Modeling of heat evolution in silicate building materials with electrically conductive admixtures

Author(s):  
Lukáš Fiala ◽  
Jiří Maděra ◽  
Eva Vejmelková ◽  
Robert Černý
2020 ◽  
Vol 24 (2 Part A) ◽  
pp. 787-794
Author(s):  
Lukas Fiala ◽  
Jiri Madera ◽  
Robert Cerny

Design of progressive building materials with increased utility value is the key issue for the development of reliable modern building structures. Compared to the conventional materials, progressive building materials are supposed to exhibit not just adequate mechanical, and thermal properties, but they are also supposed to be applicable in sophisticated solutions, such as in self-sensing, self-heating or magnetic-shielding systems. In terms of electric properties, the most of building materials are electric insulators which is the main limiting factor for their applicability in such sophisticated solutions. However, this deficiency can be solved by the addition of a proper amount of electrically conductive admixtures. Within the paper, electrically conductive alkali-activated aluminosilicate with 8.89 mass.% of carbon black admixture was designed and its materials properties necessary for calculations of heat evolution by the action of an electric source were experimentally determined. The electrical conductivity of such material equal to 5.57?10?2 S m?1 was sufficiently high to ensure self-heating ability. It was observed good agreement of experimentally determined data with those modeled by means of heat equation on sample with dimensions 40 ? 40 ? 10 mm. Finally, one- and two-layered large-scaled heating elements based on materials with experimentally determined properties were designed and calculations were conducted to determine the voltage level necessary for one-hour heating from 268.15 K and 273.15 K to 278.15 K in the middle-top point of the construction.


Energies ◽  
2019 ◽  
Vol 12 (21) ◽  
pp. 4121 ◽  
Author(s):  
Lukáš Fiala ◽  
Michaela Petříková ◽  
Wei-Ting Lin ◽  
Luboš Podolka ◽  
Robert Černý

Sustainable development in the construction industry can be achieved by the design of multifunctional materials with good mechanical properties, durability, and reasonable environmental impacts. New functional properties, such as self-sensing, self-heating, or energy harvesting, are crucially dependent on electrical properties, which are very poor for common building materials. Therefore, various electrically conductive admixtures are used to enhance their electrical properties. Geopolymers based on waste or byproduct precursors are promising materials that can gain new functional properties by adding a reasonable amount of electrically conductive admixtures. The main aim of this paper lies in the design of multifunctional geopolymers with self-heating abilities. Designed geopolymer mortars based on blast-furnace slag activated by water glass and 6 dosages of carbon black (CB) admixture up to 2.25 wt. % were studied in terms of basic physical, mechanical, thermal, and electrical properties (DC). The self-heating ability of the designed mortars was experimentally determined at 40 and 100 V loads. The percolation threshold for self-heating was observed at 1.5 wt. % of carbon black with an increasing self-heating performance for higher CB dosages. The highest power of 26 W and the highest temperature increase of about 110 °C were observed for geopolymers with 2.25 wt. % of carbon black admixture at 100 V.


Author(s):  
K. A. Fisher ◽  
M. G. L. Gustafsson ◽  
M. B. Shattuck ◽  
J. Clarke

The atomic force microscope (AFM) is capable of imaging electrically conductive and non-conductive surfaces at atomic resolution. When used to image biological samples, however, lateral resolution is often limited to nanometer levels, due primarily to AFM tip/sample interactions. Several approaches to immobilize and stabilize soft or flexible molecules for AFM have been examined, notably, tethering coating, and freezing. Although each approach has its advantages and disadvantages, rapid freezing techniques have the special advantage of avoiding chemical perturbation, and minimizing physical disruption of the sample. Scanning with an AFM at cryogenic temperatures has the potential to image frozen biomolecules at high resolution. We have constructed a force microscope capable of operating immersed in liquid n-pentane and have tested its performance at room temperature with carbon and metal-coated samples, and at 143° K with uncoated ferritin and purple membrane (PM).


Author(s):  
J. R. Millette ◽  
R. S. Brown

The United States Environmental Protection Agency (EPA) has labeled as “friable” those building materials that are likely to readily release fibers. Friable materials when dry, can easily be crumbled, pulverized, or reduced to powder using hand pressure. Other asbestos containing building materials (ACBM) where the asbestos fibers are in a matrix of cement or bituminous or resinous binders are considered non-friable. However, when subjected to sanding, grinding, cutting or other forms of abrasion, these non-friable materials are to be treated as friable asbestos material. There has been a hypothesis that all raw asbestos fibers are encapsulated in solvents and binders and are not released as individual fibers if the material is cut or abraded. Examination of a number of different types of non-friable materials under the SEM show that after cutting or abrasion, tuffs or bundles of fibers are evident on the surfaces of the materials. When these tuffs or bundles are examined, they are shown to contain asbestos fibers which are free from binder material. These free fibers may be released into the air upon further cutting or abrasion.


Author(s):  
Mykhailo Kosmii ◽  
Vasyl. Kasiianchuk ◽  
Ruslan Zhyrak ◽  
Ivan Krykhovetskyi

The purpose of this paper is to analyze and research the legal mechanisms which make it possible to improve agroecology through the organization of cultivation of Jerusalem artichoke.Methodology. The methodology includes comprehensive analysis and generalization of available scientific, theoretical, practical and applied material and development of relevant conclusions and recommendations. During the research, the following methods of scientific cognition were used: dialectical, terminological, historical and legal, logical and normative, systemic and structural, functional, normative and dogmatic, generalization methods. Results. The process of analysis and research highlighted the possibilities of cultivating Jerusalem artichoke for improving agroecology, namely improving the ecological state of the atmosphere air and soil, preparing them for organic farming. The article contains examples of practical application of tubers of Jerusalem artichoke and herbage for the production of therapeutic and prophylactic products, alternative energy and highly efficient building materials. Scientific novelty. The study found that the authors summarized and systematized the levels of legal regulation in the field of using Jerusalem artichoke for improving agroecology, preparing soil for organic farming, in particular: the inter-sectoral level which covers the interaction of agricultural and environmental law in terms of cultivation and use of Jerusalem artichoke; the level of integrated environmental and legal regulation; level of individual resource (floristic) legal regulation; the level of environmental protection (anthropoprotection) legislation.Practical importance. The results of the study can be used in law-making and environmental protection activities related to issues of cultivating and using the Jerusalem artichoke as a means of improving agroecology.


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