Self-assembled ultralight three-dimensional polypyrrole aerogel for effective electromagnetic absorption

2015 ◽  
Vol 106 (22) ◽  
pp. 222902 ◽  
Author(s):  
Aming Xie ◽  
Fan Wu ◽  
Mengxiao Sun ◽  
Xiaoqing Dai ◽  
Zhuanghu Xu ◽  
...  
Keyword(s):  
Three Dimensional ◽  
Electromagnetic Absorption ◽  
Self Assembled

Nanoscale Self-Assembly Using Ion and Electron Beam Techniques: A Rapid Review

MRS Advances ◽  
2020 ◽  
Vol 5 (64) ◽  
pp. 3507-3520
Author(s):  
Chunhui Dai ◽  
Kriti Agarwal ◽  
Jeong-Hyun Cho
Keyword(s):  
Electron Beam ◽  
Self Assembly ◽  
Ion Beam ◽  
Three Dimensional ◽  
The Self ◽  
Stress Generation ◽  
Rapid Review ◽  
High Yield ◽  
3D Nanostructures ◽  
Self Assembled

AbstractNanoscale self-assembly, as a technique to transform two-dimensional (2D) planar patterns into three-dimensional (3D) nanoscale architectures, has achieved tremendous success in the past decade. However, an assembly process at nanoscale is easily affected by small unavoidable variations in sample conditions and reaction environment, resulting in a low yield. Recently, in-situ monitored self-assembly based on ion and electron irradiation has stood out as a promising candidate to overcome this limitation. The usage of ion and electron beam allows stress generation and real-time observation simultaneously, which significantly enhances the controllability of self-assembly. This enables the realization of various complex 3D nanostructures with a high yield. The additional dimension of the self-assembled 3D nanostructures opens the possibility to explore novel properties that cannot be demonstrated in 2D planar patterns. Here, we present a rapid review on the recent achievements and challenges in nanoscale self-assembly using electron and ion beam techniques, followed by a discussion of the novel optical properties achieved in the self-assembled 3D nanostructures.

scholarly journals A novel three-dimensional spherical CuBi2O4 consisting of nanocolumn arrays with persulfate and peroxymonosulfate activation functionalities for 1H-benzotriazole removal

Nanoscale ◽  
2015 ◽  
Vol 7 (17) ◽  
pp. 8149-8158 ◽  
Author(s):  
Wen-Da Oh ◽  
Shun-Kuang Lua ◽  
Zhili Dong ◽  
Teik-Thye Lim
Keyword(s):  
Hydrothermal Method ◽  
Three Dimensional ◽  
Facile Hydrothermal Method ◽  
Self Assembled

A novel CuBi2O4 consisting of self-assembled spherical nanocolumn arrays (CuB-H) was synthesized via a facile hydrothermal method.

Theory of non-equilibrium critical phenomena in three-dimensional condensed systems of charged mobile nanoparticles

2014 ◽  
Vol 16 (27) ◽  
pp. 13974-13983 ◽  
Author(s):  
V. N. Kuzovkov ◽  
G. Zvejnieks ◽  
E. A. Kotomin
Keyword(s):  
Critical Phenomena ◽  
3D Structure ◽  
Three Dimensional ◽  
Charged Nanoparticles ◽  
Self Assembled ◽  
Oppositely Charged ◽  
Condensed Systems ◽  
Non Equilibrium

The 3d structure of self-assembled and oppositely charged nanoparticles.

Self-assembled three-dimensional hierarchical graphene hybrid hydrogels with ultrathin β-MnO2 nanobelts for high performance supercapacitors

2015 ◽  
Vol 3 (4) ◽  
pp. 1540-1548 ◽  
Author(s):  
Sheng Zhu ◽  
Hui Zhang ◽  
Ping Chen ◽  
Lin-Hui Nie ◽  
Chuan-Hao Li ◽  
...  
Keyword(s):  
Self Assembly ◽  
High Performance ◽  
Three Dimensional ◽  
The Self ◽  
Mass Loading ◽  
Hybrid Hydrogel ◽  
Precise Control ◽  
Ultrafine Structure ◽  
Hybrid Hydrogels ◽  
Self Assembled

A facile protocol for the self-assembly of the rGO/β-MnO2 hybrid hydrogel with ultrafine structure and precise control of mass-loading for high performance supercapacitors is reported.

Square-grid coordination networks of (5,10,15,20-tetra-4-pyridylporphyrinato)zinc(II) in its clathrate with two guest molecules of 1,2-dichlorobenzene: supramolecular isomerism of the porphyrin self-assembly

2009 ◽  
Vol 65 (3) ◽  
pp. m139-m142 ◽  
Author(s):  
Rajesh Koner ◽  
Israel Goldberg
Keyword(s):  
Self Assembly ◽  
Metal Ion ◽  
Three Dimensional ◽  
Two Dimensional ◽  
Coordination Networks ◽  
Guest Molecules ◽  
Square Grid ◽  
Supramolecular Isomerism ◽  
Self Assembled ◽  
Solvent Molecules

The title compound, (5,10,15,20-tetra-4-pyridylporphyrinato)zinc(II) 1,2-dichlorobenzene disolvate, [Zn(C40H24N8)]·2C6H4Cl2, contains a clathrate-type structure. It is composed of two-dimensional square-grid coordination networks of the self-assembled porphyrin moiety, which are stacked one on top of the other in a parallel manner. The interporphyrin cavities of the overlapping networks combine into channel voids accommodated by the dichlorobenzene solvent. Molecules of the porphyrin complex are located on crystallographic inversion centres. The observed two-dimensional assembly mode of the porphyrin units represents a supramolecular isomer of the unique three-dimensional coordination frameworks of the same porphyrin building block observed earlier. The significance of this study lies in the discovery of an additional supramolecular isomer of the rarely observed structures of metalloporphyrins self-assembled directly into extended coordination polymers without the use of external ligand or metal ion auxiliaries.

Coating agent-induced mechanical behavior of 3D self-assembled nanocrystals

2017 ◽  
Vol 19 (35) ◽  
pp. 23887-23897 ◽  
Author(s):  
Arzu Çolak ◽  
Jingjing Wei ◽  
Imad Arfaoui ◽  
Marie-Paule Pileni
Keyword(s):  
Mechanical Behavior ◽  
Young’S Modulus ◽  
Young's Modulus ◽  
Three Dimensional ◽  
Coating Agent ◽  
Self Assembled

The Young's modulus of three-dimensional self-assembled Ag nanocrystals, as so-called supracrystals, is correlated with the type of coating agent as well as the nanocrystal morphology.

scholarly journals ORGANOGELS AS A POTENTIAL TOPICAL DRUG DELIVERY SYSTEM

2018 ◽  
Vol 1 (2) ◽  
pp. 49-58
Author(s):  
Shubhendra Jha ◽  
Sheo Datta Maurya
Keyword(s):  
Organic Liquid ◽  
Three Dimensional ◽  
Systemic Effect ◽  
Dosage Forms ◽  
External Application ◽  
Self Assembled ◽  
Bioactive Agents ◽  
Topical Dosage ◽  
Semi Solid ◽  
Topical Dosage Forms

Semisolid preparations for external application to skin have gained much demand, since it is easily absorbed through the skin layers. Many novel topical dosage forms have been discovered, among which organogels appears to play an important role. Interest in organogels has increased in a wide variety of fields including chemistry, biotechnology and pharmaceutics. Organogels are thermodynamically stable, biocompatible, isotropic gel, which not only give localized effect, but also systemic effect through percutaneous absorption. Organogels are semi-solid systems, in which an organic liquid phase is immobilized by a three-dimensional network composed of self assembled, intertwined gelator fibers. The apolar phase gets immobilized within spaces of the three-dimensional networked structure formed due to the physical interactions amongst the self assembled structures of compounds regarded as gelators. Organogels have been explored as matrices for the delivery of bioactive agents. Compared to conventional topical dosage forms, these novel formulations are found to be more advantageous and efficient. In future, organogels can give way to many promising discoveries in the field of topical dosage forms. The current review aims at giving an idea about organogels, its applications and importance in topical delivery.

scholarly journals Three-dimensional self-assembled hybrid silicon nanostructures for high sensitivity SERS chemical and biosensing applications

2021 ◽  
Author(s):  
Jeffery Alexander Powell
Keyword(s):  
Noble Metal ◽  
Three Dimensional ◽  
High Sensitivity ◽  
Metal Nanostructures ◽  
Silicon Nanostructures ◽  
Sers Enhancement ◽  
Noble Metal Nanostructures ◽  
Self Assembled ◽  
Hybrid Silicon ◽  
Si Nanostructures

Raman spectroscopy is a powerful tool for detection of chemical and bioanalytes but lacks enhancement required to detect these analytes at the ultrahigh sensitivity needed for many applications. Surface enhanced Raman Scattering is a technique by which an analyte signal can become greatly enhanced and, near single molecule sensitivity, is achievable. Currently, SERS-based detection platforms currently rely on noble metal nanostructures as primary enhancing sources for the detection of chemical and bioanalytes but have significant limitations in terms of reproducibility and biocompatibility. Recent research has shown that semiconductors have the ability to exhibit SERS enhancing characteristics that can potentially supplant the use of noble metals without the limitations associated with noble metal nanomaterials. This thesis presents, the generation of three-dimensional self-assembled hybrid silicon nanostructures though a laser-ion plume formation mechanism. These Si nanostructures exhibit high sensitivity SERS enhancement characteristics which can be applied for chemical and biosensing applications. In this thesis, the Raman enhancing characteristics of the hybrid Si nanostructures are examined and correlated to the unique physical morphology and material chemistry of these nanostructures. These Si nanostructures are shown to be comprised of individual Si nanospheroids that have fused to form a highly 3D nanoweb-like self-assembled nanostructures. It is also shown that these nanospheroids are composed of both amorphous and polycrystalline sub-regions, which can only be generated within an ion-plume formed by a femtosecond pulsed laser. By programming the laser, the nanostructure morphology and hybrid nature can be manipulated and optimized. These Si nanostructures are shown to be highly sensitive as SERS platforms for chemical analytes. In addition, it is shown that with the application of noble metal nanoparticles on the surface of the 3D hybrid silicon nanowebs structures, an additional enhancement boost can be optimized for the detection of chemical molecules. With this, the dual contribution to the SERS sensitivity from both the primary Si nanostructures and the secondary noble metal nanostructures can be used to detect the presence of a biomolecule analyte is shown. To delve deeper into how these hybrid Si nanostructures cause SERS enhancement of bioanalytes, the Si ion interactions within the laser-ion plume were manipulated to induce quantum-scale defects within the hybrid Si nanospheroids. By creating both an inert and oxygenated laser-ion plumes the formation of sub-nanograins within the nanospheroids and sub-nanovoids on the nanospheroid surface is shown to significantly enhance the detection of bioanalyte signal for multiple biomolecules which act as signals for various diseases. Based on the results in this thesis, it has been proven that Si-based nanostructures have the capacity to be used as sole SERS enhancing sources for chemical and biomolecule analytes.

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