process of piercing a pipe plank has been elaborated. A dependence was obtained characterizing the speed of front of plastic deformation propagation on the speed of penetration of a vibrated axisymmetric mandrel into the pipe workpiece being pierced. The dynamic characteristics of the occurrence of wave phenomena in the metal being pierced under the influence of a vibrated tool have been determined, which significantly complements the previously known ideas about the stress-strain state of the metal in the deformation zone. The deformation fields in the zones of the disturbed region of the deformation zone were established, taking into account the high-frequency vibrations of the technological tool. It has been established that the choice of rational parameters (amplitude-frequency characteristics) of the vibration piercing process of a pipe blank results in significant increase in the efficiency of the process, the durability of the technological tool and the quality of the pierced blanks.


1970 ◽  
Vol 25 (10) ◽  
pp. 1394-1400 ◽  
Author(s):  
W. Krasser ◽  
H. W. Nürnberg

Abstract The thiocyanates of the transition metals iron, cobalt, copper as well as of rhenium and of tech-netium appear in solution as strongly coloured complexes. The resonance raman bands in the sol-vent acetonitrile are investigated. To achieve an unambiguous identification the infrared spectra were recorded too. The change in position and structure of the acetonitrile bands indicates strong complexation of iron, cobalt and copper with acetonitrile, thus indicating the existence of mixed acetonitrile-thiocyanate complexes. The resonance raman spectra of the rhenium-and technetium-thiocyanates present as tetramethyl ammonium salts show however no raman-and infrared-bands of complexed acetonitrile molecules.In the raman spectrum of the thiocyanates of iron, cobalt and copper mainly the totally sym-metric C≡N, S-C, Me-S and Me-N valence vibrations are observed, among which the S-C vibration shows a remarkably high intensity. Besides, a series of bands is obtained which is inter-preted partly as caused by decay products, and partly as bands of complexed acetonitrile. The thiocyanates of rhenium and of technetium show the three possible valence vibrations only. The high frequency of the S-C valence indicates the N-coordination of the thiocyanate group.


2016 ◽  
Vol 32 (3) ◽  
pp. 297-311
Author(s):  
T.-Y. Zhao ◽  
H.-Q. Yuan ◽  
B.-B. Li ◽  
Z.-J. Li ◽  
L.-M. Liu

AbstractThe analysis method is developed to obtain dynamic characteristics of the rotating cantilever plate with thermal shock and tip-rub. Based on the variational principle, equations of motion are derived considering the differences between rubbing forces in the width direction of the plate. The transverse deformation is decomposed into quasi-static deformation of the cantilever plate with thermal shock and dynamic deformation of the rubbing plate under thermal shock. Then deformations are obtained through the calculation of modal characteristics of rotating cantilever plate and temperature distribution function. Special attention is paid to the influence of tip-rub and thermal shock on the plate. The results show that tip-rub has the characteristics of multiple frequency vibrations, and high frequency vibrations are significant. On the contrary, thermal shock shows the low frequency vibrations. The thermal shock makes the rubbing plate gradually change into low frequency vibrations. Because rub-induced vibrations are more complicated than those caused by thermal shock, tip-rub is easier to result in the destruction of the blade. The increasing friction coefficient intensifies vibrations of the rubbing plate. Minimizing friction coefficients can be an effective way to reduce rub-induced damage through reducing the surface roughness between the blade tip and the inner surface of the casing.


2013 ◽  
Vol 341 (4-5) ◽  
pp. 477-482 ◽  
Author(s):  
Sergey M. Ishutov ◽  
Bela I. Myznikova ◽  
Boris L. Smorodin

2013 ◽  
Vol 113 (11) ◽  
pp. 2871-2871 ◽  
Author(s):  
Pierpaolo Iodice ◽  
Rosa Grazia Bellomo ◽  
Glaugo Gialluca ◽  
Giorgio Fanò ◽  
Raoul Saggini

2021 ◽  
Vol 34 (4) ◽  
pp. 538-547
Author(s):  
Duncan W. Shaw

The article of Apffel et al. [Nature 585, 48 (2020)] reported on an experiment that produced the sight of two miniature sailboats floating upside down to each other on the two sides of a layer of glycerol that was levitated by high frequency vibrations. The vessel on the underside of the glycerol is a remarkable display of the results of simulated gravity caused by vibrations. The present article considers this and other experiments on simulated gravity and finds that they provide support for the flowing aether concept of the cause of gravity.


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