Giant strain and electric-field-induced phase transition in lead-free (Na0.5Bi0.5)TiO3-BaTiO3-(K0.5Na0.5)NbO3 single crystal

2016 ◽  
Vol 108 (2) ◽  
pp. 022903 ◽  
Author(s):  
Chao Chen ◽  
Xiangyong Zhao ◽  
Yaojin Wang ◽  
Haiwu Zhang ◽  
Hao Deng ◽  
...  
2014 ◽  
Vol 04 (02) ◽  
pp. 1450014 ◽  
Author(s):  
Venkata Sreenivas Puli ◽  
Dhiren K. Pradhan ◽  
Brian C. Riggs ◽  
Shiva Adireddy ◽  
Ram S. Katiyar ◽  
...  

Polycrystalline sample of lead-free 1/3( Ba 0.70 Sr 0.30 TiO 3) + 1/3( Ba 0.70 Ca 0.30 TiO 3) + 1/3( BaZr 0.20 Ti 0.80 O 3)( BST - BCT - BZT ) ceramic was synthesized by solid state reaction method. Phase purity and crystal structure of as-synthesized materials was confirmed by X-ray diffraction (XRD). Temperature-dependent dielectric permittivity studies demonstrated frequency-independent behavior, indicating that the studied sample has typical diffuse phase transition behavior with partial thermal hysteresis. A ferroelectric phase transition between cubic and tetragonal phase was noticed near room temperature (~ 330 K). Bulk P–E hysteresis loop showed a saturation polarization of 20.4 μC/cm2 and a coercive field of ~ 12.78 kV/cm at a maximum electric field of ~ 115 kV/cm. High dielectric constant (ε ~ 5773), low dielectric loss (tan δ ~ 0.03) were recorded at room temperature. Discharge energy density of 0.44 J/cm3 and charge energy density of 1.40 J/cm3 were calculated from nonlinear ferroelectric hysteresis loop at maximum electric field. Dielectric constant at variable temperatures and electric fields, ferroelectric to paraelectric phase transition and energy storage properties were thoroughly discussed.


2019 ◽  
Vol 165 ◽  
pp. 94-97
Author(s):  
Saidong Xue ◽  
Haosu Luo ◽  
Xiangyong Zhao ◽  
Feifei Wang ◽  
Di Lin ◽  
...  

2021 ◽  
Vol 875 ◽  
pp. 55-59
Author(s):  
Ghulam Shabbir ◽  
Ahmad H. Qureshi

The capacitance of (1-x)Pb(Mg1/3Nb2/3)O3-xPbTiO3 (PMN-xPT) [001]-oriented single crystal was examined as a function of temperature and applied external dc electric field. The phase transition temperatures under the applied electric field were measured upon cooling the crystal (zero-field heating field-cooling condition) from paraelectric cubic phase. From these data, temperature versus electric field phase diagram of PMN-xPT crystal have been constructed and discussed.


2015 ◽  
Vol 107 (7) ◽  
pp. 072909 ◽  
Author(s):  
Jinghan Gao ◽  
Qiang Li ◽  
Yuanyuan Li ◽  
Fangping Zhuo ◽  
Qingfeng Yan ◽  
...  

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