scholarly journals Enhanced salt-removal percentage in capacitive deionization with addition of ion-exchange membrane using carbon electrode synthesized with freezing thawing method

2016 ◽  
Author(s):  
Intan Permata Sari ◽  
Endarko
Keyword(s):  
Ion Exchange ◽  
Ion Exchange Membrane ◽  
Carbon Electrode ◽  
Capacitive Deionization ◽  
Exchange Membrane

scholarly journals Exploring the Function of Ion-Exchange Membrane in Membrane Capacitive Deionization via a Fully Coupled Two-Dimensional Process Model

Processes ◽  
2020 ◽  
Vol 8 (10) ◽  
pp. 1312
Author(s):  
Xin Zhang ◽  
Danny Reible
Keyword(s):  
Ion Exchange ◽  
Removal Efficiency ◽  
Cycle Time ◽  
Process Model ◽  
Ion Exchange Membrane ◽  
Membrane Thickness ◽  
Two Dimensional ◽  
Capacitive Deionization ◽  
Exchange Membrane ◽  
Fully Coupled

In the arid west, the freshwater supply of many communities is limited, leading to increased interest in tapping brackish water resources. Although reverse osmosis is the most common technology to upgrade saline waters, there is also interest in developing and improving alternative technologies. Here we focus on membrane capacitive deionization (MCDI), which has attracted broad attention as a portable and energy-efficient desalination technology. In this study, a fully coupled two-dimensional MCDI process model capable of capturing transient ion transport and adsorption behaviors was developed to explore the function of the ion-exchange membrane (IEM) and detect MCDI influencing factors via sensitivity analysis. The IEM enhanced desalination by improving the counter-ions’ flux and increased adsorption in electrodes by encouraging retention of ions in electrode macropores. An optimized cycle time was proposed with maximal salt removal efficiency. The usage of the IEM, high applied voltage, and low flow rate were discovered to enhance this maximal salt removal efficiency. IEM properties including water uptake volume fraction, membrane thickness, and fixed charge density had a marginal impact on cycle time and salt removal efficiency within certain limits, while increasing cell length and electrode thickness and decreasing channel thickness and dispersivity significantly improved overall performance.

Selective removal of lead ions through capacitive deionization: Role of ion-exchange membrane

2019 ◽  
Vol 361 ◽  
pp. 1535-1542 ◽  
Author(s):  
Qianqian Dong ◽  
Xiaoru Guo ◽  
Xingkang Huang ◽  
Lianjun Liu ◽  
Rebecca Tallon ◽  
...  
Keyword(s):  
Ion Exchange ◽  
Selective Removal ◽  
Ion Exchange Membrane ◽  
Lead Ions ◽  
Capacitive Deionization ◽  
Exchange Membrane

The role of ion exchange membrane in vanadium oxygen fuel cell

2021 ◽  
Vol 629 ◽  
pp. 119271
Author(s):  
Jiří Charvát ◽  
Petr Mazúr ◽  
Martin Paidar ◽  
Jaromír Pocedič ◽  
Jiří Vrána ◽  
...  
Keyword(s):  
Fuel Cell ◽  
Ion Exchange ◽  
Ion Exchange Membrane ◽  
Exchange Membrane ◽  
Oxygen Fuel

scholarly journals Transparent Ion-Exchange Membrane Exhibiting Intense Emission under a Specific pH Condition Based on Polypyridyl Ruthenium(II) Complex with Two Imidazophenanthroline Groups

Membranes ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 400
Author(s):  
Hajime Kamebuchi ◽  
Satoshi Tamaki ◽  
Atsushi Okazawa ◽  
Norimichi Kojima
Keyword(s):  
Ion Exchange ◽  
Emission Intensity ◽  
Density Functional ◽  
Emission Spectra ◽  
Density Functional Theory Calculations ◽  
Ion Exchange Membrane ◽  
Quantum Yields ◽  
Relative Emission Intensity ◽  
Nafion Film ◽  
Exchange Membrane

The development and the photophysical behavior of a transparent ion-exchange membrane based on a pH-sensitive polypyridyl ruthenium(II) complex, [(bpy)2RuII(H2bpib)RuII(bpy)2](ClO4)4 (bpy = 2,2′-bipyridine, H2bpib = 1,4-bis([1,10]phenanthroline[5,6-d]-imidazol-2-yl)benzene), are experimentally and theoretically reported. The emission spectra of [(bpy)2RuII(H2bpib)RuII(bpy)2]@Nafion film were observed between pH 2 and pH 11 and showed the highest relative emission intensity at pH 5 (λmaxem = 594.4 nm). The relative emission intensity of the film significantly decreased down to 75% at pH 2 and 11 compared to that of pH 5. The quantum yields (Φ) and lifetimes (τ) showed similar correlations with respect to pH, Φ = 0.13 and τ = 1237 ns at pH 5, and Φ = 0.087 and τ = 1014 ns and Φ = 0.069 and τ = 954 ns at pH 2 and pH 11, respectively. These photophysical data are overall considerably superior to those of the solution, with the radiative- (kr) and non-radiative rate constants (knr) at pH 5 estimated to be kr = 1.06 × 105 s−1 and knr = 7.03 × 105 s−1. Density functional theory calculations suggested the contribution of ligand-to-ligand- and intraligand charge transfer to the imidazolium moiety in Ru-H3bpib species, implying that the positive charge on the H3bpib ligand works as a quencher. The Ru-Hbpib species seems to enhance non-radiative deactivation by reducing the energy of the upper-lying metal-centered excited state. These would be responsible for the pH-dependent “off-on-off” emission behavior.

scholarly journals Fabrication of a lead ion selective membrane based on a polycarbazole Sn(iv) arsenotungstate nanocomposite and its ion exchange membrane (IEM) kinetic studies

RSC Advances ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 4210-4220
Author(s):  
Mohd. Zeeshan ◽  
Rais Ahmad ◽  
Asif Ali Khan ◽  
Aftab Aslam Parwaz Khan ◽  
Guillermo C. Bazan ◽  
...  
Keyword(s):  
Ion Exchange ◽  
Polyvinyl Chloride ◽  
Cation Exchanger ◽  
Kinetic Studies ◽  
Ion Exchange Membrane ◽  
Lead Ion ◽  
Solution Technique ◽  
Casting Solution ◽  
Selective Membrane ◽  
Exchange Membrane

A polycarbazole-Sn(iv) arsenotungstate (Pcz-SnAT) nanocomposite cation exchanger membrane (CEM) was prepared via the casting solution technique utilizing polycarbazole-Sn(iv) arsenotungstate and PVC (polyvinyl chloride) as a binder.

Synthesis of ion exchange membrane by radiation grafting of acrylic acid onto polyethylene

1981 ◽  
Vol 18 (5-6) ◽  
pp. 899-905 ◽  
Author(s):  
I. Ishigaki ◽  
T. Sugo ◽  
K. Senoo ◽  
T. Takayama ◽  
S. Machi ◽  
...  
Keyword(s):  
Ion Exchange ◽  
Acrylic Acid ◽  
Ion Exchange Membrane ◽  
Radiation Grafting ◽  
Exchange Membrane
Sign in / Sign up

Export Citation Format

Share Document