Preferential nucleation, guiding, and blocking of self-propelled droplets by dislocations

2018 ◽  
Vol 123 (16) ◽  
pp. 161570 ◽  
Author(s):  
Songphol Kanjanachuchai ◽  
Thipusa Wongpinij ◽  
Suphakan Kijamnajsuk ◽  
Chalermchai Himwas ◽  
Somsak Panyakeow ◽  
...  
2004 ◽  
Vol 812 ◽  
Author(s):  
Z. -S. Choi ◽  
C. L. Gan ◽  
F. Wei ◽  
C. V. Thompson ◽  
J. H. Lee ◽  
...  

AbstractThe median-times-to-failure (t50's) for straight dual-damascene via-terminated copper interconnect structures, tested under the same conditions, depend on whether the vias connect down to underlaying leads (metal 2, M2, or via-below structures) or connect up to overlaying leads (metal 1, M1, or via-above structures). Experimental results for a variety of line lengths, widths, and numbers of vias show higher t50's for M2 structures than for analogous M1 structures. It has been shown that despite this asymmetry in lifetimes, the electromigration drift velocity is the same for these two types of structures, suggesting that fatal void volumes are different in these two cases. A numerical simulation tool based on the Korhonen model has been developed and used to simulate the conditions for void growth and correlate fatal void sizes with lifetimes. These simulations suggest that the average fatal void size for M2 structures is more than twice the size of that of M1 structures. This result supports an earlier suggestion that preferential nucleation at the Cu/Si3N4 interface in both M1 and M2 structures leads to different fatal void sizes, because larger voids are required to span the line thickness in M2 structures while smaller voids below the base of vias can cause failures in M1 structures. However, it is also found that the fatal void sizes corresponding to the shortest-times-to-failure (STTF's) are similar for M1 and M2, suggesting that the voids that lead to the shortest lifetimes occur at or in the vias in both cases, where a void need only span the via to cause failure. Correlation of lifetimes and critical void volumes provides a useful tool for distinguishing failure mechanisms.


1992 ◽  
Vol 280 ◽  
Author(s):  
B. Y. Lin ◽  
C. P. Beetz ◽  
D. W. Brown ◽  
B. A. Lincoln

ABSTRACTWe report a set of CH4 pyrolysis experiments in a UHV system on diamond surfaces having varying degrees of surface roughness or perfection. Scanning electron microscopy (SEM), Auger electron spectroscopy (AES) and reflection high energy electron diffraction (RHEED) were used to examine the formation of graphite and the resulting surface morphologies. A (100) type Ha natural diamond having 3 sputtered craters on the surface was used as the substrate, sp2 carbon was formed preferentially on the structurally defective crater surfaces after ∼3×1010 L of CH4 exposure at 900°C, whereas essentially no sp2 carbon was found on the flat portions of the diamond surface. Similar experiments were also carried out on a polycrystalline CVD diamond film and sp2 carbon was formed on that surface afte ∼4×109 L of CH4 exposure at 900°C. These results indicate that structural defects on diamond surfaces are a crucial factor in the preferential nucleation of sp2 carbon during CH4 pyrolysis.


2002 ◽  
Vol 14 (16) ◽  
pp. 4187-4198 ◽  
Author(s):  
A L Vázquez de Parga ◽  
J M Gallego ◽  
J J de Miguel ◽  
R Miranda

2008 ◽  
Vol 25 (8) ◽  
pp. 2957-2960 ◽  
Author(s):  
Dong Wen ◽  
Guo Xiang ◽  
Wang Si-Zhen ◽  
Wang Zhen-Lin ◽  
Ming Nai-Ben

2007 ◽  
Vol 1031 ◽  
Author(s):  
Sarah O'Donnell ◽  
Michael Buettner ◽  
Petra Reinke

AbstractThe first step in synthesizing a model film morphology via a surface-driven hierarchical assembly process is presented. The goal of the hierarchical assembly is the control of the morphology of complex molecular layers for the investigation of fundamental processes in organic solar cells. Using a focused ion beam (FIB) with Ga+ ions at 30 keV, the surface of highly oriented pyrolitic graphite (HOPG) is patterned with an array of local amorphous carbon ellipsoid spots (ACES), which provide preferential nucleation lines at their perimeter, and thus are instrumental in the control of fullerene island growth. On the undamaged surface regions outside the ACES pattern the fullerene island growth is unperturbed, and presents the well-known combination of round and fractal island shapes. The fullerene deposition at the periphery of the ACES pattern, which is characterized by single ion impact defects, results in stunted, smaller and irregular islands. Inside the ACES array, the C60 island growth is controlled by the shape of the ACES and is constrained to lobes which form around each ACES spot. The array and C60 lobe morphology and geometry are characterized and a subsequent understanding of the C60 diffusion fields and nucleation lines within the array is discussed.


2006 ◽  
Vol 980 ◽  
Author(s):  
Yuichiro Koizumi ◽  
Kazuki Iwamoto ◽  
Takayuki Tanaka ◽  
Yoritoshi Minamino ◽  
Nobuhiro Tsuji

AbstractWe studied antiphase domain (APD) growth and lamellar structure formation during isothermal annealing of Ti-39at%Al single crystals at α2+γ dual phase temperature after quenching from α single phase state, intending to obtain a APD/lamellae mixed microstructure and to examine whether such a microstructure provides a strength higher than that obtained only by refining lamellar structure. The effect of plastic deformation prior to the annealing was also examined expecting a acceleration of γ lamellae formation through a preferential nucleation of γ-plates at dislocations. The lower was the annealing temperature, the smaller both the APD size and the lamellar spacing at the moment of a homogeneous lamellar structure formation tended to be, although naturally both the APD growth and the γ lamellae formation were slower. However, the APD size in the homogeneous lamellar structure was no smaller than 400 nm. A structure with finer APDs and finer lamellar structure was obtained by deforming the crystal before annealing since the lamellar structure formation was accelerated and the time for APD growth before the lamellar structure formation was shortened. For instance, a structure with an average lamellar spacing of 88 nm and an average APD size of 214 nm was obtained by deforming the crystals to 10 % plastic strain and subsequently annealing at 1073 K for 1×104 s, while no γ plate was obtained only by such an annealing without deformation.


Nanoscale ◽  
2019 ◽  
Vol 11 (44) ◽  
pp. 21354-21363 ◽  
Author(s):  
Nathan A. Fleer ◽  
Melonie P. Thomas ◽  
Justin L. Andrews ◽  
Gregory R. Waetzig ◽  
Oscar Gonzalez ◽  
...  

Metastable cubic HfO2 is prepared by preferential nucleation using a lattice crystallographic relationship.


1994 ◽  
Vol 9 (8) ◽  
pp. 2029-2039 ◽  
Author(s):  
M.A. McCoy ◽  
S.A. Dregia ◽  
W.E. Lee

The decomposition of congruent lithium niobate (LN) crystals proceeds by surface nucleation and growth of LiNb3O8 precipitates which exhibit an epitaxial orientation relationship. The same orientation relationship is observed on x-, y-, and z-cut LN substrates. The epitaxy arises from similarities between the two crystal structures and provides for an essentially continuous oxygen-ion framework from parent to product. On y-cut LN, the precipitates have a well-defined habit plane, and the interfacial misfit between the two structures is accommodated by a rectangular grid of misfit dislocations. The density, geometry, and imaging behavior of the misfit dislocations suggest that their Burgers vectors serve to accommodate the disregistry in the oxygen-ion framework. Based on these observations, it is concluded that the mechanism of formation of LiNb3O8 consists of preferential nucleation on the surface and subsequent growth, possibly by counterdiffusion of cations in a closed system where the oxygen-ion framework remains essentially fixed in space.


2001 ◽  
Vol 696 ◽  
Author(s):  
Sergey V. Ivanov ◽  
Tatiana V. Shubina ◽  
Sergey V. Sorokin ◽  
Alexey A. Toropov ◽  
Reginald N. Kyutt ◽  
...  

AbstractStressor-controlled epitaxy has been proposed as an efficient method of CdSe quantum dot fabrication. The studies are performed on a type-II CdSe/BeTe system, where CdTe and BeSe inteface bonds play a role of intrinsic stressors. Predeposition of ~0.2 ML CdTe stressor ( Δ a/a= +15%), corresponding to a local maximum of RHEED specular spot intensity, appears to induce variation of stress field across the BeTe surface, caused by alternating regions with CdTe and BeSe bonds. It results in preferential nucleation of regularly arranged CdSe QDs at the BeSe sites with the following vertical chess-ordering in the CdSe/BeTe multilayers. The structures demonstrate bright up to RT PL in the 1.9-2.1 eV range and strong in-plane PL anisotropy related to non-equivalent bottom and top CdSe QD interfaces having estimated from x-ray diffraction total concentrations of CdTe and BeSe bonds of 0.3-0.4 and 0.6-0.7 ML, respectively.


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