scholarly journals Understanding the impact of C60 at the interface of perovskite solar cells via drift-diffusion modeling

AIP Advances ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 035026 ◽  
Author(s):  
Timofey Golubev ◽  
Dianyi Liu ◽  
Richard Lunt ◽  
Phillip Duxbury
Keyword(s):  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Diffusion Modeling ◽  
Drift Diffusion ◽  
The Impact

scholarly journals Unraveling the Impact of Halide Mixing on Crystallization and Phase Evolution in CsPbX3 Perovskite Solar Cells

Matter ◽  
2020 ◽  
Author(s):  
Junjie Ma ◽  
Minchao Qin ◽  
Yuhao Li ◽  
Xiao Wu ◽  
Zhaotong Qin ◽  
...  
Keyword(s):  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Phase Evolution ◽  
The Impact

The Impact of PbI 2 :KI Alloys on the Performance of Sequentially Deposited Perovskite Solar Cells

2021 ◽  
Author(s):  
Xiaoyan Yu ◽  
Qin Zhou ◽  
Jianbin Xu ◽  
Lusheng Liang ◽  
Xiaobing Wang ◽  
...  
Keyword(s):  
Solar Cells ◽  
Perovskite Solar Cells ◽  
The Impact

scholarly journals Elucidating the Impact of Charge Selective Contact in Halide Perovskite Through Impedance Spectroscopy

2019 ◽  
Author(s):  
Mohd Taukeer Khan ◽  
Manuel Salado ◽  
Abdullah R. D. Almohammedi ◽  
Samrana Kazim ◽  
Shahzada Ahmad
Keyword(s):  
Solar Cells ◽  
Impedance Spectroscopy ◽  
Charge Carrier ◽  
Carrier Mobility ◽  
Short Circuit ◽  
Perovskite Solar Cells ◽  
Charge Carrier Mobility ◽  
Charge Accumulation ◽  
Frequency Dependent ◽  
The Impact

<p>The electron and hole selective contact (SC) play a pivotal role in the performance of perovskite solar cells. In order to separate the interfacial phenomenon from bulk, the influence of charge SC was elucidated, by means of impedance spectroscopy. The specific role played by TiO<sub>2</sub> and <i>Spiro-OMeTAD</i> as electron and hole SC in perovskite solar cells was investigated at short circuit condition at different temperatures. We have probed MAPbI<sub>3</sub> and (FAPbI<sub>3</sub>)<sub>0.85</sub>(MAPbBr<sub>3</sub>)<sub>0.15 </sub>and elucidated parameters such as charge carrier mobility, recombination resistance, time constant and charge carrier kinetics in perovskite layer and at the interface of perovskite/SC. Charge carrier mobility in mixed perovskite was found to be nearly two order of magnitude higher as compared to MAPbI<sub>3</sub>. Moreover, the carrier mobility in devices with only electron SC was found to be higher as compared only hole SC. The charge accumulation at TiO<sub>2</sub>/perovskite/<i>Spiro</i>-OMeTAD interfaces were studied via frequency dependent capacitance, revealing higher charge accumulation at perovskite/S<i>piro</i>-OMeTAD than at TiO<sub>2</sub>/perovskite interface. By performing varying temperature frequency dependent capacitance measurements the distribution of density of state within the bandgap of the perovskites, the emission rate of electrons from the trap states and traps activation energy was determined. </p>

Analytical drift-diffusion modeling of GaAs solar cells incorporating a back mirror

2013 ◽  
Author(s):  
Matthew P. Lumb ◽  
Christopher G. Bailey ◽  
Jessica G. J. Adams ◽  
Glen Hillier ◽  
Francis Tuminello ◽  
...  
Keyword(s):  
Solar Cells ◽  
Diffusion Modeling ◽  
Drift Diffusion

Correlating hysteresis phenomena with interfacial charge accumulation in perovskite solar cells

2020 ◽  
Vol 22 (1) ◽  
pp. 245-251 ◽  
Author(s):  
Tianyang Chen ◽  
Zhe Sun ◽  
Mao Liang ◽  
Song Xue
Keyword(s):  
Solar Cells ◽  
Charge Exchange ◽  
Perovskite Solar Cells ◽  
Exchange Model ◽  
Diffusion Equations ◽  
Charge Accumulation ◽  
Drift Diffusion ◽  
Charge Extraction ◽  
Interfacial Charge ◽  
Hysteresis Phenomena

A generalized charge exchange model is introduced into drift–diffusion equations for modeling the charge extraction in perovskite solar cells.

scholarly journals Understanding the Impact of Cu-In-Ga-S Nanoparticles Compactness on Holes Transfer of Perovskite Solar Cells

Nanomaterials ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 286 ◽  
Author(s):  
Dandan Zhao ◽  
Yinghui Wu ◽  
Bao Tu ◽  
Guichuan Xing ◽  
Haifeng Li ◽  
...  
Keyword(s):  
Grain Size ◽  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Transport Layer ◽  
Device Performance ◽  
Device Structure ◽  
Optimal Point ◽  
Hole Transfer ◽  
Coverage Ratio ◽  
The Impact

Although a compact holes-transport-layer (HTL) film has always been deemed mandatory for perovskite solar cells (PSCs), the impact their compactness on the device performance has rarely been studied in detail. In this work, based on a device structure of FTO/CIGS/perovskite/PCBM/ZrAcac/Ag, that effect was systematically investigated with respect to device performance along with photo-physics characterization tools. Depending on spin-coating speed, the grain size and coverage ratio of those CIGS films on FTO substrates can be tuned, and this can result in different hole transfer efficiencies at the anode interface. At a speed of 4000 r.p.m., the band level offset between the perovskite and CIGS modified FTO was reduced to a minimum of 0.02 eV, leading to the best device performance, with conversion efficiency of 15.16% and open-circuit voltage of 1.04 V, along with the suppression of hysteresis. We believe that the balance of grain size and coverage ratio of CIGS interlayers can be tuned to an optimal point in the competition between carrier transport and recombination at the interface based on the proposed mechanism. This paper definitely deepens our understanding of the hole transfer mechanism at the interface of PSC devices, and facilitates future design of high-performance devices.

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