Bimolecular reaction of CH3 + CO in solid p-H2: Infrared absorption of acetyl radical (CH3CO) and CH3-CO complex

2014 ◽  
Vol 140 (24) ◽  
pp. 244303 ◽  
Author(s):  
Prasanta Das ◽  
Yuan-Pern Lee
1977 ◽  
Vol 38 (C2) ◽  
pp. C2-93-C2-96 ◽  
Author(s):  
C. G. GRANQVIST ◽  
R. A. BUHRMAN ◽  
J. WYNS ◽  
A. J. SIEVERS

2013 ◽  
Vol 10 (2) ◽  
pp. 51
Author(s):  
Siti Farhana Zakaria ◽  
Keith R Millington

Polymers and organic materials that are exposed to sunlight undergo photooxidation, which leads to deterioration of their physical properties. To allow adequate performance under outdoor conditions, synthetic polymers require additives such as antioxidants and UV absorbers. A major problem with optimising polymer formulations to maximise their working life span is that accelerated weathering tests are empirical. The conditions differ significantly from real weathering situations, and samples require lengthy irradiation period. Degradation may not be apparent in the early stages of exposure, although this is when products such as hydroperoxides are formed which later cause acceleration of oxidation. A simple way of quantifying the number of free radicals presents in organic materials following exposure to light or heat is by measuring chemiluminescence (CL) emission. Most polymers emit CL when they undergo oxidative degradation, and it originates from the bimolecular reaction of macroperoxy radicals which creates an excited carbonyl.


2010 ◽  
Vol 25 (10) ◽  
pp. 1029-1033
Author(s):  
Shi-Xing XIA ◽  
Chun-Hui YANG ◽  
Chong-Qiang ZHU ◽  
Tian-Hui MA ◽  
Meng WANG ◽  
...  

1999 ◽  
Author(s):  
Simon Tam ◽  
Michelle E. DeRose ◽  
Mario E. Fajardo ◽  
Norihito Sogoshi ◽  
Yoshiyasu Kato

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