Theoretical study of photodetachment spectroscopy of hydrogenated boron cluster anion H2B7− and its deuterated isotopomer

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Herein, we demonstrate that the bench stable <i>closo</i>-hexaborate cluster anion can engage in a nucleophilic substitution reaction with a wide array of organic and main group electrophiles. The resulting molecules containing B‒C bonds can be further converted to tricoordinate boron species widely used in organic synthesis.<br>


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