scholarly journals Enhancement of the conversion efficiency of thin film kesterite solar cell

2018 ◽  
Vol 10 (3) ◽  
pp. 033501 ◽  
Author(s):  
Yousaf Hameed Khattak ◽  
Faisal Baig ◽  
Shafi Ullah ◽  
Bernabé Marí ◽  
Saira Beg ◽  
...  
2017 ◽  
Vol 173 ◽  
pp. 37-42 ◽  
Author(s):  
Kunta Yoshikawa ◽  
Wataru Yoshida ◽  
Toru Irie ◽  
Hayato Kawasaki ◽  
Katsunori Konishi ◽  
...  

2015 ◽  
Vol 7 (12) ◽  
pp. 6472-6479 ◽  
Author(s):  
Wilman Septina ◽  
Masaaki Kurihara ◽  
Shigeru Ikeda ◽  
Yasuhiro Nakajima ◽  
Toshiyuki Hirano ◽  
...  

2015 ◽  
Vol 1738 ◽  
Author(s):  
Liyuan Zhang ◽  
Sreejith Karthikeyan ◽  
Mandip J. Sibakoti ◽  
Stephen A. Campbell

ABSTRACTWe investigate the synthesis of kesterite Cu2ZnSnS4 (CZTS) thin films using thermal evaporation from copper, zinc and tin pellets and post-annealing in a sulfur atmosphere. The effects of chemical composition were studied both on the absorber layer properties and on the final solar cell performance. It is confirmed that CZTS thin film chemical composition affects the carrier concentration profile, which then influences the solar cell properties. Solar cells using a CZTS thin film with composition ratio Cu/(Zn+Sn) = 0.87, and Zn/Sn = 1.24 exhibited an open-circuit voltage of 483 mV, a short-circuit current of 14.54 mA/cm2, a fill factor of 37.66 % and a conversion efficiency of 2.64 %. Only a small deviation from the optimal chemical composition can drop device performance to a lower level, which confirms that the CZTS solar cells with high conversion efficiency existed in a relatively narrow composition region.


2011 ◽  
Vol 21 (1) ◽  
pp. 72-76 ◽  
Author(s):  
Byungha Shin ◽  
Oki Gunawan ◽  
Yu Zhu ◽  
Nestor A. Bojarczuk ◽  
S. Jay Chey ◽  
...  

2013 ◽  
Vol 22 (1) ◽  
pp. 58-68 ◽  
Author(s):  
Lian Guo ◽  
Yu Zhu ◽  
Oki Gunawan ◽  
Tayfun Gokmen ◽  
Vaughn R. Deline ◽  
...  

Author(s):  
Samer H. Zyoud ◽  
Ahed H. Zyoud ◽  
Naser M. Ahmed ◽  
Anupama R. Prasad ◽  
Sohaib Naseem Khan ◽  
...  

This article describes in detail the numerical modeling of a CZTS (copper zinc tin sulfide) based kesterite solar cell. The Solar Cell Capacitance Simulator -one-dimension (SCAPS-1D) software was used to simulate MO/CZTS/CdS/ZnO/FTO structured solar cells. The parameters of different photovoltaic thin-film solar cells are estimated and analyzed using numerical modeling. The effects of various parameters on the performance of the photovoltaic cell and the conversion efficiency are discussed. Since the response of the solar cell is also contingent on its internal physical mechanism, J-V characteristic measures are insufficient to characterize the behavior of a device. Different features, as well as different potential conditions, must be considered for simulation, disregarding the belief in the modeling of a solar cell. With a conversion efficiency of 25.72%, a fill factor of 83.75%, a short-circuit current of 32.96436 mA/cm2 and an open-circuit voltage of 0.64V, promising optimized results have been achieved. The findings will be useful in determining the feasibility of fabricating high-efficiency CZTS-based photovoltaic cells. The efficiency of a CZTS-based experimental solar cell is also discussed. First, the effects of experimentally developed CZTS solar cells are simulated in the SCAPS-1D environment. The experimental results are then compared to the SCAPS-1D simulated results. The conversion efficiency of an optimized system increases after cell parameters are optimized. Using one-dimensional SCAPS-1D software, the effect of system parameters such as the thickness, acceptor and donor carrier concentration densities of absorber and electron transport layers, and the effect of temperature on the efficiency of CZTS-based photovoltaic cells is investigated. The proposed results will greatly assist engineers and researchers in determining the best method for optimizing solar cell efficiency, as well as in the development of efficient CZTS-based solar cells.


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