scholarly journals Communication: Direct measurements of nascent O(3P0,1,2) fine-structure distributions and branching ratios of correlated spin-orbit resolved product channels CO(ã3Π; v) + O(3P0,1,2) and CO(X̃Σ+1; v) + O(3P0,1,2) in VUV photodissociation of CO2

2014 ◽  
Vol 140 (23) ◽  
pp. 231101 ◽  
Author(s):  
Zhou Lu ◽  
Yih Chung Chang ◽  
Hong Gao ◽  
Yanice Benitez ◽  
Yu Song ◽  
...  
RSC Advances ◽  
2016 ◽  
Vol 6 (102) ◽  
pp. 100568-100576 ◽  
Author(s):  
Mingkai Fu ◽  
Jianwei Cao ◽  
Haitao Ma ◽  
Wensheng Bian

A laser cooling scheme is proposed for CuF by including the spin–orbit coupling effects, and based on our calculated radiative lifetimes and vibrational branching ratios.


2012 ◽  
Vol 109 (16) ◽  
Author(s):  
F. Baboux ◽  
F. Perez ◽  
C. A. Ullrich ◽  
I. D’Amico ◽  
J. Gómez ◽  
...  

2020 ◽  
Vol 6 (17) ◽  
pp. eaay9672 ◽  
Author(s):  
Michael R. Wilczynska ◽  
John K. Webb ◽  
Matthew Bainbridge ◽  
John D. Barrow ◽  
Sarah E. I. Bosman ◽  
...  

Observations of the redshift z = 7.085 quasar J1120+0641 are used to search for variations of the fine structure constant, a, over the redshift range 5:5 to 7:1. Observations at z = 7:1 probe the physics of the universe at only 0.8 billion years old. These are the most distant direct measurements of a to date and the first measurements using a near-IR spectrograph. A new AI analysis method is employed. Four measurements from the x-shooter spectrograph on the Very Large Telescope (VLT) constrain changes in a relative to the terrestrial value (α0). The weighted mean electromagnetic force in this location in the universe deviates from the terrestrial value by Δα/α = (αz − α0)/α0 = (−2:18 ± 7:27) × 10−5, consistent with no temporal change. Combining these measurements with existing data, we find a spatial variation is preferred over a no-variation model at the 3:9σ level.


1987 ◽  
Vol 42 (6) ◽  
pp. 597-602
Author(s):  
H. N. v. Allwörden ◽  
W. Preetz

The vibrational and electronic resonance Raman spectra of the solid tetraalkylammonium salts of [RuClnBr6-n]2-, n = 0 . . . 6, are measured at 80 K. The observed electronic Raman bands in the regions of 640-740 cm-1 and 1560-1790 cm-1 are assigned to the intraconfigurational transitions Γ1 → Γ4 and Γ1 → Γ3, Γ5 within the 3T1g(Oh) ground term. The observed splittings and shifts, due to spin orbit coupling and lowered symmetry, are interpreted qualitatively according to the point groups D4h, C4V, C3V and C2V. The O-O-transitions are deduced from vibrational fine structure. The electronic Raman bands of [RuCl6]2- and [RuBr6]2- are assigned in detail by polarisation measurements.


2009 ◽  
Vol 64 (12) ◽  
pp. 834-836
Author(s):  
Chao Ni ◽  
Yi Huang ◽  
Maolu Du

Introducing the average covalent factor N and considering the interaction of the cubic crystal field, the spin-orbit coupling and Tree’s correction effects, the crystal field parameter Dq was calculated. Also the varying tendency of Dq with the bond length R was investigated. Using the complete diagonalizing method the energy levels of the fine structure of Ga2Se3:Co2+ single crystal were calculated and assigned. The calculated and assigned results are consistent with the experimental data


2009 ◽  
Vol 11 (23) ◽  
pp. 4770 ◽  
Author(s):  
Kristin S. Dooley ◽  
Michael P. Grubb ◽  
Justine Geidosch ◽  
Marloes A. van Beek ◽  
Gerrit C. Groenenboom ◽  
...  

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