scholarly journals Dynamic corrosion tests comparison: Dynamic reactor vs high temperature pilot plant scale setup for Chilean LiNO3 containing molten salt

Author(s):  
A. G. Fernández ◽  
M. Henriquez ◽  
A. Mallco ◽  
B. Muñoz-Sánchez ◽  
J. Nieto-Maestre
2014 ◽  
Vol 1019 ◽  
pp. 187-194 ◽  
Author(s):  
Salomon Johannes Oosthuizen ◽  
Jaco Johannes Swanepoel ◽  
Dawid Steyn van Vuuren

The CSIR-Ti process produces titanium metal powder through continuous stepwise metallothermic reduction of titanium tetrachloride (TiCl4) in molten salt medium, and represents a cost-effective alternative to the standard Kroll process to produce titanium metal. Subsequent to proving the CSIR-Ti process at bench scale producing batches of ±2 kg titanium powder, the design, build and test of a continuous 2 kg/h Ti pilot plant was authorised. The scale-up process highlighted limited expertise in South Africa with regards to handling molten salt and molten reducing metals. Such gaps in knowledge are addressed in this study, which discusses a number of the engineering challenges faced and solutions developed around agitation of molten salt reactors, process pipe heating and insulation, molten salt flow measurement and also feeding of a highly reactive molten reducing metal. Scaling up the CSIR-Ti process, with requirements of continuous operation, compact size, effective agitation, pumping and maintaining salt in the molten state brought an unusual set of challenges requiring development of unique and prototype equipment. Further challenges were encountered in the handling and continuous feeding of molten reducing metal at the relatively small scale of the pilot plant. Solutions developed and discussed in this study include custom-modified agitators, custom-developed flow meters for measuring molten salt and molten metal flows, and a custom-designed molten metal feed system. Specialised materials such as, ultra-high temperature heating tape and ultra-low thermal conductivity insulation had to be imported as well as a special high-temperature pump that can pump a slurry consisting of molten salt containing a high weight percentage of suspended metal powder. The experience illustrates the technological difficulty of bridging the chasm between science and technology in that many unforeseen problems are encountered when developing and scaling up a new technology.


1986 ◽  
Vol 51 (2) ◽  
pp. 403-407 ◽  
Author(s):  
C. A. MERLO ◽  
W. W. ROSE ◽  
L. D. PEDERSEN ◽  
E. M. WHITE ◽  
J. A. NICHOLSON

2016 ◽  
Vol 94 ◽  
pp. 175-185 ◽  
Author(s):  
Cristina Prieto ◽  
Rafael Osuna ◽  
A. Inés Fernández ◽  
Luisa F. Cabeza

2009 ◽  
Vol 166 (2-3) ◽  
pp. 1530-1534 ◽  
Author(s):  
Ane Urtiaga ◽  
Ana Rueda ◽  
Ángela Anglada ◽  
Inmaculada Ortiz

2006 ◽  
Vol 138 (2) ◽  
pp. 363-369 ◽  
Author(s):  
M MALDONADO ◽  
S MALATO ◽  
L PEREZESTRADA ◽  
W GERNJAK ◽  
I OLLER ◽  
...  

2010 ◽  
Vol 73 ◽  
pp. 36-40 ◽  
Author(s):  
Ana Morán ◽  
Rubén Coto ◽  
Javier Belzunce ◽  
Jose Manuel Artímez

<span><span style="font-family: Times New Roman;">Ferritic/Martensitic steels, with chromium contents ranging between 9 and 12%, were introduced into fusion material programs due to their better creep resistance and excellent thermal and nuclear properties compared to austenitic stainless steels. Reduced activation ferritic/martensitic (RAFM) steels are considered promising candidates for the test blanket modules of the future International Thermonuclear Experimental Reactor (ITER), being EUROFER steel is the EU reference material. It is a 9 % Cr RAFM steel which exhibits a tempered martensitic <span style="font-family: Times New Roman;">microstructure and presently allows operation up to 550 </span><span style="font-family: Cambria Math;">⁰</span><span style="font-family: Times New Roman;">C. This paper shows the work carried out</span></span><span style="font-family: Times New Roman;"><span style="font-family: Times New Roman;"> to develop at a pilot plant scale a Reduced Activation Ferritic/Martensitic (RAFM) steel, Asturfer </span><span style="font-family: Times New Roman; font-size: xx-small;"><span style="font-family: Times New Roman; font-size: xx-small;">®</span></span><span style="font-family: Times New Roman;">,</span></span><span style="font-family: Times New Roman;"> with chemical composition and mechanical properties very close to EUROFER steel. </span>


2006 ◽  
Vol 29 (9) ◽  
pp. 1118-1121 ◽  
Author(s):  
K. Terasaka ◽  
Y. Suyama ◽  
K. Nakagawa ◽  
M. Kato ◽  
K. Essaki

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