Surface modification of cellulose acetate membrane using thermal annealing to enhance produced water treatment

Author(s):  
T. D. Kusworo ◽  
N. Aryanti ◽  
M. M. H. Firdaus ◽  
H. Sukmawati
2018 ◽  
Vol 24 (2) ◽  
pp. 139-147 ◽  
Author(s):  
Tutuk Kusworo ◽  
Hadiyanto Hadiyanto ◽  
Deariska Deariska ◽  
Nugraha Lutfi

Produced water is the wastewater generated from the process of exploration in oil and gas production, which needs special treatment. A membrane with cellulose acetate is widely used for produced water treatment, but further developments and improvements are still required. Therefore, it is important to determine the factors of separation efficiency of an ultrathin cellulose acetate membrane by assessing the influence of the composition of the dope solution. The response surface methodology was employed to determine the optimal conditions for this application. The investigations were conducted by varying the cellulose acetate polymer concentration at 18-20 wt.%, polyethylene glycol 4000 at 2-3 wt.% and nonsolvent addition at 3-5 wt.%. The evaluation of membrane performance for the produced water treatment was performed in a dead-end filtration cell with permeate water flux and rejection parameters for turbidity, total dissolved solids, Ca2+, Mg2+ and sulfides of produced water upstream and downstream of the membrane. The optimal composition of the dope solution was: 19 wt.% of cellulose acetate, 3 wt.% of polyethylene glycol, and 5.67 wt.% of non-solvent.


2018 ◽  
Vol 156 ◽  
pp. 08003 ◽  
Author(s):  
Tutuk Djoko Kusworo ◽  
Danny Soetrisnanto ◽  
Cynthia Santoso ◽  
Tyas Dwi Payanti ◽  
Dani Puji Utomo

Produced water is a wastewater generated from petroleum industry with high concentration of pollutants such as Total Dissolved Solid, Organic content, and Oil and grease. Membrane technology has been currently applied for produced water treatment due to its efficiency, compact, mild and clean process. The main problem of produced water using membrane is fouling on the membrane surface which causes on low permeate productivity. This paper is majority focused on the improvement of anti-fouling performance through several modifications to increase CA membrane hydrophilicity. The membrane was prepared by formulating the dope solution consists of 18 wt-% CA polymer, acetone, and PEG additive (3 wt-%, 5 wt-%, and 7 wt-%). The membranes are casted using NIPS method and being irradiated under UV light exposure. The SEM images show that parepared membrane has asymmetric structure consist of dense layer, intermediete layer, and finger-like support layer. The filtration test shows that PEG addition increase the membrane hydrophilicity and the permeate flux increases. UV light exposure on the membrane improves the membrane stability and hydrophilicity. The imrpovement of membrane anti-fouling performance is essential to achieve the higher productivity without lowering its pollutants rejection.


RSC Advances ◽  
2017 ◽  
Vol 7 (77) ◽  
pp. 48904-48912 ◽  
Author(s):  
Ruijun Zhang ◽  
Shuili Yu ◽  
Wenxin Shi ◽  
Xiaoying Wang ◽  
Jun Cheng ◽  
...  

A facile membrane modification method with serinol to improve the membrane performance in the advanced treatment of polymer flooding produced water.


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