Effect of excluded volume on the force-extension of wormlike chains in slit confinement

2016 ◽  
Vol 144 (10) ◽  
pp. 104902 ◽  
Author(s):  
Xiaolan Li ◽  
Kevin D. Dorfman
Keyword(s):  
Excluded Volume ◽  
Force Extension

Modeling the stretching of wormlike chains in the presence of excluded volume

Soft Matter ◽  
2015 ◽  
Vol 11 (29) ◽  
pp. 5947-5954 ◽  
Author(s):  
Xiaolan Li ◽  
Charles M. Schroeder ◽  
Kevin D. Dorfman
Keyword(s):  
Interpolation Formula ◽  
Excluded Volume ◽  
Force Extension

An interpolation formula captures the effect of excluded volume on the force–extension of wormlike chains.

A Field Theory for Polymeric Networks with Excluded Volume

1995 ◽  
Vol 5 (10) ◽  
pp. 1241-1246 ◽  
Author(s):  
Thomas A. Vilgis ◽  
Michael P. Solf
Keyword(s):  
Field Theory ◽  
Excluded Volume ◽  
Polymeric Networks

scholarly journals An interplay of excluded-volume and polymer–(co)solvent attractive interactions regulates polymer collapse in mixed solvents

2021 ◽  
Vol 154 (13) ◽  
pp. 134903
Author(s):  
Swaminath Bharadwaj ◽  
Divya Nayar ◽  
Cahit Dalgicdir ◽  
Nico F. A. van der Vegt
Keyword(s):  
Mixed Solvents ◽  
Excluded Volume ◽  
Polymer Collapse

scholarly journals Spatial segregation of mixed-sized counterions in dendritic polyelectrolytes

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
J. S. Kłos ◽  
J. Paturej
Keyword(s):  
Electrostatic Interactions ◽  
Spatial Separation ◽  
Excluded Volume ◽  
The Core ◽  
Bjerrum Length ◽  
Two Component ◽  
Conformational Properties ◽  
Dynamics Simulations ◽  
Two Parameters ◽  
Swelling Factor

AbstractLangevin dynamics simulations are utilized to study the structure of a dendritic polyelectrolyte embedded in two component mixtures comprised of conventional (small) and bulky counterions. We vary two parameters that trigger conformational properties of the dendrimer: the reduced Bjerrum length, $$\lambda _B^*$$ λ B ∗ , which controls the strength of electrostatic interactions and the number fraction of the bulky counterions, $$f_b$$ f b , which impacts on their steric repulsion. We find that the interplay between the electrostatic and the counterion excluded volume interactions affects the swelling behavior of the molecule. As compared to its neutral counterpart, for weak electrostatic couplings the charged dendrimer exists in swollen conformations whose size remains unaffected by $$f_b$$ f b . For intermediate couplings, the absorption of counterions into the pervaded volume of the dendrimer starts to influence its conformation. Here, the swelling factor exhibits a maximum which can be shifted by increasing $$f_b$$ f b . For strong electrostatic couplings the dendrimer deswells correspondingly to $$f_b$$ f b . In this regime a spatial separation of the counterions into core–shell microstructures is observed. The core of the dendrimer cage is preferentially occupied by the conventional ions, whereas its periphery contains the bulky counterions.

scholarly journals On Using the BMCSL Equation of State to Renormalize the Onsager Theory Approach to Modeling Hard Prolate Spheroidal Liquid Crystal Mixtures

Entropy ◽  
2021 ◽  
Vol 23 (7) ◽  
pp. 846
Author(s):  
Donya Ohadi ◽  
David S. Corti ◽  
Mark J. Uline
Keyword(s):  
Equation Of State ◽  
Second Virial Coefficient ◽  
Virial Coefficients ◽  
Pure Component ◽  
Excluded Volume ◽  
Theory Approach ◽  
Prolate Spheroidal ◽  
Empirical Correction ◽  
Prolate Spheroids ◽  
Onsager Theory

Modifications to the traditional Onsager theory for modeling isotropic–nematic phase transitions in hard prolate spheroidal systems are presented. Pure component systems are used to identify the need to update the Lee–Parsons resummation term. The Lee–Parsons resummation term uses the Carnahan–Starling equation of state to approximate higher-order virial coefficients beyond the second virial coefficient employed in Onsager’s original theoretical approach. As more exact ways of calculating the excluded volume of two hard prolate spheroids of a given orientation are used, the division of the excluded volume by eight, which is an empirical correction used in the original Lee–Parsons resummation term, must be replaced by six to yield a better match between the theoretical and simulation results. These modifications are also extended to binary mixtures of hard prolate spheroids using the Boublík–Mansoori–Carnahan–Starling–Leland (BMCSL) equation of state.

Gelation of micellar solutions of diblock-copoly (oxyethylene/oxybutylene) in aqueous K2SO4. An investigation of excluded volume effects

1995 ◽  
Vol 33 (7) ◽  
pp. 1085-1096 ◽  
Author(s):  
Nan-Jie Deng ◽  
Yun-Zhu Luo ◽  
Siriporn Tanodekaew ◽  
Nicole Bingham ◽  
David Attwood ◽  
...  
Keyword(s):  
Excluded Volume ◽  
Micellar Solutions ◽  
Excluded Volume Effects ◽  
Volume Effects
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