scholarly journals Surface degradation of Li1–xNi0.80Co0.15Al0.05O2 cathodes: Correlating charge transfer impedance with surface phase transformations

2016 ◽  
Vol 108 (26) ◽  
pp. 263902 ◽  
Author(s):  
S. Sallis ◽  
N. Pereira ◽  
P. Mukherjee ◽  
N. F. Quackenbush ◽  
N. Faenza ◽  
...  
Nanoscale ◽  
2019 ◽  
Vol 11 (34) ◽  
pp. 15881-15891 ◽  
Author(s):  
Yong Xu ◽  
Jun Chen ◽  
Ze'en Xiao ◽  
Caixia Ou ◽  
Weixia Lv ◽  
...  

A novel porous diatomite composite electrode composed of NTCDA nanowires exhibits lower charge transfer impedance, higher capacity and better rate performance.


2011 ◽  
Vol 19 ◽  
pp. 331-336 ◽  
Author(s):  
V. Schulze ◽  
J. Michna ◽  
J. Schneider ◽  
P. Gumbsch

Materials ◽  
2020 ◽  
Vol 13 (3) ◽  
pp. 779
Author(s):  
Liangshou Hao ◽  
Feng Zheng ◽  
Xiaoping Chen ◽  
Jiayang Li ◽  
Shengping Wang ◽  
...  

To optimize the operating temperature and flow velocity of cooling water in a high voltage direct current (HVDC) thyristor valve cooling system, the erosion corrosion characteristics of aluminum electrodes in deionized water at various temperatures were studied. With increasing water temperature, the corrosion current of the aluminum electrode gradually increases and the charge transfer impedance gradually decreases, thus, the corrosion of aluminum tends to become serious. The aluminum electrode in 50 °C deionized water has the most negative corrosion potential (−0.930 V), the maximum corrosion current (1.115 × 10−6 A cm−2) and the minimum charge transfer impedance (8.828 × 10−6 Ω), thus, the aluminum corrosion at this temperature is the most serious. When the temperature of deionized water increases, the thermodynamic activity of the ions and dissolved oxygen in the deionized water increases, and the mass transfer process accelerates. Therefore, the electrochemical corrosion reaction of the aluminum surface will be accelerated. The corrosion products covering the aluminum electrode surface are mainly Al(OH)3. With increasing water temperature, the number of pits and grooves formed by corrosion on the aluminum surface increased. In this paper, the molar activation energy Ea and the equilibrium constant K of the aluminum corrosion reaction with various temperatures are calculated. This clarifies the effect of temperature on the aluminum corrosion reaction, which provides a basis for protecting aluminum from corrosion. The results of this study will contribute to research that is focused on the improvement of production techniques used for HVDC thyristor valve cooling systems.


1996 ◽  
Vol 363 (1-3) ◽  
pp. 289-295 ◽  
Author(s):  
Z.C. Ying ◽  
J. Wang ◽  
E.W. Plummer

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