The origins of near band-edge transitions in hexagonal boron nitride epilayers

2016 ◽  
Vol 108 (5) ◽  
pp. 052106 ◽  
Author(s):  
X. Z. Du ◽  
J. Li ◽  
J. Y. Lin ◽  
H. X. Jiang
Keyword(s):  
Boron Nitride ◽  
Hexagonal Boron Nitride ◽  
Band Edge ◽  
Near Band Edge

Time-resolved photoluminescence in band-edge region of hexagonal boron nitride single crystals

2008 ◽  
Vol 17 (4-5) ◽  
pp. 830-832 ◽  
Author(s):  
Kenji Watanabe ◽  
Takashi Taniguchi ◽  
Takashi Kuroda ◽  
Osamu Tsuda ◽  
Hisao Kanda
Keyword(s):  
Boron Nitride ◽  
Single Crystals ◽  
Hexagonal Boron Nitride ◽  
Band Edge ◽  
Edge Region ◽  
Time Resolved ◽  
Time Resolved Photoluminescence

Band-edge luminescence of deformed hexagonal boron nitride single crystals

2006 ◽  
Vol 15 (11-12) ◽  
pp. 1891-1893 ◽  
Author(s):  
Kenji Watanabe ◽  
Takashi Taniguchi ◽  
Takashi Kuroda ◽  
Hisao Kanda
Keyword(s):  
Boron Nitride ◽  
Single Crystals ◽  
Hexagonal Boron Nitride ◽  
Band Edge ◽  
Edge Luminescence ◽  
Band Edge Luminescence

Effects of deformation on band-edge luminescence of hexagonal boron nitride single crystals

2006 ◽  
Vol 89 (14) ◽  
pp. 141902 ◽  
Author(s):  
Kenji Watanabe ◽  
Takashi Taniguchi ◽  
Takashi Kuroda ◽  
Hisao Kanda
Keyword(s):  
Boron Nitride ◽  
Single Crystals ◽  
Hexagonal Boron Nitride ◽  
Band Edge ◽  
Edge Luminescence ◽  
Band Edge Luminescence

Band-edge transitions in hexagonal boron nitride epilayers

2012 ◽  
Vol 101 (5) ◽  
pp. 051110 ◽  
Author(s):  
S. Majety ◽  
X. K. Cao ◽  
J. Li ◽  
R. Dahal ◽  
J. Y. Lin ◽  
...  
Keyword(s):  
Boron Nitride ◽  
Hexagonal Boron Nitride ◽  
Band Edge

Marcus-Hush Theory Revealed by Electron Tunneling Through Hexagonal Boron Nitride

2019 ◽  
Author(s):  
Matěj Velický ◽  
Sheng Hu ◽  
Colin R. Woods ◽  
Peter S. Toth ◽  
Viktor Zólyomi ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Boron Nitride ◽  
Electron Tunneling ◽  
Hexagonal Boron Nitride ◽  
Large Body ◽  
Liquid Solution ◽  
Limiting Current ◽  
Electron Transfer Rate Constant ◽  
Electrochemical Parameters ◽  
Voltammetric Measurements

Marcus-Hush theory of electron transfer is one of the pillars of modern electrochemistry with a large body of supporting experimental evidence presented to date. However, some predictions, such as the electrochemical behavior at microdisk electrodes, remain unverified. Herein, we present a study of electron tunneling across a hexagonal boron nitride barrier between a graphite electrode and redox levels in a liquid solution. This was achieved by the fabrication of microdisk electrodes with a typical diameter of 5 µm. Analysis of voltammetric measurements, using two common redox mediators, yielded several electrochemical parameters, including the electron transfer rate constant, limiting current, and transfer coefficient. They show a significant departure from the Butler-Volmer behavior in a clear manifestation of the Marcus-Hush theory of electron transfer. In addition, our system provides a novel experimental platform, which could be applied to address a number of scientific problems such as identification of reaction mechanisms, surface modification, or long-range electron transfer.

scholarly journals Self-Sensitization and Photo-Polymerization of Diacetylene Molecules Self-Assembled on a Hexagonal-Boron Nitride Nanosheet

Polymers ◽  
2018 ◽  
Vol 10 (2) ◽  
pp. 206 ◽  
Author(s):  
Elisseos Verveniotis ◽  
Yuji Okawa ◽  
Kenji Watanabe ◽  
Takashi Taniguchi ◽  
Takaaki Taniguchi ◽  
...  
Keyword(s):  
Boron Nitride ◽  
Hexagonal Boron Nitride ◽  
Photo Polymerization ◽  
Boron Nitride Nanosheet ◽  
Self Assembled
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