scholarly journals Development of an electrochemically integrated SR-GIXRD flow cell to study FeCO3 formation kinetics

2016 ◽  
Vol 87 (10) ◽  
pp. 105125 ◽  
Author(s):  
D. Burkle ◽  
R. De Motte ◽  
W. Taleb ◽  
A. Kleppe ◽  
T. Comyn ◽  
...  
Keyword(s):  
1992 ◽  
Vol 6 (3) ◽  
pp. 193-198 ◽  
Author(s):  
Ching-Tsan Huang ◽  
Steven W. Peretti ◽  
James D. Bryers

2009 ◽  
Vol 404 (23-24) ◽  
pp. 4576-4578
Author(s):  
Nikolai Yarykin ◽  
Jörg Weber

2006 ◽  
Vol 78 (5) ◽  
pp. 1657-1664 ◽  
Author(s):  
Khanh C. Hoang ◽  
Dmitry Malakhov ◽  
William E. Momsen ◽  
Howard L. Brockman

Molecules ◽  
2019 ◽  
Vol 24 (17) ◽  
pp. 3065
Author(s):  
Juan Lv ◽  
Yan Wang ◽  
Na Li

The highly prescribed antidepressant, citalopram, as one of newly emerging pollutants, has been frequently detected in the aquatic environment. Citalopram oxidation was examined during sodium hypochlorite (NaOCl) and chlorine dioxide (ClO2) chlorination processes since conventional wastewater treatment plants cannot remove citalopram effectively. Citalopram has been demonstrated to form N-nitrosodimethylamine (NDMA) during chlorination in our previous study. Further investigation on NDMA formation kinetics was conducted in the present study. Influences of operational variables (disinfectant dose, pH value) and water matrix on citalopram degradation, as well as NDMA generation, were evaluated. The results indicated high reactivity of citalopram with NaOCl and ClO2. NDMA formation included two stages during CIT oxidation, which were linear related with reaction time. NaOCl was more beneficial to remove CIT, but it caused more NDMA formation. Increasing disinfectant dosage promoted citalopram removal and NDMA formation. However, no consistent correlation was found between citalopram removal and pH. Contrary to the situation of citalopram removal, NDMA generation was enhanced when citalopram was present in actual water matrices, especially in secondary effluent. DMA, as an intermediate of citalopram chlorination, contributed to NDMA formation, but not the only way.


Author(s):  
L.N. Moskvin ◽  
О.V. Rodinkov ◽  
А.L. Moskvin ◽  
V. Spivakovskii ◽  
A.Y. Vlasov ◽  
...  

2021 ◽  
Author(s):  
A. A. Barzov ◽  
A. L. Galinovskiy ◽  
A. I. Denchik ◽  
Kyaw Myo Htet

Energies ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 1109
Author(s):  
Robert Bock ◽  
Björn Kleinsteinberg ◽  
Bjørn Selnes-Volseth ◽  
Odne Stokke Burheim

For renewable energies to succeed in replacing fossil fuels, large-scale and affordable solutions are needed for short and long-term energy storage. A potentially inexpensive approach of storing large amounts of energy is through the use of a concentration flow cell that is based on cheap and abundant materials. Here, we propose to use aqueous iron chloride as a reacting solvent on carbon electrodes. We suggest to use it in a red-ox concentration flow cell with two compartments separated by a hydrocarbon-based membrane. In both compartments the red-ox couple of iron II and III reacts, oxidation at the anode and reduction at the cathode. When charging, a concentration difference between the two species grows. When discharging, this concentration difference between iron II and iron III is used to drive the reaction. In this respect it is a concentration driven flow cell redox battery using iron chloride in both solutions. Here, we investigate material combinations, power, and concentration relations.


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