The glass-like thermal conductivity in ZrO2-Dy3TaO7 ceramic for promising thermal barrier coating application

2018 ◽  
Vol 112 (13) ◽  
pp. 131903 ◽  
Author(s):  
Peng Wu ◽  
Ming Yu Hu ◽  
Xiao Yu Chong ◽  
Jing Feng
2014 ◽  
Vol 1033-1034 ◽  
pp. 907-911 ◽  
Author(s):  
Huai Fei Liu ◽  
Xiang Xiong ◽  
Ya Lei Wang

Rare earth oxides co-doped zirconia has been developed for application in thermal barrier coating (TBC) systems to promote the performance and durability. In this paper, the phase stability and thermal physical properties of 1mol.%La2O3, 4.5mol.%Y2O3stabilized ZrO2(LaYSZ) were investigated. After 100 h heat treated at 1400°C, the content of monoclinic phase in LaYSZ was 2.32 mol%, which is lower than that in YSZ (46.9 mol%). Result indicates that the LaYSZ has better phase stability and lower thermal conductivity than YSZ. The LaYSZ system can be explored as the candidate material as ceramic layer in TBC.


Coatings ◽  
2018 ◽  
Vol 8 (7) ◽  
pp. 253 ◽  
Author(s):  
Qi Wang ◽  
Lei Guo ◽  
Zheng Yan ◽  
Fuxing Ye

TiO2 was doped into Er2O3-stabilized ZrO2 (ErSZ) to obtain desirable properties for thermal barrier coating (TBC) applications. The phase composition, thermal conductivity, and mechanical properties of TiO2-doped ErSZ were investigated. ErSZ had a non-transformable metastable tetragonal (t′) phase, the compound with 5 mol % TiO2 consisted of t′ and cubic (c) phases, while 10 mol % TiO2 doped ErSZ had t′, c, and about 3.5 mol % monoclinic (m) phases. Higher TiO2 doping contents caused more m phase, and the compounds were composed of t′ and m phases. When the dopant content was below 10 mol %, TiO2 doping could decrease the thermal conductivity and enhance the toughness of the compounds. At higher doping levels, the compounds exhibited an increased thermal conductivity and a reduction in the toughness, mainly attribable to the formation of the undesirable m phase. Hence, 10 mol % TiO2-doped ErSZ could be a promising candidate for TBC applications.


2019 ◽  
Vol 39 (4) ◽  
pp. 1463-1476 ◽  
Author(s):  
Zhilin Tian ◽  
Jie Zhang ◽  
Tianyin Zhang ◽  
Xiaomin Ren ◽  
Wanpeng Hu ◽  
...  

Author(s):  
Jianhua Yu ◽  
Huayu Zhao ◽  
Shunyan Tao ◽  
Xiaming Zhou ◽  
Chuanxian Ding

Plasma-sprayed thermal barrier coating (TBC) systems are widely used in gas turbine blades to increase turbine entry temperature (TET) and better efficiency. Yttria stabilized zirconia (YSZ) has been the conventional thermal barrier coating material because of its low thermal conductivity, relative high thermal expansion coefficient and good corrosion resistance. However the YSZ coatings can hardly fulfill the harsh requirements in future for higher reliability and the lower thermal conductivity at higher temperatures. Among the interesting TBC candidates, materials with pyrochlore structure show promising thermo-physical properties for use at temperatures exceeding 1200 °C. Sm2Zr2O7 bulk material does not only have high temperature stability, sintering resistance but also lower thermal conductivity and higher thermal expansion coefficient. The sintering characteristics of ceramic thermal barrier coatings under high temperature conditions are complex phenomena. In this paper, samarium zirconate (Sm2Zr2O7, SZ) powder and coatings were prepared by solid state reaction and atmosphere plasma spraying process, respectively. The microstructure development of coatings derived from sintering after heat-treated at 1200–1500 °C for 50 h have been investigated. The microstructure was examined by scanning electron microscopy (SEM) and the grain growth was analyzed in this paper as well.


1998 ◽  
Vol 7 (1) ◽  
pp. 43-46 ◽  
Author(s):  
A.J. Slifka ◽  
B.J. Filla ◽  
J.M. Phelps ◽  
G. Bancke ◽  
C.C. Berndt

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