IUPAC-NIST Solubility Data Series. 104. Lithium Sulfate and its Double Salts in Aqueous Solutions

2017 ◽  
Vol 46 (2) ◽  
pp. 023101 ◽  
Author(s):  
Julia Sohr ◽  
Wolfgang Voigt ◽  
Dewen Zeng
Keyword(s):  
Aqueous Solutions ◽  
Solubility Data ◽  
Data Series ◽  
Lithium Sulfate ◽  
Double Salts

Solubility phenomena in science and education: Experiments, thermodynamic analyses, and theoretical aspects

2013 ◽  
Vol 85 (11) ◽  
pp. 2059-2076 ◽  
Author(s):  
Heinz Gamsjäger
Keyword(s):  
Aqueous Solutions ◽  
International Symposium ◽  
Solubility Data ◽  
Data Series ◽  
The Third ◽  
Ionic Solids ◽  
Salt Hydrates ◽  
Science And Education ◽  
Hydrolysis Of

Solubility equilibria between solid salts, salt hydrates, and water play an important role in fundamental and applied branches of chemistry. The continuous interest in this field has been reflected by the 15th International Symposium on Solubility Phenomena as well as by the ongoing IUPAC-NIST Solubility Data Series (SDS), which by now comprises close to 100 volumes. Three typical examples concerning solubility phenomena of ionic solids in aqueous solutions are discussed: (1) sparingly soluble, simple molybdates; (2) sparingly soluble ionic solids with basic anions; and (3) hydrolysis of inert hexa-aqua-M(III) ions, where M is Ir, Rh, or Cr. In the first two cases, essential experimental details are discussed, an outline of thermodynamic analyses is given, and theoretical aspects are emphasized. In the third case, an educational suggestion is made.

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