A Peltier cooling diamond anvil cell for low-temperature Raman spectroscopic measurements

2016 ◽  
Vol 87 (12) ◽  
pp. 125107 ◽  
Author(s):  
Naoki Noguchi ◽  
Takuo Okuchi
2000 ◽  
Vol 17 (8) ◽  
pp. 555-557 ◽  
Author(s):  
Xu Li-Wen ◽  
Che Rong-Zheng ◽  
Jin Chang-Qing

2006 ◽  
Vol 62 (6) ◽  
pp. 1090-1098 ◽  
Author(s):  
Marcin Podsiadło ◽  
Kamil Dziubek ◽  
Marek Szafrański ◽  
Andrzej Katrusiak

Dibromomethane, CH2Br2, and diiodomethane, CH2I2, have been in situ pressure-crystallized in a diamond–anvil cell and their structures determined by single-crystal X-ray diffraction at 0.61 and 0.16 GPa, respectively. The pressure-frozen CH2Br2 crystal is isostructural with its C2/c phase obtained by cooling. CH2I2 is known to form several phases at low temperature, one of which is isostructural with CH2Br2. However, pressure freezing leads to the polar Fmm2 phase. The formation of the polar CH2I2 structure at 0.16 GPa has been rationalized by the electrostatic and anisotropic van der Waals interactions of the I atoms. No ferroelectric behaviour of the Fmm2 polar phase II of CH2I2 has been determined. The diffraction, calorimetric and dielectric constant studies reveal considerable temperature hysteresis of transformations between the CH2I2 phases, as well as metastable regions strongly dependent on the sample shape and history.


2012 ◽  
Vol 112 (12) ◽  
pp. 124503 ◽  
Author(s):  
Hitoshi Yamaoka ◽  
Yumiko Zekko ◽  
Ignace Jarrige ◽  
Jung-Fu Lin ◽  
Nozomu Hiraoka ◽  
...  

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