scholarly journals Non-equilibrium oxidation states of zirconium during early stages of metal oxidation

2015 ◽  
Vol 106 (10) ◽  
pp. 101603 ◽  
Author(s):  
Wen Ma ◽  
F. William Herbert ◽  
Sanjaya D. Senanayake ◽  
Bilge Yildiz
Keyword(s):  
Oxidation States ◽  
Metal Oxidation ◽  
Early Stages ◽  
Non Equilibrium

Inherent Selectivity of Pd C–H Activation from Different Metal Oxidation States

2021 ◽  
Author(s):  
Peter Amadeo ◽  
Bangaru Bhaskararao ◽  
Yun-Fang Yang ◽  
Marisa C. Kozlowski
Keyword(s):  
Oxidation States ◽  
Metal Oxidation

Monodisperse Samarium and Cerium Orthovanadate Nanocrystals and Metal Oxidation States on the Nanocrystal Surface

Langmuir ◽  
2009 ◽  
Vol 25 (18) ◽  
pp. 11142-11148 ◽  
Author(s):  
Thanh-Dinh Nguyen ◽  
Cao-Thang Dinh ◽  
Trong-On Do
Keyword(s):  
Oxidation States ◽  
Metal Oxidation

The assignment and validation of metal oxidation states in the Cambridge Structural Database

2000 ◽  
Vol 56 (3) ◽  
pp. 455-465 ◽  
Author(s):  
Gregory P. Shields ◽  
Paul R. Raithby ◽  
Frank H. Allen ◽  
W. D. Samuel Motherwell
Keyword(s):  
Bond Length ◽  
Copper Complexes ◽  
Search Time ◽  
Cambridge Structural Database ◽  
Oxidation States ◽  
Metal Oxidation ◽  
Metal Atoms ◽  
Organic Complexes ◽  
Length Data ◽  
Structural Database

A methodology has been developed for the semi-automatic assignment and checking of formal oxidation states for metal atoms in the majority of metallo-organic complexes stored in the Cambridge Structural Database (CSD). The method uses both chemical connectivity and bond-length data, via ligand donor group templates and bond-valence sums, respectively. In order to use bond-length data, the CSD program QUEST has been modified to allow the coordination sphere of metal atoms to be recalculated using user-defined criteria at search time. The new methodology has been used successfully to validate the +1, +2 and +3 oxidation states in 743 four-coordinate copper complexes in the CSD for which atomic coordinates are available in ca 99% of structures using one or other method, and both succeed for >86% of structures.

scholarly journals Influencing the coordination mode of tbta (tbta = tris[(1-benzyl-1H-1,2,3-triazol-4-yl)methyl]amine) in dicobalt complexes through changes in metal oxidation states

2013 ◽  
Vol 42 (19) ◽  
pp. 6944 ◽  
Author(s):  
David Schweinfurth ◽  
Johannes Klein ◽  
Stephan Hohloch ◽  
Sebastian Dechert ◽  
Serhiy Demeshko ◽  
...  
Keyword(s):  
Coordination Mode ◽  
Oxidation States ◽  
Metal Oxidation ◽  
Methyl Amine

scholarly journals Single crystal structures and theoretical calculations of uranium endohedral metallofullerenes (U@C2n, 2n = 74, 82) show cage isomer dependent oxidation states for U

2017 ◽  
Vol 8 (8) ◽  
pp. 5282-5290 ◽  
Author(s):  
Wenting Cai ◽  
Roser Morales-Martínez ◽  
Xingxing Zhang ◽  
Daniel Najera ◽  
Elkin L. Romero ◽  
...  
Keyword(s):  
Single Crystal ◽  
Crystal Structures ◽  
Oxidation State ◽  
Theoretical Calculations ◽  
State Dependence ◽  
Oxidation States ◽  
Metal Oxidation ◽  
X Ray ◽  
Endohedral Metallofullerenes ◽  
Single Crystal Structures

First X-ray structures and metal oxidation state dependence on cage isomerism for U-EMFs.

How Innocent are Potentially Redox Non-Innocent Ligands? Electronic Structure and Metal Oxidation States in Iron-PNN Complexes as a Representative Case Study

2015 ◽  
Vol 54 (10) ◽  
pp. 4909-4926 ◽  
Author(s):  
Burkhard Butschke ◽  
Kathlyn L. Fillman ◽  
Tatyana Bendikov ◽  
Linda J. W. Shimon ◽  
Yael Diskin-Posner ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Oxidation States ◽  
Metal Oxidation ◽  
Representative Case

scholarly journals Metal oxidation states in biological water splitting

2015 ◽  
Vol 6 (3) ◽  
pp. 1676-1695 ◽  
Author(s):  
Vera Krewald ◽  
Marius Retegan ◽  
Nicholas Cox ◽  
Johannes Messinger ◽  
Wolfgang Lubitz ◽  
...  
Keyword(s):  
Photosystem Ii ◽  
Water Splitting ◽  
Oxidation States ◽  
Oxygen Evolving Complex ◽  
Central Question ◽  
Manganese Ions ◽  
Metal Oxidation ◽  
Biological Water ◽  
Oxygen Evolving

A central question in biological water splitting concerns the oxidation states of the manganese ions that comprise the oxygen-evolving complex of photosystem II.

scholarly journals Mechanistic elucidation of the role of metal oxidation states in nickel mediated electrocatalytic coupling of benzyl halides

2020 ◽  
Vol 1 (2) ◽  
pp. 143-149
Author(s):  
Pradip K. Das ◽  
Priyanka Chakraborty ◽  
Sandeep Suryabhan Gholap ◽  
Théo P. Gonçalves ◽  
Changguang Yao ◽  
...  
Keyword(s):  
Oxidation States ◽  
Metal Oxidation ◽  
Benzyl Halides
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