Relationship between global and segmental dynamics of poly(butylene oxide) studied by broadband dielectric spectroscopy

2018 ◽  
Vol 148 (3) ◽  
pp. 034904 ◽  
Author(s):  
Osamu Urakawa ◽  
Minoru Yamane ◽  
Shota Tomie ◽  
Tadashi Inoue ◽  
Toshiyuki Shikata ◽  
...  
Keyword(s):  
Dielectric Spectroscopy ◽  
Segmental Dynamics ◽  
Broadband Dielectric Spectroscopy

scholarly journals Dynamics of aqueous peptide solutions in folded and disordered states examined by dynamic light scattering and dielectric spectroscopy

2021 ◽  
Author(s):  
Jorge Humberto Melillo ◽  
Jan Gabriel ◽  
Florian Pabst ◽  
Thomas Blochowicz ◽  
Silvina Cerveny
Keyword(s):  
Light Scattering ◽  
Dynamic Light Scattering ◽  
Dielectric Spectroscopy ◽  
Intrinsically Disordered Proteins ◽  
Disordered Proteins ◽  
Segmental Dynamics ◽  
Intrinsically Disordered ◽  
Broadband Dielectric Spectroscopy ◽  
Combining Data

Characterizing the segmental dynamics of proteins, and intrinsically disordered proteins in particular, is a challenge in biophysics. In this study, by combining data from broadband dielectric spectroscopy (BDS) and both...

Site-Dependent Segmental Dynamics Revealed Using Broadband Dielectric Spectroscopy on Well-Defined Functionalized Polystyrenes

2011 ◽  
Vol 44 (19) ◽  
pp. 7810-7819 ◽  
Author(s):  
Sandra Plaza-García ◽  
Reidar Lund ◽  
Angel Alegría ◽  
Juan Colmenero ◽  
Jonathan Janoski ◽  
...  
Keyword(s):  
Dielectric Spectroscopy ◽  
Segmental Dynamics ◽  
Broadband Dielectric Spectroscopy

scholarly journals Glassy dynamics of poly(2-vinyl-pyridine) brushes with varying grafting density

Soft Matter ◽  
2015 ◽  
Vol 11 (15) ◽  
pp. 3062-3066 ◽  
Author(s):  
Nils Neubauer ◽  
René Winkler ◽  
Martin Tress ◽  
Petra Uhlmann ◽  
Martin Reiche ◽  
...  
Keyword(s):  
Glass Transition ◽  
Dielectric Spectroscopy ◽  
Glassy Dynamics ◽  
Segmental Dynamics ◽  
Broadband Dielectric Spectroscopy ◽  
Nanostructured Silicon ◽  
Grafting Density ◽  
Vinyl Pyridine

By using Broadband Dielectric Spectroscopy with nanostructured silicon electrodes we found that the segmental dynamics (dynamic glass transition) of a series of P2VP brushes is bulk-like.

scholarly journals Broadband dielectric spectroscopy for monitoring temperature-dependent chloride ion motion in BiOCl plates

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Adrian Radoń ◽  
Dariusz Łukowiec ◽  
Patryk Włodarczyk
Keyword(s):  
Electrical Conductivity ◽  
Dielectric Spectroscopy ◽  
Low Frequency ◽  
Chloride Ion ◽  
Ion Source ◽  
Chloride Ions ◽  
Ion Concentration ◽  
Broadband Dielectric Spectroscopy ◽  
Free Chloride ◽  
Structure Rebuilding

AbstractThe dielectric properties and electrical conduction mechanism of bismuth oxychloride (BiOCl) plates synthesized using chloramine-T as the chloride ion source were investigated. Thermally-activated structure rebuilding was monitored using broadband dielectric spectroscopy, which showed that the onset temperature of this process was 283 K. This rebuilding was related to the introduction of free chloride ions into [Bi2O2]2+ layers and their growth, which increased the intensity of the (101) diffraction peak. The electrical conductivity and dielectric permittivity were related to the movement of chloride ions between plates (in the low-frequency region), the interplanar motion of Cl− ions at higher frequencies, vibrations of these ions, and charge carrier hopping at frequencies above 10 kHz. The influence of the free chloride ion concentration on the electrical conductivity was also described. Structure rebuilding was associated with a lower concentration of free chloride ions, which significantly decreased the conductivity. According to the analysis, the BiOCl plate conductivity was related to the movement of Cl− ions, not electrons.

Broadband dielectric spectroscopy on glycerol and CKN

1996 ◽  
Vol 176 (1) ◽  
pp. 33-41 ◽  
Author(s):  
A. Pimenov ◽  
P. Lunkenheimer ◽  
A. Loidl
Keyword(s):  
Dielectric Spectroscopy ◽  
Broadband Dielectric Spectroscopy
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