Exchange bias of CoO1−δ/(NiFe,Fe) system with blocking temperature beyond Néel temperature of bulk CoO

2015 ◽  
Vol 107 (17) ◽  
pp. 172404 ◽  
Author(s):  
S. L. Ding ◽  
R. Wu ◽  
J. B. Fu ◽  
X. Wen ◽  
H. L. Du ◽  
...  
2011 ◽  
Vol 10 (04n05) ◽  
pp. 581-585
Author(s):  
BISWAJIT CHOUDHURY ◽  
AMARJYOTI CHOUDHURY ◽  
RAJENDRA K SINGH

Co doped TiO2 nanopowder has been synthesized by a simple sol–gel route. XRD and TEM analysis confirms anatase phase of TiO2 with crystallite and particle sizes of 10 and 15 nm respectively. Presence of Co is confirmed by EDX. FTIR shows a slight shift in the Ti-O bonding vibration to lower frequency suggesting dopant incorporation on Ti site. For magnetic measurements the sample with dopant amount x = 0.075 is annealed both in vacuum and air. Weak ferromagnetism and a blocking temperature of 39 K is obtained for vacuum annealed sample while ferromagnetism is lost in the air annealed sample and shows only paramagnetic behavior. Temperature dependent magnetic measurements for air annealed sample shows antiferromagnetic behavior with a Neel temperature of 36.51 K. Here we report that oxygen vacancy and cobalt aggregates is a key factor for inducing ferromagnetism–superparamagnetism in vacuum annealed sample. Appearance of Neel temperature reveals the presence of antiferromagnetic Co3O4 which is the oxidation results of metallic Co or cobalt clusters present on host TiO2 surface.


Author(s):  
С.А. Борисов ◽  
А.А. Набережнов ◽  
B. Nacke ◽  
A. Nikanorov

The magnetic properties of two-phase borosilicate glasses containing in the skeleton a mixture of β-Fe2O3 and Fe3O4 nanoparticles have been studied. The sizes of nanoparticles have been determined, the value of blocking temperature (TB ~ 330 K) for ensemble of superparamagnetic nanoparticles is obtained. It is shown that in the high applied magnetic fields the specific magnetization of these glasses increases sharply at approaching and below Neel temperature for the bulk β-Fe2O3.


2008 ◽  
Vol 8 (6) ◽  
pp. 2923-2928 ◽  
Author(s):  
J. Nogués ◽  
V. Langlais ◽  
J. Sort ◽  
S. Doppiu ◽  
S. Suriñach ◽  
...  

The magnetic properties of ferromagnetic (FM)–antiferromagnetic (AFM), Ni-NiO, nanocomposites obtained from a reactive ball milling reduction of NiO in H2 atmosphere have been studied. The formation of ferromagnetic Ni from antiferromagnetic NiO can be accurately followed by the increase of the saturation magnetization. The microstructure of the nanocomposite, consisting of FM Ni nanoparticles embedded in an AFM NiO matrix leads to exchange bias effects, i.e., loop shifts and coercivity enhancement, after field cooling from above the Néel temperature of NiO.


2014 ◽  
Vol 105 (12) ◽  
pp. 122405 ◽  
Author(s):  
E. A. Tereshina ◽  
Z. Bao ◽  
L. Havela ◽  
S. Daniš ◽  
C. Kuebel ◽  
...  

2004 ◽  
Vol 69 (21) ◽  
Author(s):  
Hongtao Shi ◽  
D. Lederman ◽  
K. V. O’Donovan ◽  
J. A. Borchers

1971 ◽  
Vol 47 (2) ◽  
pp. K99-K101 ◽  
Author(s):  
A. Sawaoka ◽  
T. Soma ◽  
S. Saito ◽  
Y. Endoh

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