The determination of ionic transport properties at high pressures in a diamond anvil cell

2016 ◽  
Vol 87 (12) ◽  
pp. 123904 ◽  
Author(s):  
Qinglin Wang ◽  
Cailong Liu ◽  
Yonghao Han ◽  
Chunxiao Gao ◽  
Yanzhang Ma
Keyword(s):  
Transport Properties ◽  
Diamond Anvil Cell ◽  
High Pressures ◽  
Ionic Transport ◽  
Diamond Anvil

scholarly journals Phase transitions beyond post-perovskite in NaMgF3 to 160 GPa

2019 ◽  
Vol 116 (39) ◽  
pp. 19324-19329 ◽  
Author(s):  
Rajkrishna Dutta ◽  
Eran Greenberg ◽  
Vitali B. Prakapenka ◽  
Thomas S. Duffy
Keyword(s):  
Phase Transitions ◽  
Diamond Anvil Cell ◽  
Extrasolar Planets ◽  
High Pressures ◽  
Model System ◽  
Similar Sequence ◽  
Deep Interior ◽  
Diamond Anvil ◽  
Binary Compounds ◽  
Pressure Phase

Neighborite, NaMgF3, is used as a model system for understanding phase transitions in ABX3 systems (e.g., MgSiO3) at high pressures. Here we report diamond anvil cell experiments that identify the following phases in NaMgF3 with compression to 162 GPa: NaMgF3 (perovskite) → NaMgF3 (post-perovskite) → NaMgF3 (Sb2S3-type) → NaF (B2-type) + NaMg2F5 (P21/c) → NaF (B2) + MgF2 (cotunnite-type). Our results demonstrate the existence of an Sb2S3-type post-post-perovskite ABX3 phase. We also experimentally demonstrate the formation of the P21/c AB2X5 phase which has been proposed theoretically to be a common high-pressure phase in ABX3 systems. Our study provides an experimental observation of the full sequence of phase transitions from perovskite to post-perovskite to post-post-perovskite followed by 2-stage breakdown to binary compounds. Notably, a similar sequence of transitions is predicted to occur in MgSiO3 at ultrahigh pressures, where it has implications for the mineralogy and dynamics in the deep interior of large, rocky extrasolar planets.

scholarly journals The thermal conductivity of the Earth's core and implications for its thermal and compositional evolution

2020 ◽  
Author(s):  
Kenji Ohta ◽  
Kei Hirose
Keyword(s):  
Thermal Conductivity ◽  
High Pressure ◽  
Thermal History ◽  
Diamond Anvil Cell ◽  
High Pressures ◽  
Iron Alloys ◽  
Compositional Evolution ◽  
The Earth ◽  
Diamond Anvil ◽  
High Pressures And Temperatures

Abstract Precise determinations of the thermal conductivity of iron alloys at high pressures and temperatures are essential for understanding the thermal history and dynamics of the metallic cores of the Earth. We review relevant high-pressure experiments using a diamond-anvil cell and discuss implications of high core conductivity for its thermal and compositional evolution.

The Fluorescence of Diamond and Raman Spectroscopy at High Pressures Using a New Design of Diamond Anvil Cell

1973 ◽  
Vol 27 (5) ◽  
pp. 377-381 ◽  
Author(s):  
D. M. Adams ◽  
S. J. Payne ◽  
K. Martin
Keyword(s):  
Raman Spectroscopy ◽  
Diamond Anvil Cell ◽  
High Pressures ◽  
Fluorescence Emission ◽  
Type I ◽  
High Pressure Cell ◽  
Scattering Geometry ◽  
Infrared And Raman Spectroscopy ◽  
Bond Stretching ◽  
Diamond Anvil

A new design of diamond anvil high pressure cell suitable for use in infrared and Raman spectroscopy is described. Its performance is demonstrated with particular reference to the pressure dependence of the infrared spectrum of K2PtCl6 and the Raman spectrum of W(CO)6. In contrast to earlier reports, in which forward scattering geometry was used, this design of cell is shown to be very suitable for Raman use in the 180° excitation mode. However, severe limitations are imposed by the fluorescence emission of diamond and of sapphire. Conditions under which the cell can be used for Raman work are summarized. New fluorescence and Raman features are reported for diamond. In particular, a band at 1730 cm−1 is characteristic of type I stones and may be due to C to N bond stretching at defect centers.

J0420306 Evaluation of elastic property of Pt thin film at high pressures using picosecond ultrasound coupled with diamond anvil cell

2014 ◽  
Vol 2014 (0) ◽  
pp. _J0420306--_J0420306-
Author(s):  
Shu SEKIGUCHI ◽  
Nobutomo NAKAMURA ◽  
Mari EINAGA ◽  
Katsuya SHIMIZU ◽  
Atsushi MIYAKE ◽  
...  
Keyword(s):  
Thin Film ◽  
Elastic Property ◽  
Diamond Anvil Cell ◽  
High Pressures ◽  
Diamond Anvil

scholarly journals An improved setup for radial diffraction experiments at high pressures and high temperatures in a resistive graphite-heated diamond anvil cell

2020 ◽  
Vol 91 (4) ◽  
pp. 045121 ◽  
Author(s):  
J. Immoor ◽  
H. Marquardt ◽  
L. Miyagi ◽  
S. Speziale ◽  
S. Merkel ◽  
...  
Keyword(s):  
High Temperatures ◽  
Diamond Anvil Cell ◽  
High Pressures ◽  
Diamond Anvil
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