scholarly journals Microscopic insight into the origin of enhanced glass-forming ability of metallic melts on micro-alloying

2015 ◽  
Vol 107 (13) ◽  
pp. 131901 ◽  
Author(s):  
C. J. Chen ◽  
A. Podlesnyak ◽  
E. Mamontov ◽  
W. H. Wang ◽  
S. M. Chathoth
2012 ◽  
Vol 490-495 ◽  
pp. 3129-3133 ◽  
Author(s):  
Gang Wang ◽  
De Chang Zeng ◽  
Zhong Wu Liu

Evaluation of glass-forming ability (GFA) is important in the development of amorphous alloys. Based on phase field theory, the kinetic model of liquid-to-solid phase transition is build, and the time-temperature-transformation (TTT) diagram is plotted according to the phase field simulations of isothermal phase transformation kinetics for a model system. Furthermore, the critical cooling rate for glass formation is calculated on the basis of the TTT curve and is taken as the intrinsic criteria of reflecting the GFA for metallic melts.


1991 ◽  
Vol 56 (10) ◽  
pp. 2142-2147
Author(s):  
Ivo Sláma

The dependence of the induction period of crystallization on supercooling was examined for the silver nitrate-ethylene glycol system over the concentration region of silver nitrate lome fraction of 0 to 0.12. Addition of AgNO3 to ethylene glycol was found to increase considerably the critical induction period of crystallization, although to a lesser extent than Ca(NO3)2, CaCl2, ZnCl2, LiCl and LiNO3 do. The effect of these salts on the critical induction period of crystallization in dimethylsulfoxide, dimethylformamide, dimethylacetamide and methanol was compared in terms of the solvent-rich composition limit of the glass-forming ability. By using the TTT(Time-Temperature-Transformation) theory, it has been deduced that the effect of the salts on the critical induction period of crystallization of ethylene glycol is probably due to the different dependences of viscosity on their concentration in ethylene glyco in the supercooling region.


2011 ◽  
Vol 357 (10) ◽  
pp. 2182-2186 ◽  
Author(s):  
Peng Gao ◽  
Zhu Xue ◽  
Guangbo Liu ◽  
Jin Zhang ◽  
Milin Zhang

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