scholarly journals Thermophysical properties and CO2 absorption of ammonium-based ionic liquids

2018 ◽  
Author(s):  
Nur Hamizah Halim ◽  
Normawati Mohamad Yunus ◽  
Cecilia Devi a/p Wilfred
Processes ◽  
2019 ◽  
Vol 7 (11) ◽  
pp. 820 ◽  
Author(s):  
Yunus ◽  
Halim ◽  
Wilfred ◽  
Murugesan ◽  
Lim ◽  
...  

Ionic liquids, which are classified as new solvents, have been identified to be potential solvents in the application of CO2 capture. In this work, six ammonium-based protic ionic liquids, containing ethanolammonium [EtOHA], tributylammonium [TBA], bis(2-ethylhexyl)ammonium [BEHA] cations, and acetate [AC] and butyrate [BA] anions, were synthesized and characterized. The thermophysical properties of the ammonium-based protic ionic liquids were measured. Density, , and dynamic viscosity, , were determined at temperatures between 293.15 K and 363.15 K. The density and viscosity values were correlated using empirical correlations and the thermal coefficient expansion, p, and molecular volume, Vm, were estimated using density values. The thermal stability of the ammonium-based protic ionic liquids was investigated using thermogravimetric analyzer (TGA) at a heating rate of 10 C.min‒1. The CO2 absorption of the ammonium-based ionic liquids were measured up to 20 bar at 298.15 K. From the experimental results, [BEHA][BA] had the highest affinity towards CO2 with the mol fraction of CO2 absorbed approaching 0.5 at 20 bar. Generally, ionic liquids with butyrate anions have better CO2 absorption than that of acetate anions while [BEHA] ionic liquids have higher affinity towards CO2 followed by [TBA] and [EtOHA] ionic liquids.


2016 ◽  
Vol 13 (1) ◽  
pp. 53
Author(s):  
Siti Nabihah Jamaludin ◽  
Ruzitah Mohd Salleh

Anthropogenic CO2 emissions has led to global climate change and widely contributed to global warming since its concentration has been increasing over time. It has attracted vast attention worldwide. Currently, the different CO2 capture technologies available include absorption, solid adsorption and membrane separation. Chemical absorption technology is regarded as the most mature technology and is commercially used in the industry. However, the key challenge is to find the most efficient solvent in capturing CO2. This paper reviews several types of CO2 capture technologies and the various factors influencing the CO2 absorption process, resulting in the development of a novel solvent for CO2 capture.


2016 ◽  
Vol 407 ◽  
pp. 188-196 ◽  
Author(s):  
Mónia A.R. Martins ◽  
Catarina M.S.S. Neves ◽  
Kiki A. Kurnia ◽  
Pedro J. Carvalho ◽  
Marisa A.A. Rocha ◽  
...  

2009 ◽  
Vol 41 (10) ◽  
pp. 1069-1073 ◽  
Author(s):  
K.A. Kurnia ◽  
F. Harris ◽  
C.D. Wilfred ◽  
M.I. Abdul Mutalib ◽  
T. Murugesan

ChemSusChem ◽  
2016 ◽  
Vol 9 (8) ◽  
pp. 763-763
Author(s):  
Qiwei Yang ◽  
Zhiping Wang ◽  
Zongbi Bao ◽  
Zhiguo Zhang ◽  
Yiwen Yang ◽  
...  

2007 ◽  
Vol 52 (5) ◽  
pp. 1979-1983 ◽  
Author(s):  
Adela Fernández ◽  
José S. Torrecilla ◽  
Julián García ◽  
Francisco Rodríguez

Author(s):  
Elaine Fabre ◽  
S M Sohel Murshed

In recent years ionic liquids have received tremendous attention from the researchers and industrial people mainly due to their unique properties, such as low vapor pressure, low toxicity, high thermal...


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