Theoretical reproduction of the Q-band absorption spectrum of free-base chlorin

2015 ◽  
Vol 142 (3) ◽  
pp. 034302 ◽  
Author(s):  
Justyna Wójcik ◽  
Alicja Ratuszna ◽  
Jerzy Peszke ◽  
Roman Wrzalik
1999 ◽  
Vol 19 (1-4) ◽  
pp. 71-74 ◽  
Author(s):  
Xuming Zheng ◽  
David Lee Phillips

We have obtained A-band absorption resonance Raman spectra of 1-chloro-2- iodoethane in cyclohexane solution. We have done preliminary time-dependent wavepacket calculations to simulate the resonance Raman intensities and absorption spectrum in order to learn more about the short-time photodissociation dynamics. We compare our preliminary results for 1-chloro-2-iodoethane with previous resonance Raman results for iodoethane and find that there appears to be more motion along non- C—I stretch modes for 1-chloro-2-iodoethane than for iodoethane. This is consistent with results of TOF photofragment spectroscopy experiments which indicate much more internal excitation of the photoproducts from 1-chloro-2-iodoethane photodissociation than the photoproducts from iodoethane photodissociation.


In some previous papers it has been shown by the author and others that saturated compounds of most substances in the vapour state show continuous absorption. A typical example is SO 3 -vapour, which was recently studied by the author and which enabled him to make an accurate estimation of the heat of dissociation of oxygen. In the present work, the absorption spectrum of N 2 O was investigated with a view to determining the heat of dissociation of nitrogen. Leifson was the first to investigate the absorption spectrum of N 2 O gas and found that the gas shows no selective absorption in the Schumann region. He states that the absorption is in the form of two continuous bands, the first extending from λ 2000 to λ 1680 and the second from λ 1550 beyond the range of observation. Recently Wulf and Melvin showed that when N 2 O is illuminated with light of wave-length λ 2300, it is decomposed photochemically into NO and N; they also noticed that N 2 O possesses no band absorption.


2014 ◽  
Vol 595-596 ◽  
pp. 97-102 ◽  
Author(s):  
Benedito J.C. Cabral ◽  
Vinícius Wilian D. Cruzeiro ◽  
Kaline Coutinho ◽  
Sylvio Canuto

1970 ◽  
Vol 33 (3) ◽  
pp. 381-406 ◽  
Author(s):  
M.A.A Clyne ◽  
J.A Coxon

2016 ◽  
Vol 4 (3) ◽  
pp. 513-520 ◽  
Author(s):  
Yun-Ming Sung ◽  
Ying-Chih Lai ◽  
Ming-Fong Tsai ◽  
Hsing-Hua Hsieh ◽  
Min-Han Yang ◽  
...  

A large enhancement in the performance of solar cells, arising from plasmonic nanomaterials with a broad band absorption spectrum, is proposed.


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