Adiabatic electron affinity of pentacene and perfluoropentacene molecules studied by anion photoelectron spectroscopy: Molecular insights into electronic properties

2016 ◽  
Vol 145 (24) ◽  
pp. 244306 ◽  
Author(s):  
Tsugunosuke Masubuchi ◽  
Yoshito Sugawara ◽  
Atsushi Nakajima
Keyword(s):  
Electronic Properties ◽  
Electron Affinity ◽  
Photoelectron Spectroscopy ◽  
Adiabatic Electron Affinity ◽  
Anion Photoelectron Spectroscopy

Anion photoelectron spectroscopy of free [Au25(SC12H25)18]−

Nanoscale ◽  
2017 ◽  
Vol 9 (36) ◽  
pp. 13409-13412 ◽  
Author(s):  
Keisuke Hirata ◽  
Keishiro Yamashita ◽  
Satoru Muramatsu ◽  
Shinjiro Takano ◽  
Keijiro Ohshimo ◽  
...  
Keyword(s):  
Electron Affinity ◽  
Photoelectron Spectroscopy ◽  
Adiabatic Electron Affinity ◽  
Anion Photoelectron Spectroscopy

The adiabatic electron affinity of [Au25(SC12H25)18]0 was experimentally determined to be 2.2 eV by anion photoelectron spectroscopy.

Dynamical fluxionality, multiplicity of structural forms, and electronic properties of the B3Si11 cluster: anion photoelectron spectroscopy and theoretical calculations

2019 ◽  
Vol 21 (23) ◽  
pp. 12241-12249 ◽  
Author(s):  
Sheng-Jie Lu ◽  
Li-Shun Wu ◽  
Bao-Hua Yin ◽  
Feng Lin ◽  
Ming-Yong Chao
Keyword(s):  
Electronic Properties ◽  
Photoelectron Spectroscopy ◽  
Sandwich Structure ◽  
Theoretical Calculations ◽  
Cluster Anion ◽  
Membered Ring ◽  
Pentagonal Bipyramid ◽  
Anion Photoelectron Spectroscopy

B3Si11− is formed by the fusion of a B3Si7 bicapped tetragonal antiprism to a B3Si4 pentagonal bipyramid by sharing a B3 triangle, while neutral B3Si11 has a B3-endohedral sandwich structure composed of a Si5 five-membered ring and a Si6 six-membered ring.

Structures and electronic properties of B2Si6−/0/+: anion photoelectron spectroscopy and theoretical calculations

RSC Advances ◽  
2016 ◽  
Vol 6 (67) ◽  
pp. 62165-62171 ◽  
Author(s):  
Guo-Jin Cao ◽  
Sheng-Jie Lu ◽  
Hong-Guang Xu ◽  
Xi-Ling Xu ◽  
Wei-Jun Zheng
Keyword(s):  
Electronic Properties ◽  
Silicon Atom ◽  
Chemical Bonding ◽  
Photoelectron Spectroscopy ◽  
Theoretical Calculations ◽  
Anion Photoelectron Spectroscopy

The lowest-energy structures of B2Si6q(q= −1, 0, +1) clusters are a peculiar structure with a silicon atom hanging over a distorted bowl-like B2Si5framework. It is characterized with σ or π delocalization in chemical bonding.

Structural evolution and electronic properties of CoSin− (n = 3–12) clusters: mass-selected anion photoelectron spectroscopy and quantum chemistry calculations

2019 ◽  
Vol 21 (11) ◽  
pp. 6207-6215 ◽  
Author(s):  
Bin Yang ◽  
Xi-Ling Xu ◽  
Hong-Guang Xu ◽  
Umar Farooq ◽  
Wei-Jun Zheng
Keyword(s):  
Quantum Chemistry ◽  
Electronic Properties ◽  
Photoelectron Spectroscopy ◽  
Theoretical Calculations ◽  
Structural Evolution ◽  
Experimental Measurements ◽  
Quantum Chemistry Calculations ◽  
Vertical Detachment Energy ◽  
Anion Photoelectron Spectroscopy

Experimental measurements and theoretical calculations show that CoSi10− has the highest vertical detachment energy among all the CoSin− (n = 3–12) clusters, implying CoSi10− has special stability.

Structural and electronic properties of HCnS− (n = 4–11): anion photoelectron spectroscopy and density functional calculations

RSC Advances ◽  
2016 ◽  
Vol 6 (81) ◽  
pp. 78064-78072
Author(s):  
Xi-Ling Xu ◽  
Bin Yang ◽  
Hong-Guang Xu ◽  
Xiao-Jiao Deng ◽  
Wei-Jun Zheng
Keyword(s):  
Electronic Properties ◽  
Photoelectron Spectroscopy ◽  
Density Functional Calculations ◽  
Density Functional ◽  
Carbon Chain ◽  
Structural And Electronic Properties ◽  
Anion Photoelectron Spectroscopy

The structures of HCnS− are all linear with the H and S atoms locating at two ends of the carbon chain. Their VDEs exhibit a strong odd–even alternation.

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