Enhancing the electron lifetime and diffusion coefficient in dye-sensitized solar cells by patterning the layer of TiO2 nanoparticles

2016 ◽  
Vol 119 (11) ◽  
pp. 114302 ◽  
Author(s):  
Mohammad Sajedi Alvar ◽  
Mohammad Javadi ◽  
Yaser Abdi ◽  
Ezatollah Arzi
2013 ◽  
Vol 2013 ◽  
pp. 1-7 ◽  
Author(s):  
En Mei Jin ◽  
Kyung-Hee Park ◽  
Ju-Young Park ◽  
Jae-Wook Lee ◽  
Soon-Ho Yim ◽  
...  

A chitosan binder-based TiO2photoelectrode is used in dye-sensitized solar cells (DSSCs). Field-emission scanning electron microscope (FE-SEM) images revealed that the grain size, thickness, and distribution of TiO2films are affected by the chitosan content. With addition of 2.0 wt% chitosan to the TiO2film (D2), the surface pore size became the smallest, and the pores were fairly evenly distributed. The electron transit time, electron recombination lifetime, diffusion coefficient, and diffusion length were analyzed by IMVS and IMPS. The best DSSC, with 2.0 wt% chitosan addition to the TiO2film, had a shorter electron transit time, longer electron recombination lifetime, and larger diffusion coefficient and diffusion length than the other samples. The results of 2.0 wt% chitosan-added TiO2DSSCs are an electron transit time of  s, electron recombination lifetime of  s, diffusion coefficient of  cm2s−1, diffusion length of 14.81 μm, and a solar conversion efficiency of 4.18%.


Energies ◽  
2018 ◽  
Vol 11 (11) ◽  
pp. 2922 ◽  
Author(s):  
Zainal Arifin ◽  
Suyitno Suyitno ◽  
Syamsul Hadi ◽  
Bayu Sutanto

In this study, dye-sensitized solar cells (DSSCs) were fabricated using double-layer photoanodes consisting of TiO2 nanoparticles (NPs) and Zn-doped TiO2 hollow fibers (HFs). The TiO2 HFs were prepared by co-axial electrospinning and used as the light-scattering layer in the DSSC. The thickness variations of the TiO2 NP and Zn-doped TiO2 HF photoanode layers affect the performance of the DSSC, especially the short-circuit photocurrent density. The thickness of the TiO2 NP layer significantly affected the absorbance of photons and N719 dye molecules in the double-layer photoanode, while that of the Zn-doped TiO2 HF layer affected the scattering of light, as indicated by the low light transmittance in the photoanode. Conventional DSSCs consist of single-layer photoanodes, and exhibit relatively low efficiency, i.e., 1.293% and 0.89% for TiO2 NP and Zn-doped TiO2 HF, respectively. However, herein, the highest efficiency of the DSSC (3.122%) was achieved with a 15 μm NP-5 μm HF photoanode, for which the short-circuit photocurrent density, open-circuit photovoltage, and fill factor were 15.81 mA/cm2, 0.566 V, and 34.91%, respectively.


2017 ◽  
Vol 43 (8) ◽  
pp. 4339-4352 ◽  
Author(s):  
Orawan Wiranwetchayan ◽  
Wonchai Promnopas ◽  
Supab Choopun ◽  
Pisith Singjai ◽  
Somchai Thongtem

RSC Advances ◽  
2017 ◽  
Vol 7 (4) ◽  
pp. 2358-2364 ◽  
Author(s):  
Hadja Fatima Mehnane ◽  
Changlei Wang ◽  
Kiran Kumar Kondamareddy ◽  
Wenjing Yu ◽  
Weiwei Sun ◽  
...  

Strontium (Sr) doped TiO2 nanoparticles are investigated with a view to studying the performance parameters of dye sensitized solar cells (DSSCs).


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