Pd doped reduced graphene oxide for hydrogen storage

2015 ◽  
Author(s):  
Tapas Das ◽  
Seemita Banerjee ◽  
V. Sudarsan
Nanoscale ◽  
2015 ◽  
Vol 7 (47) ◽  
pp. 20180-20187 ◽  
Author(s):  
Wei Qin ◽  
Lu Han ◽  
Hai Bi ◽  
Jiahuang Jian ◽  
Xiaohong Wu ◽  
...  

With the high energy ball milling method, a Co9S8-decorated reduced graphene oxide (RGO) composite, which shows excellent hydrogen storage capacity, has been successfully fabricated with a well-organized layered structure.


2015 ◽  
Vol 1086 ◽  
pp. 91-95 ◽  
Author(s):  
A. Venkatesan ◽  
Raj Nanalal Patel ◽  
E.S. Kannan

Graphene oxide (GO) is extracted from graphite oxide synthesized using modified Hummers method. The extracted GO solution is then drop casted onto a p type silicon substrate and dried in hot air oven. The dried solution is annealed at a temperature of about 200 degree Celsius for about one hour to obtain thermally reduced graphene oxide (RGO). Such thermally synthesized RGO usually have a lot of structural defects which can act as a binding site for hydrogen. The binding efficiency of hydrogen to defect centers can be increased by applying electric field to RGO as it changes the carrier concentration (doping) on the surface. This induces more polarization in the hydrogen molecule resulting in strong binding force, thereby increasing its hydrogen storage efficiency. In our experiment we have demonstrated room temperature electric field doping in RGO films by modulating the channel current by changing the back gate voltage which is a precursor for employing RGO in hydrogen storage applications.KeywordsGraphene oxide, Reduced graphene oxide, Field effect, Hydrogen storage, and Defects


RSC Advances ◽  
2016 ◽  
Vol 6 (82) ◽  
pp. 79072-79084 ◽  
Author(s):  
R. Naresh Muthu ◽  
S. Rajashabala ◽  
R. Kannan

The hydrogen storage performance of hybrid nanocomposites composed of reduced graphene oxide, acid treated halloysite nanotubes and hexagonal boron nitride nanoparticles (RGO/A-HNT/h-BN) was studied.


2017 ◽  
Vol 25 (5) ◽  
pp. 295-300 ◽  
Author(s):  
Mohammadreza Pirzadi Jahromi ◽  
Seyyed Ershad Moradi ◽  
Atefe Nasrollahpour ◽  
Seyyed Mohammad Javad Moradi

2014 ◽  
Vol 2014 ◽  
pp. 1-9 ◽  
Author(s):  
Yuwen Yang ◽  
Fei Zhang ◽  
Hualan Wang ◽  
Qilu Yao ◽  
Xiangshu Chen ◽  
...  

Well dispersed magnetically recyclable bimetallic CoNi nanoparticles (NPs) supported on the reduced graphene oxide (RGO) were synthesized by one-step in situ coreduction of aqueous solution of cobalt(II) chloride, nickel (II) chloride, and graphite oxide (GO) with ammonia borane (AB) as the reducing agent under ambient condition. The CoNi/RGO NPs exhibits excellent catalytic activity with a total turnover frequency (TOF) value of 19.54 mol H2 mol catalyst−1 min−1and a low activation energy value of 39.89 kJ mol−1at room temperature. Additionally, the RGO supported CoNi NPs exhibit much higher catalytic activity than the monometallic and RGO-free CoNi counterparts. Moreover, the as-prepared catalysts exert satisfying durable stability and magnetically recyclability for the hydrolytic dehydrogenation of AB, which make the practical reusing application of the catalysts more convenient. The usage of the low-cost, easy-getting catalyst to realize the production of hydrogen under mild condition gives more confidence for the application of ammonia borane as a hydrogen storage material. Hence, this general method indicates that AB can be used as both a potential hydrogen storage material and an efficient reducing agent, and can be easily extended to facile preparation of other RGO-based metallic systems.


ACS Nano ◽  
2020 ◽  
Vol 14 (2) ◽  
pp. 1745-1756 ◽  
Author(s):  
Sohee Jeong ◽  
Tae Wook Heo ◽  
Julia Oktawiec ◽  
Rongpei Shi ◽  
ShinYoung Kang ◽  
...  

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