scholarly journals Direct observation of high-spin states in manganese dimer and trimer cations by x-ray magnetic circular dichroism spectroscopy in an ion trap

2015 ◽  
Vol 142 (23) ◽  
pp. 234301 ◽  
Author(s):  
V. Zamudio-Bayer ◽  
K. Hirsch ◽  
A. Langenberg ◽  
M. Kossick ◽  
A. Ławicki ◽  
...  
1976 ◽  
Vol 159 (3) ◽  
pp. 811-813 ◽  
Author(s):  
T Brittain ◽  
J Springall ◽  
C Greenwood ◽  
A J Thomson

The spin states of the haem components of mixed-valence cytochrome oxidase were studied at room temperature and at temperature down to 20K by using magnetic circular dichroism. The room-temperature studies show the presence of a low-spin ferrous haem together with a low-spin ferric haem, which we attribute to heams a3 and a respectively. At temperatures below 100K it appears that the CO of the mixed-valence CO complex may be irreversibly photolysed, and that in this case haems a and a3 assume their high-spin states. Thus in this enzyme haem-haem interactions appear possible at temperatures below 100K.


2015 ◽  
Vol 91 (7) ◽  
Author(s):  
S. Agrestini ◽  
Z. Hu ◽  
C.-Y. Kuo ◽  
M. W. Haverkort ◽  
K.-T. Ko ◽  
...  

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