Structural investigation of room-temperature ionic liquids and high-temperature ionic melts using triplet correlation functions

2017 ◽  
Vol 146 (9) ◽  
pp. 094503 ◽  
Author(s):  
Debdas Dhabal ◽  
Aditya Gupta ◽  
Hemant K. Kashyap
Keyword(s):  
Ionic Liquids ◽  
High Temperature ◽  
Correlation Functions ◽  
Room Temperature ◽  
Structural Investigation ◽  
Room Temperature Ionic Liquids ◽  
Ionic Melts ◽  
Triplet Correlation

Substitution of Conventional High-temperature Syntheses of Inorganic Compounds by Near-room-temperature Syntheses in Ionic Liquids

2013 ◽  
Vol 68 (10) ◽  
pp. 1108-1122 ◽  
Author(s):  
Matthias F. Groh ◽  
Ulrike Müller ◽  
Ejaz Ahmed ◽  
Alexander Rothenberger ◽  
Michael Ruck
Keyword(s):  
Ionic Liquids ◽  
High Temperature ◽  
Room Temperature ◽  
Inorganic Compounds ◽  
Chemical Transport ◽  
Room Temperature Ionic Liquids ◽  
X Ray Diffraction ◽  
One Pot ◽  
X Ray

The high-temperature syntheses of the low-valent halogenides P2I4, Te2Br, a-Te4I4, Te4(Al2Cl7)2, Te4(Bi6Cl20), Te8(Bi4Cl14), Bi8(AlCl4)2, Bi6Cl7, and Bi6Br7, as well as of WSCl4 and WOCl4 have been replaced by resource-efficient low-temperature syntheses in room temperature ionic liquids (RTILs). The simple one-pot syntheses generally do not require elaborate equipment such as two zone furnaces or evacuated silica ampoules. Compared to the published conventional approaches, reduction of reaction time (up to 80%) and temperature (up to 500 K) and, simultaneously, an increase in yield were achieved. In the majority of cases, the solid products were phase-pure. X-Ray diffraction on single crystals (redetermination of 11 crystal structures) has demonstrated that the quality of the crystals from RTILs is comparable to that of products obtained by chemical transport reactions.

scholarly journals Structure and dynamics of room temperature ionic liquids with bromide anion: results from 81 Br NMR spectroscopy

2015 ◽  
Vol 53 (5) ◽  
pp. 369-378 ◽  
Author(s):  
Takatsugu Endo ◽  
Mamoru Imanari ◽  
Yuki Hidaka ◽  
Hiroko Seki ◽  
Keiko Nishikawa ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Nmr Spectroscopy ◽  
Room Temperature ◽  
Room Temperature Ionic Liquids ◽  
Bromide Anion ◽  
Structure And Dynamics
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