CO oxidation on Ru–Pt bimetallic nanoclusters supported on TiO2(101): The effect of charge polarization

2018 ◽  
Vol 148 (12) ◽  
pp. 124701 ◽  
Author(s):  
Chuanyi Jia ◽  
Wenhui Zhong ◽  
Mingsen Deng ◽  
Jun Jiang
Keyword(s):  
Co Oxidation ◽  
Bimetallic Nanoclusters ◽  
Charge Polarization

A computational study of supported Cu-based bimetallic nanoclusters for CO oxidation

2018 ◽  
Vol 20 (11) ◽  
pp. 7508-7513 ◽  
Author(s):  
Yulu Liu ◽  
Hao Li ◽  
Wanglai Cen ◽  
Jianjun Li ◽  
Zhengming Wang ◽  
...  
Keyword(s):  
Dft Calculations ◽  
Co Oxidation ◽  
Computational Study ◽  
Bimetallic Nanoclusters ◽  
Functional Nature

In this study, we used DFT calculations to investigate the bi-functional nature of Cu-based alloy nanoclusters (NCs) supported on CeO2(111) for CO oxidation.

scholarly journals CO Oxidation at the Au–Cu Interface of Bimetallic Nanoclusters Supported on CeO2(111)

2013 ◽  
Vol 4 (17) ◽  
pp. 2943-2947 ◽  
Author(s):  
Liang Zhang ◽  
Hyun You Kim ◽  
Graeme Henkelman
Keyword(s):  
Co Oxidation ◽  
Bimetallic Nanoclusters

Catalytic CO Oxidation on Unreconstructed Cu(110) by Reactive As-Adsorbed Oxygen Atoms below 230 K

1996 ◽  
Vol 100 (3) ◽  
pp. 1048-1054 ◽  
Author(s):  
Tsuyoshi Sueyoshi ◽  
Takehiko Sasaki ◽  
Yasuhiro Iwasawa
Keyword(s):  
Co Oxidation ◽  
Adsorbed Oxygen ◽  
Catalytic Co Oxidation ◽  
Oxygen Atoms

Effects of H2O and O2 on CO Oxidation using Dielectric Barrier Discharge

2013 ◽  
Vol 133 (12) ◽  
pp. 642-647 ◽  
Author(s):  
Hitomi Kawakami ◽  
Akinori Zukeran ◽  
Koji Yasumoto ◽  
Yoshiyasu Ehara ◽  
Toshiaki Yamamoto
Keyword(s):  
Co Oxidation ◽  
Dielectric Barrier Discharge ◽  
Barrier Discharge ◽  
Dielectric Barrier

Bacterial Co-oxidation of Natural Humic Substances in the Presence of Glucose

2004 ◽  
Vol 40 (1) ◽  
pp. 8
Author(s):  
N. Dzyuban ◽  
E. S. Bikbulatov ◽  
E. M. Bikbulatova ◽  
I. A. Kuznetsova
Keyword(s):  
Co Oxidation ◽  
Humic Substances

CO OXIDATION ON THIN Pt CRYSTALS : STOICHIOMETRIC AND MATHEMATICAL MODELS

2007 ◽  
Vol 21 (0) ◽  
pp. 272-281
Author(s):  
І. О. Пеняк ◽  
Б. В. Гнатів ◽  
М. В. Токарчук
Keyword(s):  
Mathematical Models ◽  
Co Oxidation

Tuning the Activities of Cu2O Nanostructures via the Oxide-Metal Interaction

2019 ◽  
Author(s):  
Wugen Huang ◽  
qingfei liu ◽  
Zhiwen Zhou ◽  
Yangsheng Li ◽  
Yong Wang ◽  
...  
Keyword(s):  
Co Oxidation ◽  
Oxidation Catalysis ◽  
Atomic Scale ◽  
Scanning Tunneling ◽  
Oxidation Reactions ◽  
Tunneling Microscopy ◽  
Temperature Oxidation ◽  
Metal Interaction ◽  
Tremendous Importance ◽  
Oxygen Atoms

Despite tremendous importance in catalysis, the design and improvement of the oxide- metal interface has been hampered by the limited understanding on the nature of interfacial sites, as well as the oxide-metal interaction (OMI). Through the construction of well-defined Cu<sub>2</sub>O-Pt, Cu<sub>2</sub>O-Ag, Cu<sub>2</sub>O-Au interfaces, we found that Cu<sub>2</sub>O Nanostructures (NSs) on Pt exhibit much lower thermal stability than on Ag and Au, although they show the same surface and edge structures, as identified by element-specific scanning tunneling microscopy (ES-STM) images. The activities of the Cu<sub>2</sub>O-Pt and Cu<sub>2</sub>O-Au interfaces for CO oxidation were further compared at the atomic scale and showed in general that the interface with Cu<sub>2</sub>O NSs could annihilate the CO-poisoning problem suffered by Pt group metals and enhance the interaction with O<sub>2</sub>, which is a limiting step for CO oxidation catalysis on group IB metals. While both interfaces could react with CO at room temperature, the OMI was found to determine the reactivity of supported Cu<sub>2</sub>O NSs by 1) tuning the activity of interfacial oxygen atoms and 2) stabilizing oxygen vacancies or vice versa, the dissociated oxygen atoms at the interface. Our study provides new insight for OMI and for the development of Cu-based catalysts for low temperature oxidation reactions.

Tuning the Activities of Cu2O Nanostructures via the Oxide-Metal Interaction

2019 ◽  
Author(s):  
Wugen Huang ◽  
Yangsheng Li ◽  
Yong Wang ◽  
Yunchuan Tu ◽  
Dehui Deng ◽  
...  
Keyword(s):  
Co Oxidation ◽  
Oxidation Catalysis ◽  
Atomic Scale ◽  
Scanning Tunneling ◽  
Oxidation Reactions ◽  
Tunneling Microscopy ◽  
Temperature Oxidation ◽  
Metal Interaction ◽  
Tremendous Importance ◽  
Oxygen Atoms

Despite tremendous importance in catalysis, the design and improvement of the oxide- metal interface has been hampered by the limited understanding on the nature of interfacial sites, as well as the oxide-metal interaction (OMI). Through the construction of well-defined Cu<sub>2</sub>O-Pt, Cu<sub>2</sub>O-Ag, Cu<sub>2</sub>O-Au interfaces, we found that Cu<sub>2</sub>O Nanostructures (NSs) on Pt exhibit much lower thermal stability than on Ag and Au, although they show the same surface and edge structures, as identified by element-specific scanning tunneling microscopy (ES-STM) images. The activities of the Cu<sub>2</sub>O-Pt and Cu<sub>2</sub>O-Au interfaces for CO oxidation were further compared at the atomic scale and showed in general that the interface with Cu<sub>2</sub>O NSs could annihilate the CO-poisoning problem suffered by Pt group metals and enhance the interaction with O<sub>2</sub>, which is a limiting step for CO oxidation catalysis on group IB metals. While both interfaces could react with CO at room temperature, the OMI was found to determine the reactivity of supported Cu<sub>2</sub>O NSs by 1) tuning the activity of interfacial oxygen atoms and 2) stabilizing oxygen vacancies or vice versa, the dissociated oxygen atoms at the interface. Our study provides new insight for OMI and for the development of Cu-based catalysts for low temperature oxidation reactions.

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